Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "free volume" wg kryterium: Temat

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-8 z 8
    Tytuł:
    Influence of low temperature on the free volume in polyethylene by positron annihilation
    Autorzy:
    Osoba, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/146305.pdf
    Data publikacji:
    2010
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    positron annihilation
    polymers
    free volume
    Opis:
    Positron lifetime measurements were performed as a function of temperature in thermo-shrunken, modified polyethylene. Mean volume of free volume cavities in the investigated polymer was estimated from the results of the measurements. This mean volume turned out to be a smooth function of temperature (from room temperature to 8.5 K). The effect of trapping of free electrons, produced during positron irradiation, was observed at lowered temperature.
    Źródło:
    Nukleonika; 2010, 55, 1; 69-72
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Positrons in naphthalene : critical remarks on the relation between o-Ps lifetime and void size
    Autorzy:
    Goworek, T.
    Zgardzińska, B.
    Wawryszczuk, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/148003.pdf
    Data publikacji:
    2013
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    high pressure
    naphthalene
    positronium quenching
    free volume
    Opis:
    Lowering the temperature or applying high pressure leads to elimination of positronium component in the e+ lifetime spectrum in solid naphthalene. Disappearance of positronium means reaching the free volume size limit at which there is no energy level in the potential well. It allows to estimate that size, which is found inconsistent with predictions of the popular Tao-Eldrup model. The range of applicability of that model is discussed. The dependence of the free e+ decay constant on pressure indicates that positronium is formed not only in the blob processes, but during the whole free positron life. The lifetime of free positrons begins to rise with temperature earlier than Ps intensity.
    Źródło:
    Nukleonika; 2013, 58, 1; 183-187
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Bean cotyledons microporosity under hydration conditions
    Autorzy:
    Golonka, P.
    Dryzek, J.
    Kluza, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/147053.pdf
    Data publikacji:
    2002
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    bound water
    free volume
    PAS
    proton NMR
    Opis:
    Positron Annihilation Spectroscopy (PAS), proton Nuclear Magnetic Relaxation (NMR) and hydration kinetics measurements were applied to study the free volume formation process in the initial stages of bean cotyledons imbibition. These methods allowed us to analyse the behaviour of bound water in the bean cotyledon molecular structure, and to observe free volume regions formed there. They also made it possible to describe their dimensions and concentration quantitatively. Good correlation was found between the increase of the free volume radius and the amount of water bound to the bean cotyledon solid matrix.
    Źródło:
    Nukleonika; 2002, 47, 4; 137-140
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    PALS investigations of free volumes thermal expansion of J-PET plastic scintillator synthesized in polystyrene matrix
    Autorzy:
    Wieczorek, A.
    Zgardzińska, B.
    Jasińska, B.
    Gorgol, M.
    Bednarski, T.
    Białas, P.
    Czerwiński, E.
    Gajos, A.
    Kamińska, D.
    Kapłon, Ł.
    Kochanowski, A.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krzemień, W.
    Kubicz, E.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Rudy, Z.
    Rundel, O.
    Sharma, N. G.
    Silarski, M.
    Silarski, A.
    Strzelecki, A.
    Wiślicki, W.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/147132.pdf
    Data publikacji:
    2015
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    free volume
    positron annihilation
    polystyrene
    positronium
    scintillator
    Opis:
    The polystyrene doped with 2,5-diphenyloxazole as a primary fluor and 2-(4-styrylphenyl)benzoxazole as a wavelength shifter prepared as a plastic scintillator was investigated using positronium probe in wide range of temperatures from 123 to 423 K. Three structural transitions at 260, 283, and 370 K were found in the material. In the o-Ps intensity dependence on temperature, the significant hysteresis is observed. Heated to 370 K, the material exhibits the o-Ps intensity variations in time.
    Źródło:
    Nukleonika; 2015, 60, No. 4, part 1; 777-781
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Biodegradable polyester blend and copolyesters studied by positron annihilation and other methods
    Autorzy:
    Dębowska, M.
    Rudzińska-Girulska, J.
    Serwadczak, M.
    Kiersnowski, A.
    Pigłowski, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/146301.pdf
    Data publikacji:
    2010
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    mixing of polymers
    polyesters
    transesterification
    positron annihilation
    positronium
    free volume
    Opis:
    Two polyesters, i.e. an aromatic one: poly(butylene terephthalate) – PBT and an aliphatic one: poly(ĺ- -caprolactone) – PCL were mixed in melt to obtain a biodegradable product. DSC, 1H NMR, SEM, WAXS, SAXS, BOD and PALS measurements were performed to study the homopolymers as well as their physical blend and copolyesters. The latter were obtained due to the transesterification reaction. Ortho-positronium (o-Ps) annihilation lifetimes were used to create the distributions of free volume. The progressive changes in probability density function of free volume, i.e. increase in large free volume holes contribution to the total free volume, appearing when going from the homopolymers to the blend and then to the copolyesters reflect the influence of: the addition of aliphatic polyester, the weight fraction of it in the composition and transesterification. The higher contribution of larger free volume holes corresponds well with the reduced crystallinity of compositions revealed in X-ray diffraction and the worsening of the regularity of structure of the macromolecules involved in formation of crystals, deduced from the 1H NMR.
    Źródło:
    Nukleonika; 2010, 55, 1; 57-64
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    PALS investigation of resorcinol under high pressure
    Autorzy:
    Tydda, M.
    Jasińska, B.
    Pieniążek, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/147999.pdf
    Data publikacji:
    2013
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    free volume
    ortho-positronium (o-Ps)
    pressure
    positron annihilation lifetime spectroscopy (PALS)
    Opis:
    Two kinds of measurements were conducted with resorcinol at high pressure : the first one with the use of a mechanical press and the second one with the use of a gaseous compressor. In the second case, due to some gas penetrating the material structure, the lifetime spectra obtained were difficult to analyze. The free volumes in resorcinol were influenced both by high pressure and the gas coming into the crystallographic structure.
    Źródło:
    Nukleonika; 2013, 58, 1; 195-198
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparison of the free volume sizes and shapes determined from crystallographic and PALS data
    Autorzy:
    Tydda, M.
    Jasińska, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/146378.pdf
    Data publikacji:
    2015
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    benzenediols
    free volume
    molecular crystals olanzapine
    positron annihilation
    positronium
    positronium diffusion coefficient
    Opis:
    Two different classes of molecular crystals were investigated. The first group was benzenediols, which are characterized by the same chemical composition but a different organization of their crystallographic structures; all of the compounds from this group have only one kind of free volumes. The second class was represented by olanzapine, which has more complex chemical composition and two kinds of free volumes in the structure. The o-Ps lifetime values determined from positron annihilation lifetime spectroscopy (PALS) measurements agree quite well with those calculated for sizes found from crystallographic data for benzenediols (agreement within 10% of the lifetime values). For olanzapine, a good agreement is observed in the case of cuboidal free volumes, while for the other kind of void, the agreement is less satisfactory. Positronium diffusion coefficient determined from o-Ps redistribution in olanzapine agrees with these found for polymers.
    Źródło:
    Nukleonika; 2015, 60, No. 4, part 1; 771-775
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Studies of unicellular microorganisms Saccharomyces cerevisiae by means of positron annihilation lifetime spectroscopy
    Autorzy:
    Kubicz, E.
    Jasińska, B.
    Zgardzińska, B.
    Bednarski, T.
    Białas, P.
    Czerwiński, E.
    Gajos, A.
    Gorgol, M.
    Kamińska, D.
    Kapłon, Ł.
    Kochanowski, A.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krzemień, W.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Rajfur, Z.
    Rudy, Z.
    Rundel, O.
    Sharma, N. G.
    Silarski, M.
    Słomski, A.
    Strzelecki, A.
    Wieczorek, A.
    Wiślicki, W.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/147902.pdf
    Data publikacji:
    2015
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    environmental scanning electron microscopy (ESEM)
    free volume
    inverted microscopy
    positron annihilation
    positronium
    yeasts
    Opis:
    Results of positron annihilation lifetime spectroscopy (PALS) and microscopic studies on simple microorganisms, brewing yeasts, are presented. Lifetime of ortho-positronium (o-Ps) were found to change from 2.4 to 2.9 ns (longer-lived component) for lyophilized and aqueous yeasts, respectively. Also hygroscopicity of yeasts in time was examined, allowing to check how water – the main component of the cell – affects PALS parameters, thus lifetime of o-Ps were found to change from 1.2 to 1.4 ns (shorter-lived component) for the dried yeasts. The time sufficient to hydrate the cells was found below 10 hours. In the presence of liquid water, an indication of reorganization of yeast in the molecular scale was observed. Microscopic images of the lyophilized, dried, and wet yeasts with best possible resolution were obtained using inverted microscopy (IM) and environmental scanning electron microscopy (ESEM) methods. As a result, visible changes to the surface of the cell me mbrane were observed in ESEM images.
    Źródło:
    Nukleonika; 2015, 60, No. 4, part 1; 749-753
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-8 z 8

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies