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    Wyświetlanie 1-8 z 8
    Tytuł:
    Prediction of Detonation Pressure and Velocity of Explosives with Micrometer Aluminum Powders
    Autorzy:
    Zhang, Q.
    Chang, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358334.pdf
    Data publikacji:
    2012
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    aluminized explosives
    detonation pressure
    nonideal explosives
    detonation velocity
    Opis:
    The data reported shows that the Chapman-Jouguet (CJ) detonation parameters of non-ideal explosives calculated from existing thermodynamic computer codes are significantly different from experimental results. We use CJ detonation theory to present a new approach predicting detonation pressure and velocity of aluminized explosives by thermodynamic detonation theory. There is no need to use the assumption of full and partial equilibrium of aluminum powder in reaction zones in the new approach. In this work the best agreement with experimental data was obtained by adjusting the parameter k in the Becker- Kistiakosky-Wilson equations of state (BKW-EOS). The detonation pressure and velocity values calculated by the present method agree well with the experimental results. All of the deviations for the calculated pressures of aluminized explosives are less than 9% and those for the detonation velocities are less than 7%.
    Źródło:
    Central European Journal of Energetic Materials; 2012, 9, 1; 77-86
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A Predictive Method for the Heat of Explosion of Non-ideal Aluminized Explosives
    Autorzy:
    Zhang, Q.
    Chang, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358737.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    aluminized explosives
    heat of explosion
    thermodynamic
    nonideal explosives
    high energy materials
    Opis:
    The heat of explosion is one of the most important thermodynamic parameters of aluminized explosives. Two improvements in numerical calculations to predict the behaviour of the explosion of non-ideal aluminized explosives were completed in this work. The chemical reaction between aluminum and the C-J detonation products of high energy ingredients was determined and the equation of state for the detonation products of high energy ingredients was revised. The constant k in the BKW equation was revised to obtain perfect results for predicting the C-J parameters for high energy ingredients. The predicted results show that the heats and temperatures of aluminized explosives become maximized when the mass fraction of aluminum powder is 30%, which is in good agreement with the results obtained by empirical formulae.
    Źródło:
    Central European Journal of Energetic Materials; 2013, 10, 4; 541-554
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Theoretical and Experimental Study on Detonation Wave Propagation in Cylindrical High Explosive Charges with a Wave-shaper
    Autorzy:
    Pan, J.
    Zhang, X.
    He, Y.
    Deng, Q.
    Guan, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/358040.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    high explosive
    detonation wave
    Mach reflection
    wave-shaper
    Whitham method
    Opis:
    The use of a cylindrical high-explosive charge with a wave-shaper is an efficient way to obtain an ultra-high pressure and a convergent detonation wave. An analysis of flow fields corresponding to the regular and Mach reflection of detonation waves in a cylindrical high-explosive charge with a wave-shaper is presented in this paper. The pressure, flow velocity and triple point growth angle of the Mach stem were calculated. The Mach stem height was also determined by using the modified Whitham method. The results show that the Mach stem height rises from zero at the critical angle of Mach reflection and changes to the Chapman-Jouguet detonation state with the propagation of the detonation waves. Shock indentation experiments were conducted, in which a wave-shaper was used in a cylindrical high-explosive charge to form Mach reflection detonation waves. The results showed that the discrepancy between the experimental results and the theoretical calculations was less than 15%, which proves the validity of the proposed theoretical model.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 3; 658-676
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, Structure and Energetic Properties of a Catenated N6, Polynitro Compound: 1,1’-Azobis(3,5-dinitropyrazole)
    Autorzy:
    Li, Y.-N.
    Shu, Y.-J.
    Wang, Y.-L.
    Wang, B.-Z.
    Zhang, S.-Y.
    Bi, F.-Q.
    Powiązania:
    https://bibliotekanauki.pl/articles/358573.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    energetic compound
    1,1’-azobis(3,5-dinitropyrazole)
    synthesis
    energetic properties
    Opis:
    A nitrogen-rich, polynitro energetic compound with an N,N-azo linkage, 1,1’-azobis(3,5-dinitropyrazole) (ABDNP), has been synthesized by an oxidative coupling reaction of 1-amino-3,5-dinitropyrazole with different oxidizing agents. The target compound was characterized by IR spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy, elemental analysis, mass spectra, X-ray diffraction and differential scanning calorimetry (DSC). The DSC results show that 1,1’-azobis(3,5-dinitropyrazole) decomposes at a relatively high onset temperature (202.9 °C), which indicates that 1,1’-azobis(3,5-dinitropyrazole) has acceptable thermal stability. The energetic properties were obtained, with a measured density and heat of formation matched by theoretically computed values based on the B3LYP method.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 2; 321-335
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effects of Polymeric Binders on the RDX-based Explosive Response Character under Slow Cook-off Conditions
    Autorzy:
    Yan, X.
    Li, X. D.
    Zhang, Y. R.
    Liu, L.
    Zhang, X. M.
    Tan, Y. X.
    Wang, H.
    Wang, X. Q.
    Powiązania:
    https://bibliotekanauki.pl/articles/358419.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    RDX-based explosive
    slow cook-off experiment
    binder content
    binder type
    Opis:
    Due to safety requirements, insensitive behaviour under slow thermal heating (cook-off) conditions is a desirable behaviour for today’s munitions. In this paper a cook-off device is designed to test two groups of RDX-based PBX explosives. In the first group the binder type was varied and in the second group the binder content of the RDX-based explosive was changed. Eleven samples were examined in order to evaluate the influence of four different binders and seven different binder contents on the shell deformation and the degree of the involved reaction. The test results showed that the degree of the reaction can be improved by changing the binder content, but not by the binder type. This phenomenon was explained by the thermal-conduction theory.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 2; 339-350
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Research on the Mechanism and Kinetics of Polymorphic Transitions of ε CL-20 in Composite Systems
    Autorzy:
    Guo, X.-Y.
    Zhang, P.
    Xu, J.-J.
    Wang, Z.-H.
    Jiao, Q.-J.
    Powiązania:
    https://bibliotekanauki.pl/articles/358032.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    polymorphic transition
    kinetics
    activation energy
    transition temperature
    Opis:
    In order to explore the polymorphic transition law for ε-CL-20 in composite systems, the polymorphic transition process of pure ε-CL-20 crystals stimulated by heat was investigated by the X-ray Diffraction (XRD) method, and the kinetic parameters of the polymorphic transition process were calculated (including the apparent activation energy Ea and the pre-exponential factor lnA). Meanwhile the effects of different additives on the polymorphic transition process and kinetics of ε-CL-20 were explored in detail. The experimental results showed that the ε-form tends to transform into the γ- form on heating and that the Ea and lnA for the transition process were 209.97 kJ/mol and 57.47, respectively. The first group of additives clearly promoted the polymorphic transition of ε-CL-20 and lowered the initial transition temperature and the activation energy. The second and third groups of additives inhibited the polymorphic transition of ε-CL-20 and raised the initial transition temperature and the activation energy.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 4; 689-702
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Characterization of a High Energy Combustion Agent (BHN) and Its Effects on the Combustion Properties of Fuel Rich Solid Rocket Propellants
    Autorzy:
    Pang, W.-Q.
    Zhao, F.-Q.
    Xue, Y.-N.
    Xu, H.-X.
    Fan, X.-Z.
    Xie, W.-X.
    Zhang, W.
    Lv, J.
    Deluca, L. T.
    Powiązania:
    https://bibliotekanauki.pl/articles/358474.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    fuel rich solid propellant
    BHN
    DSC
    TG-DTG
    burning rate
    combustion properties
    Opis:
    A high energy combustion agent (tetraethylammonium decahydrodecaborate, BHN) was prepared by means of an ion exchange reaction (IER), and the prepared samples were characterized by the advanced diagnostic techniques of Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) etc. The effects of BHN particles on the hazard and combustion properties of fuel rich solid propellants were investigated. The results showed that the BHN samples and fuel rich propellants containing BHN particles can be prepared successfully and solidified safely. The peak temperature of thermal decomposition and the heat of decomposition of the BHN samples prepared were 305.8 °C and 210.9 J•g-1 at a heating rate of 10 K•min-1, respectively. The burning rate and pressure exponent of fuel rich solid propellants decreases with increases in the fraction of BHN particles in the propellant formulation. Compared with the reference formulation (sample BP-1), the burning rate of the propellant with 10% mass fraction of BHN particles (sample BP-4) had decreased 30% at 3.0 MPa, and the pressure exponent had dropped from 0.44 to 0.41.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 3; 537-552
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
    Autorzy:
    Yan, G.
    Tian, Q.
    Liu, J.
    Fan, Z.
    Sun, G.
    Zhang, C.
    Wang, Y.
    Chen, B.
    Gong, J.
    Zhou, X.
    Yang, Z.
    Nie, F.
    Li, J.
    Li, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/358618.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    SANS
    SAXS
    HMX-PBX
    thermal damages
    phase transition
    Opis:
    The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-8 z 8

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