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Wyświetlanie 1-2 z 2
Tytuł:
Thermally induced damage in hexanitrohexaazaisowurtzitane
Autorzy:
Tian, Q.
Yan, G.
Sun, G.
Huang, C.
Xie, L.
Chen, B.
Huang, M.
Li, H.
Liu, X.
Wang, J.
Powiązania:
https://bibliotekanauki.pl/articles/358735.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
CL-20
SAXS
AFM
thermal effects
voids
Opis:
The evolution of the microstructure of hexanitrohexaazaisowurtzitane (CL-20) after a thermal stimulus plays a key role in the performance of CL-20. In the current work, microstructural variations of CL-20 caused by thermal treatment were investigated by X-ray diffraction, in situ variable-temperature optical microscopy, atom force microscopy, and small-angle X-ray scattering. A wave-like process, an abrupt volume expansion, movement, and fragmentation of CL-20 particles during phase transition were observed. After the phase transition (160 °C) the CL-20 sample acquired a very rough surface with numerous dimple depressions, and during the thermal decomposition stage (200 °C) a large number of voids were produced in both the bulk and the surface of the CL-20.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 3; 359-369
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Coating of LiBH4 and Its Effect on the Decomposition of RDX and AP
Autorzy:
Ding, X.
Shu, Y.
Chen, Z.
Liu, N.
Gou, B.
Zhang, J.
Wu, M.
Xie, G.
Dang, T.
Powiązania:
https://bibliotekanauki.pl/articles/358086.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
coating
hydride
additive
hygroscopicity
DSC
Opis:
The novel fuel additive LiBH4 was introduced as an energetic component for its outstanding hydrogen content, perfect burning performance and high reactivity. In order to limit the hygroscopicity and to improve the stability in the air, LiBH4 was coated on the surface with wax and polyester carbonate. The final product was characterized by scanning electron microscopy (SEM), X-ray photoelectron energy spectroscopy (XPS) and Raman spectroscopy, while the stability in air was investigated by regular checking of variations in weight. The results show that a uniform coating layer was formed on the surface of the LiBH4, and the coverage was estimated from the boron content as approximately 82%. A healing effect was confirmed on defective surfaces exposed to air; the coating layer improves the relative stability by 50.7%. Furthermore, LiBH4 as an additive to promote the thermal decomposition of 1,3,5-trinitro-1,3,5-trazinane (RDX) and ammonium perchlorate (AP) was explored by differential scanning calorimetry (DSC), in which the catalytic effects of pure LiBH4 and coated LiBH4 were compared, and indicated that the coating does not decrease the reactivity of LiBH4. It is suggested that surface coating with some inert materials is a simple and effective method for improving the storage and performance of LiBH4, while ensuring its reactivity.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 134-151
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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