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Tytuł:
Analiza środowiskowa warunków topienia brązów aluminiowych
Environmental Analysis for the Melting of Aluminum Bronzes Process
Autorzy:
Schlafka, P.
Bydałek, A. W.
Bydałek, A.
Powiązania:
https://bibliotekanauki.pl/articles/379809.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
topienie metali
analiza termiczna
właściwości
melting metals
thermal analysis
properties
Opis:
W artykule przedstawiona zostanie analiza środowiskowych oddziaływań żużlowych powłok rafinujących w warunkach topienia brązów aluminiowych. Zostaną pokazane analizy termiczno-różnicowe analizowanych powłok rafinacyjnych. Przeprowadzona zostanie analiza powstających produktów.
Not yet been clarified issues impact the individual components of slag refining. This applies to impacts on the process of mass transfer and the environment. For these ingredients include substances of stimulating the process of refining slag. The aim of the present study was to show the possibility of optimizing the components of the slag, through the use of stimulating substances intentionally introduced in the conditions of melting aluminum bronzes conditions. The analysing of the studied refiners compositions at an angle of environmental impacts noted a significant impact promoters containing sodium fluoride. Changes refining effect (on the plus side), however cause significant environmental burden. As evidenced by the results presented in Table 5 it follows that not only a fluorine leak out of the slag, but also react with the compounds of silicon and calcium. Compounds of fluorine therefore create a risk to the ambient gas in foundries. To the detriment of chloride NaCl speaks while the formation of water-soluble compounds which may pose a risk to groundwater. However, this can be countered through special bulkheads for storage of waste slag. We conclude that under the conditions of melting aluminum bronzes should be used slags containing no fluorine compounds.
Źródło:
Archives of Foundry Engineering; 2014, 14, 2 spec.; 71-76
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of AlSi9Cu3 Alloy Crystallization Process with Increased Iron Content at Different Number of Remelts
Autorzy:
Matejka, M.
Bolibruchova, D.
Kasińska, J.
Kuriš, M.
Powiązania:
https://bibliotekanauki.pl/articles/380082.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Al-Si-Cu
remelting
thermal analysis
structural analysis
przetapianie
analiza termiczna
analiza strukturalna
Opis:
Monitoring the solidification process is of great importance for understanding the quality of the melt, for controlling it, and for predicting the true properties of the alloy. Solidification is accompanied by the development of heat, the magnitude of which depends on the different phases occurring during solidification. Thermal analysis is now an important part of and tool for quality control, especially when using secondary aluminium alloys in the automotive industry. The effect of remelting on the change of crystallization of individual structural components of experimental AlSi9Cu3 alloy was determined by evaluation of cooling curves and their first derivatives. Structural analysis was evaluated using a scanning electron microscope. The effect of remelting was manifested especially in nucleation of phases rich in iron and copper. An increasing number of remelts had a negative effect after the fourth remelting, when harmful iron phases appeared in the structure in much larger dimensions.
Źródło:
Archives of Foundry Engineering; 2020, 20, 1; 79-83
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Thermal Degradation of Starch-Based Binder by TG-DTG-DSC, Py-GC/MS and DRIFTS
Autorzy:
Kaczmarska, K.
Żymankowska-Kumon, S.
Grabowska, B.
Bobrowski, A.
Cukrowicz, S.
Powiązania:
https://bibliotekanauki.pl/articles/379964.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
foundry binders
starch-based binder
thermal analysis
thermal decomposition
spoiwa odlewnicze
analiza termiczna
rozkład termiczny
Opis:
This paper focuses on the thermal behavior of the starch-based binder (Albertine F/1 by Hüttenes-Albertus) used in foundry technology of molding sand. The analysis of the course of decomposition of the starch material under controlled heating in the temperature range of 25- 1100°C was conducted. Thermal analysis methods (TG-DTG-DSC), pyrolysis gas chromatography coupled with mass spectrometry (Py- GC/MS) and diffuse reflectance spectroscopy (DRIFT) were used. The application of various methods of thermal analysis and spectroscopic methods allows to verify the binder decomposition process in relation to conditions in the form in both inert and oxidizing atmosphere. It was confirmed that the binder decomposition is a complex multistage process. The identification of CO2 formation at set temperature range indicated the progressive process of decomposition. A qualitative evaluation of pyrolysis products was carried out and the course of structural changes occurring in the presence of oxygen was determined based on thermo-analytical investigations the temperature of the beginning of binder degradation in set condition was determined. It was noticed that, significant intensification of Albertine F/1 sample decomposition with formation of more degradation products took place at temperatures above 550ºC. Aromatic hydrocarbons were identified at 1100ºC.
Źródło:
Archives of Foundry Engineering; 2019, 4; 21-26
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the compounds from the BTEX group, emitted during thermal decomposition of alkyd resin
Autorzy:
Kubecki, M.
Holtzer, M.
Bobrowski, A.
Dańko, R.
Grabowska, B.
Żymankowska-Kumon, S.
Powiązania:
https://bibliotekanauki.pl/articles/380216.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
masa formierska
wiązanie
BTEX
analiza termiczna
GC-MS
moulding sand
binding
thermal analysis
Opis:
Suitability of the given binding agent for the moulding sands preparation depends on the one hand on the estimation of technological properties of the sand and the mould made of it and the obtained casting quality and on the other hand on the assessment of this sand influence on the natural and working environment. Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. If in the initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin (phenol-formaldehyde, urea, furfuryl, urea-furfuryl, alkyd) under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAH) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX group. An emission of these components constitutes one of the basic criteria of the harmfulness assessment of binders applied for moulding and core sands. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 5000C - 13000C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. Within investigations the minimal amount of adsorbent necessary for the adsorption of compounds released during the decomposition of the resin sample of a mass app. 15 mg was selected. Also the minimal amount of solvent needed for the desorption of compounds adsorbed in the column with adsorbent was found. The temperature range, in which the maximal amounts of benzene, toluene, ethylobenzene and xylenes are released from the resin, was defined. The qualitative and quantitative analyses of compounds from the BTEX group were performed by means of the gas chromatography combined with the mass spectrometry (GC/MS).
Źródło:
Archives of Foundry Engineering; 2012, 12, 3; 69-74
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocena jakości metalurgicznej żeliwa sferoidalnego w oparciu o analizę termiczną ATAS
Rating Metallurgical Quality Ductile Iron Based on Thermal Analysis ATAS
Autorzy:
Ronduda, M.
Zaczyński, A.
Schmalenberg, K.
Powiązania:
https://bibliotekanauki.pl/articles/382827.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
analiza termiczna
żeliwo sferoidalne
system ATAS
thermal analysis
spheroidal cast iron
ATAS system
Opis:
Przedstawiono dwie metody oceny stabilności jakości metalurgicznej ciekłego metalu podczas przetrzymywania stopu w piecu, sferoidyzacji i modyfikacji. Powszechnie stosowane prowadzenie procesu metalurgicznego bazuje się na doborze tworzywa o określonym równoważniku węglowym CE z wykorzystaniem wyników analizy spektralnej składu chemicznego stopu. Wprowadzenie analizy termicznej pozwoliło na procesowy monitoring on-line wykorzystujący aktywny równoważnik węglowy ACEL. Zastosowana analiza termiczna (system ATAS) umożliwiła uzyskanie większej stabilności procesowej otrzymywania odlewów z żeliwa sferoidalnego bez porowatości skurczowej.
There were presented two methods to estimate the liquid cast iron metallurgical quality stability, during casting alloy’s furnace processing, spheroidization and modification. Commonly used metallurgical process handling was based on choice of the material with specified carbon equivalent (CE), basing on spectroanalysis. On the other hand thermoanalysis has enabled the „on-line” process monitoring, with the use of active carbon equivalent ACEL. Thermoanalysis applied (the ATAS system) allowed to achieve better process stability of nodular cast iron and castings without shrinkage porosity.
Źródło:
Archives of Foundry Engineering; 2015, 15, 4 spec.; 103-108
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Reclamation Process of the Spent Moulding Sand with the Polymer BioCo2 Binder
Autorzy:
Grabowska, B.
Łucarz, M.
Kaczmarska, K.
Powiązania:
https://bibliotekanauki.pl/articles/382132.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spent sand
polymeric binder BioCo
thermal analysis
thermal reclamation
thermal reclaimer
zużyta masa
spoiwo polimerowe BioCo
analiza termiczna
rekultywacja
Opis:
The results of the thermal reclamation investigations of the spent moulding sand with the polymer BioCo2 binder, are presented in the paper. The reclamation process of the quartz matrix was carried out on the basis of the author's own method of selecting the reclamation temperature. On the bases of the performed thermo-gravimetric analysis of the binder the temperature range required for the efficient thermal reclamation was indicated. In order to confirm the assumption the thermal reclamations were performed at a temperature determined by the TG and - for comparisons - at a lower and higher temperature. During the reclamation process samples of the reclaim were taken for testing ignition losses in order to determine the process efficiency. The correctness of the assumed method of selecting the temperature range of the thermal reclamation of spent moulding sand with the polymer BioCo2 binder was confirmed.
Źródło:
Archives of Foundry Engineering; 2014, 14, 3 spec.; 90-94
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Analysis in the Technological “Step” Test of H282 Nickel Alloy
Autorzy:
Pirowski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/382213.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nickel alloy
superalloy
step test
thermal analysis
stop niklu
superstop
test krokowy
analiza termiczna
Opis:
Superalloys show a good combination of mechanical strength and resistance to surface degradation under the influence of chemically active environments at high temperature. They are characterized by very high heat and creep resistance. Their main application is in gas turbines, chemical industry, and in all those cases where resistance to creep and the aggressive corrosion environment is required. Modern jet engines could never come into use if not for progress in the development of superalloys. Superalloys are based on iron, nickel and cobalt. The most common and the most interesting group includes superalloys based on nickel. They carry loads at temperatures well in excess of the eighty percent of the melting point. This group includes the H282 alloy, whose nominal chemical composition is as follows (wt%): Ni - base, Fe - max. 1.5%, Al - 1.5% Ti - 2.1%, C - 0.06% Co - 10% Cr - 20% Mo - 8.5%. This study shows the results of thermal analysis of the H282 alloy performed on a cast step block with different wall thickness. Using the results of measurements, changes in the temperature of H282 alloy during its solidification were determined, and the relationship dT / dt = f (t) was derived. The results of the measurements taken at different points in the cast step block allowed identifying a number of thermal characteristics of the investigated alloy and linking the size of the dendrites formed in a metal matrix (DAS) with the thermal effect of solidification. It was found that the time of solidification prolonged from less than one minute at 10 mm wall thickness to over seven minutes at the wall thickness of 44 mm doubled the value of DAS.
Źródło:
Archives of Foundry Engineering; 2015, 15, 1; 87-92
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Peritectic Determination by a Melt Deck Thermal Analysis System
Autorzy:
Tuttle, R. B.
Powiązania:
https://bibliotekanauki.pl/articles/382534.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermal analysis
solidification
continuous casting
peritectic reaction
analiza termiczna
krzepnięcie
odlewanie ciągłe
reakcja perytektyczna
Opis:
There has been a growing interest in the peritectic due to increasing productivity, quality, and alloy development. Differential scanning calorimetry (DSC) has traditionally been used to study steel solidification but suffers significant limitations when measuring the solidus and peritectic. This work covers a new thermal analysis system that can characterize the peritectic reaction. Heats of AISI/SAE 1030 and 4130 steel were poured to provide some benchmarking of this new technique. The peritectic was detected and the reaction temperature measured. Measurements agree reasonably well with reference information. A review of the literature and thermodynamic calculations did find some disagreement on the exact temperatures for the peritectic and solidus. Some of this difference appears to be related to the experimental techniques employed. It was determined that the system developed accurately indicates these reaction temperatures. The system provides a unique method for examining steel solidification that can be employed on the melt deck.
Źródło:
Archives of Foundry Engineering; 2019, 1; 83-88
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the Atmosphere on the Type of Evolved Gases from Phenolic Binders
Autorzy:
Żymankowska-Kumon, S.
Kaczmarska, K.
Grabowska, B.
Bobrowski, A.
Cukrowicz, S.
Powiązania:
https://bibliotekanauki.pl/articles/383144.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
resin
emission
atmosphere
thermal analysis
ochrona środowiska
żywica
emisja
atmosfera
analiza termiczna
Opis:
The problem of harmful casting resins has been present in foundries for many years. Manufacturers are introducing new products that contain in their composition environmentally and eco-friendly ingredients. Unfortunately, not all types of technology can be used, sometimes environmental benefits are disproportionate to the quality of castings and their price. In the foundry industry, the most popular binders are based on organic compounds (often carcinogenic) and other harmful substances. Due to strict legal regulations regarding environmental protection, as well as care for the foundry's workers' comfort - their occurrence should be reduce to a minimum. These compounds often behave also depending on the conditions of use (temperature, atmosphere). The application of various methods of thermal analysis and spectroscopic methods allows to verify the mechanism of resin decomposition process in relation to conditions in the form in both inert and oxidizing atmosphere. For analysis the resins from cold-box technology, were used TG–DTG–DSC, Py-GC/MS methods and specified the course of changes occurring in combination of different atmosphere.
Źródło:
Archives of Foundry Engineering; 2020, 20, 1; 31-36
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rule of the fluoride stymulators in to the Carbo-N-Ox method during aluminium bronze melting process
Autorzy:
Bydałek, A. W.
Schlafka, P.
Powiązania:
https://bibliotekanauki.pl/articles/379535.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
refining
stimulator
slag
thermal analysis
copper alloy
rafinacja
stymulator
żużel
analiza cieplna
stop miedzi
Opis:
During the slag refining process, in the real systems, the complex processes of mass exchange appear. Some relations between the stimulators in the environment - slag - metal system allow to initiate mass exchange reactions in the process of slag refining. Due to this kind of influences there is a possibility of direction and control of melting copper and it’s alloys.
Źródło:
Archives of Foundry Engineering; 2013, 13, 3; 15-18
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure and properties investigation of MCMgAl12Zn1 magnesium alloy
Autorzy:
Dobrzański, L. A.
Król, M.
Powiązania:
https://bibliotekanauki.pl/articles/380517.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermal analysis
microstructure
mechanical properties
magnesium alloy
analiza termiczna
mikrostruktura
właściwości mechaniczne
stop magnezu
Opis:
This work presents an influence of cooling rate on crystallization process, structure and mechanical properties of MCMgAl12Zn1 cast magnesium alloy. The experiments were performed using the novel Universal Metallurgical Simulator and Analyzer Platform. The apparatus enabled recording the temperature during refrigerate magnesium alloy with three different cooling rates, i.e. 0.6, 1.2 and 2.4ºC/s and calculate a first derivative. Based on first derivative results, nucleation temperature, beginning of nucleation of eutectic and solidus temperature were described. It was fund that the formation temperatures of various thermal parameters, mechanical properties (hardness and ultimate compressive strength) and grain size are shifting with an increasing cooling rate.
Źródło:
Archives of Foundry Engineering; 2013, 13, 1; 9-14
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Thermal Reclamation Temperature on the Strength of the Moulding Sand Made of the Reclaim in the Hot-box Technology
Autorzy:
Łucarz, M.
Grabowska, B.
Powiązania:
https://bibliotekanauki.pl/articles/380159.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spent sand
thermal analysis
thermal reclamation
thermal reclaimer
hot-box technology
usuwanie piasku
analiza termiczna
regeneracja termiczna
technologia hot-box
Opis:
The results of the thermal reclamation investigations of the spent moulding sand with the Ekotec 35 binder, are presented in the paper. The reclamation process of the quartz matrix was carried out on the basis of the author's own method of selecting the reclamation temperature. On the bases of the performed thermo-gravimetric analysis of the binder the temperature range required for the efficient thermal reclamation was indicated. In order to confirm the assumption the thermal reclamations were performed at a temperature determined by the TG and - for comparisons - at a lower and higher temperature. During the reclamation process samples of the reclaim were taken for testing ignition losses in order to determine the process efficiency. The correctness of the assumed method of selecting the temperature range of the thermal reclamation of spent moulding sand with the Ekotec 35 binder was confirmed.
Źródło:
Archives of Foundry Engineering; 2015, 15, 1 spec.; 131-135
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies of the Thermal Degradation of the BioCo3 Polymer Binder
Badania degradacji termicznej spoiwa polimerowego BioCo3
Autorzy:
Grabowska, B.
Grabowski, G.
Olejnik, E.
Kaczmarska, K.
Powiązania:
https://bibliotekanauki.pl/articles/381155.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
polymer binder
foundry sand
thermal analysis
TG-DSC
thermal degradation
spoiwo polimerowe
masa formierska
analiza termiczna
degradacja termiczna
Opis:
The basic research included a thermal analysis of the BioCo3 polymer binder in the form of a water-based poly(sodium acrylate)/dextrin composition to determine the temperature range in which this binder does not degrade and hence does not lose its binding properties in the binder/matrix system. The thermal decomposition was proven to be complex and to occur in multiple stages. It was found that as the temperature rises, physical and chemical changes take place in the binder as a result of the solvent water (20-100°C) and then of the structural water evaporating, and finally of intermolecular dehydration reactions (100-220°C) Mainly reversible processes occur within this temperature range. Within the temperature range of 220-300°C, polymer chains decompose, which includes the disintegration of side groups and glycoside bonds. Between 300 and 500°C, the polymer composition decomposes producing with gaseous destruction products, including mainly small-molecule inorganic compounds (CO2, H2O, CO) and organic ones (hydrocarbons). The part of the mass which has not decomposed at the temperature of about 550°C may contain carbonised carbon.
Badania podstawowe obejmowały analizę termiczną spoiwa polimerowego BioCo3 w postaci wodnej kompozycji poli(akrylan sodu)/dekstryna, która umożliwiła ustalenie zakresu temperatury, w jakim nie ulega ono degradacji, przez co nie traci swoich właściwości wiążących w układzie spoiwo-osnowa. Wykazano, że przebieg termicznego rozkładu jest złożony i wieloetapowy. Stwierdzono, że wraz ze wzrostem temperatury w spoiwie dochodzi do zmian fizycznych i chemicznych związanych z odparowywaniem wody rozpuszczalnikowej (20-100°C), następnie wody konstytucyjnej i wreszcie z reakcjami dehydratacji intermolekularnej (100-220°C). W tym zakresie temperatury zachodzą głównie procesy odwracalne. W zakresie temperatury 220-300°C dochodzi do dekompozycji łańcuchów polimerowych, w tym rozpadu grup bocznych i wiązań glikozydowych. W zakresie temperatury 300-500°C następuje rozkład kompozycji polimerowej z powstawaniem gazowych produktów destrukcji, w tym przede wszystkim małocząsteczkowych związków nieorganicznych (CO2, H2O, CO) i organicznych (węglowodory). Część masy, która nie uległa rozkładowi w temperaturze około 550°C może zawierać skarbonizowany węgiel.
Źródło:
Archives of Foundry Engineering; 2013, 13, 1 spec.; 27-30
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
TG/DTG/DTA, FTIR and GC/MS Studies of Oil Sand for Artistic and Precision Foundry with the Emission of Gases Assessment
Autorzy:
Bobrowski, A.
Żymankowska-Kumon, S.
Drożyński, D.
Grabowska, B.
Kaczmarska, K.
Powiązania:
https://bibliotekanauki.pl/articles/382154.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
molding sand
thermal analysis
emission of gases
FTIR
GC/MS
masa formierska
analiza termiczna
emisja gazowa
Opis:
The paper presents the results of thermoanalytical studies by TG/DTG/DTA, FTIR and GC/MS for the oil sand used in art and precision foundry. On the basis of course of DTG and DTA curves the characteristic temperature points for thermal effects accompanying the thermal decomposition reactions were determined. This results were linked with structural changes occurred in sample. It has been shown that the highest weight loss of the sample at temperatures of about 320°C is associated with destruction of C-H bonds (FTIR). In addition, a large volume of gases and high amounts of compounds from the BTEX group are generated when liquid metal interacts with oil sand. The results show, that compared to other molding sands used in foundry, this material is characterized by the highest gaseous emissions and the highest harmfulness, because benzene emissions per kilogram of oil sand are more than 7 times higher than molding sand with furan and phenolic binders and green sand with bentonite and lustrous carbon carrier.
Źródło:
Archives of Foundry Engineering; 2017, 17, 4; 25-30
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Analysis of the ZnAl10 Alloy Modified by Ti Additions in AlTi5C0.15 and ZnTi3.2 Inoculants
Autorzy:
Piwowarski, G.
Buraś, J.
Krajewski, W. K.
Krajewski, P. K.
Powiązania:
https://bibliotekanauki.pl/articles/383098.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
alloy ZnAl
grain refinement
thermal analysis
inoculants
modified by Ti
stop ZnAl
ziarna
analiza termiczna
modyfikatory
Opis:
Cast alloys on the Zn matrix and of an increased Al content are characterised by good technological and mechanical properties, due to which they should meet special, more demanding requirements. However, the basic problem in these alloys technology, apart from a high tendency for gases pick-up and oxidation of liquid metals, is a tendency to form coarse-grained dendritic structures in castings solidifying in sand moulds, what - in turn - unfavourably influences their plastic properties [1, 2, 7, 11]. Therefore several treatments aimed at obtaining fine-grained structure and improving plastic properties are applied in these alloys technology. The presented study concerns the modification process of binary, middle-aluminium Zn alloys performed by additions of inoculants containing titanium and investigations of these modifications influence on the structure refinement degree. The Zn-10wt% Al (ZnAl10) alloy modified, before pouring into a sand mould, either by addition of the traditional inoculant i.e. Al-3wt% Ti-0.15wt% C (AlTi3C0.15 – TiCAl) or the new inoculant Zn-3.2wt% Ti (ZnTi3.2) was tested. Within investigations the thermal analysis was performed, especially cooling curves and their first derivatives, and also measurements by means of the differential scanning calorimetry (DSC), with a purpose of determining the modification influence on undercooling degree changes. Microstructures of the tested alloy were observed by the light microscopy (LM). The applied modification of middle-aluminium zinc alloys by AlTi3C0.15 and ZnTi3.2 inoculants causes a significant refinement of the alloy structure. Inoculants applied in investigations have a strong nucleating activity, which is confirmed by decreasing of undercooling and the temperature recalescence in cooling curves, which occurs simultaneously with grain refinements.
Źródło:
Archives of Foundry Engineering; 2014, 14, 4 spec.; 101-106
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 46

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