Temat: 61.50.Nw - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Structure Refinement of the Semiconducting Compound $Cu_3TaS_4$ from X-Ray Powder Diffraction Data
Autorzy:: Delgado, G.
Contreras, J.
Mora, A.
Durán, S.
Muñoz, M.
Grima-Gallardo, P.
Powiązania:: https://bibliotekanauki.pl/articles/1493612.pdf
Data publikacji:: 2011-09
Wydawca:: Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:: 61.50.Nw
61.66.Fn
Opis:: The ternary compound $Cu_{3}TaS_{4}$ has been investigated by means of X-ray powder diffraction and its structure has been refined by the Rietveld method. This compound is isostructural with the sulvanite mineral $Cu_{3}VS_{4}$, and crystallizes in the cubic $P \bar{4} 3m$ space group (No. 215), Z = 1, with unit cell parameters a = 5.5145(1) Å and V = 167.70(1) $Å^{3}$. The refinement of 14 instrumental and structural parameters converged to $R_{p}$ = 4.4%, $R_{wp}$ = 6.8%, $R_{exp}$ = 5.5% and S = 1.2 for 4501 step intensities and 33 independent reflections.
Źródło:: Acta Physica Polonica A; 2011, 120, 3; 468-472
0587-4246
1898-794X
Pojawia się w:: Acta Physica Polonica A
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: Influence of Nonstoichiometry on Magnetocaloric Effect in $(La_{0.7}Ca_{0.3})_{1 - x}Mn_{1+x}O_3$
Autorzy:: Sazanovich, A.
Pietosa, J.
Pashchenko, A.
Zubov, E.
Dyakonov, V.
Szymczak, H.
Powiązania:: https://bibliotekanauki.pl/articles/1419814.pdf
Data publikacji:: 2012-07
Wydawca:: Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:: 75.30.Sg
61.50.Nw
65.40.gd
Opis:: Magnetocaloric effect in $(La_{0.7}Ca_{0.3})_{1 - x}Mn_{1 + x}O_3$ manganites with x = 0, 0.1, 0.2 has been investigated. It is found a strong influence of nonstoichiometry caused by excessive manganese on the magnetic entropy change. The magnetocaloric effect was evaluated from the isothermal curves of spontaneous magnetization versus the applied magnetic field by using the well-known thermodynamical Maxwell relation. The maximum entropy value, $| \Delta S_{M}^\text{max} |,$ near the ferromagnetic-paramagnetic phase transition is shown to increase with the manganese content. The $La_{0.56}Ca_{0.24}Mn_{1.2}O_3$ manganite exhibits the largest $| \Delta S_{M}^\text{max} |$ value equal to $3.09 J kg^{-1} K^{-1}$ at 15 kOe near $T_{C}$ = 267 K. The magnetocaloric effect values obtained allow to propose that the studied manganites are promising materials for future cooling application.
Źródło:: Acta Physica Polonica A; 2012, 122, 1; 162-166
0587-4246
1898-794X
Pojawia się w:: Acta Physica Polonica A
Dostawca treści:: Biblioteka Nauki

Artykuł

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