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Wyszukujesz frazę "Arulkumaran, R." wg kryterium: Autor


Tytuł:
Aryl Chalcones as Efficient Precursors for Deriving Oxazine: Solvent-free Synthesis and Antimicrobial Activities of some Oxazine-2-amines
Autorzy:
Thirunarayanan, G.
Sundararajan, R.
Arulkumaran, R.
Powiązania:
https://bibliotekanauki.pl/articles/411627.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxazine amines
Chalcones
fly-ash
H2SO4
Environmentally benign reaction
antimicrobial activities
Opis:
A series of some oxazine derivatives has been synthesised by fly-ash:H2SO4 catalyzed solvent-free cyclization of aryl chalcones and urea under microwave irradiation. The yields of the oxazines were more than 85 %. The synthesised oxazines were characterized by their physical constants, analytical and spectroscopic data. The antimicrobial activities of these oxazines have been studied using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 82-97
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Hammett spectral correlation studies of some substituted cyanopyridine compounds
Autorzy:
Arulkumaran, R.
Manikandan, V.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1179260.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Hammett constants
IR and NMR spectra
Single and multi-correlation analysis
Substituted cyanopyridine
Opis:
About ten substituted cyanopyridine compounds have been synthesized and the purities of these pyridines were examined with their physical constants, analytical and spectroscopic data provided in the literature. They are characteristic infrared stretches and NMR chemical shifts were assigned and they are correlated with Hammett substituent constants using single and multi-linear regression analysis. From the results, the effect of substituents on the spectral data of cyanopyridine has been discussed.
Źródło:
World Scientific News; 2017, 80; 239-255
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines
Autorzy:
Arulkumaran, R.
Manikandan, V.
Christuraj, P.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1182844.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(e)-1-benzylidene-2-(diphenylmethylene) hydrazine
ir and nmr spectra
hammett correlations
Opis:
About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.
Źródło:
World Scientific News; 2017, 62; 93-110
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hammett spectral LFER of some antioxidant substituted benzylidene hydrazines
Autorzy:
Thirunarayanan, G.
Manikandan, V.
Arulkumaran, R.
Rajarajan, M.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1182556.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-(2
5-dinitrophenyl)-2-(substituted benzylidene)hydrazines
Hammett correlations
IR spectra
NMR spectra
antioxidant activity
hydroxy apatite
Opis:
About nine (E)-(2,5-dinitrophenyl)-2-(substituted benzylidene)hydrazines have been synthesized by hydroxy apatite catalyzed condensation of 2,4-dinitrophenyl hydrazine and substituted benzaldehydes under microwave irradiation conditions. The obtained yields of these hydrazines are more than 85%. The purities of synthesized hydrazines are examined by the analytical and spectroscopic data reported earlier. The infrared spectral C=N, NH frequencies (v, cm-1) and the NMR spectral chemical shifts of CH, NH protons and carbons are assigned and are correlated with Hammett substituent constants, F and R parameter using single and multi-regression analysis. From the results of statistical analysis the effects of substituent on the group frequencies have been discussed. The antioxidant activities of these synthesized hydrazines were measured using DPPH radical scavenging method. The hydroxy- and methoxy- substituted hydrazines shows significant antioxidant activity.
Źródło:
World Scientific News; 2017, 69; 201-219
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Hammett spectral QSAR analysis of some (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
Autorzy:
Vijayakumar, S.
Manikandan, V.
Arulkumaran, R.
Christuraj, P.
Sundararajan, R.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1076503.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
IR
NMR spectra
QSAR study
UV
regression analysis
Opis:
About nine substituted (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones have been synthesized by solvent-free method. These enones were analyzed by spectral techniques. The characteristic spectral frequencies were correlated through Hammett equation with Hammett substituent constants, F and R parameters using single and multi-regression analysis method. From the statistical analysis results, the quantitative structure activity relationships have been discussed by means of effects of substituents on the spectral frequencies.
Źródło:
World Scientific News; 2019, 115; 52-67
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
IR and 1H NMR spectral studies of some 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamides: Assessment of substituent effects
Autorzy:
Arulkumaran, R.
Sundararajan, R.
Manikandan, V.
Sathiyendiran, V.
Pazhamalai, S.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412343.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamides
IR spectra
NMR spectra
substituent effects
Opis:
A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and 1HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 19, 1; 15-25
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infrared and 13C NMR Spectral Correlation Analysis of Some Substituted Oxazepin Based Ketone and Thione Derivatives with Hammett Constant
Autorzy:
Sathiyamoorthi, K.
Kamalakkannan, D.
Suresh, R.
Sakthinathan, S. P.
Arulkumaran, R.
Sundararajan, R.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1193044.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxazepins
IR
13C NMR
Hammett constant
F and R parameter
Single and multi-regression analysis
Opis:
Single and multi-regression analysis was applied for the corrosion study of transmission of substituent effects on IR carbonyl stretching frequencies and 13C chemical shifts of some substituted oxazepin compounds. The substituent effects were estimated on the basis of results of the statistical analysis. The differences among the obtained regression coefficients were discussed in terms of the relative importance of the field, inductive and resonance effects of substituent.
Źródło:
World Scientific News; 2016, 58; 48-64
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and effects of substituent on (E)-styryl-3-methyl-2-thienyl chalcones
Autorzy:
Christuraj, P.
Geetha, C.
Vanangamudi, G.
Arulkumaran, R.
Manikandan, V.
Rajakumar, P. R.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1161056.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones
FT-IR & NMR spectra
Fly-ash:H3PO4 nanocatalyst
Hammett correlation analysis
Substituent effects
UV
solvent-free synthesis
Opis:
Series of eleven substituted of (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones compounds by cross-aldol condensation reaction of 3-methylthiophene-2-carbaldehyde with various substituted acetaldehyde in the occurrence of Fly-Ash: H3PO4 catalyst. The effect of catalytic activity of this fly-ash:H3PO4 nanocatalyst was studied with the obtained yield of products under solvent-free conditions. The synthesized substituted (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The infrared group frequencies of ʋ(cm-1) of COs-cis & s-trans, CHip and CHop, CH=CHop, >C=C
Źródło:
World Scientific News; 2018, 112; 55-73
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral correlations and antimicrobial activities of some 1-pyrenyl chalcones
Autorzy:
Arulkumaran, R.
Vijayakumar, S.
Sundararajan, R.
Sakthinathan, S.P.
Kamalakkannan, D.
Suresh, R.
Ranganathan, K.
Rajakumar, P.R.
Powiązania:
https://bibliotekanauki.pl/articles/411776.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 1-pyrenyl ketones
UV spectra
IR spectra
NMR spectra
substituent effects
antimicrobial activities
Opis:
A series of 1-pyrenyl chalcones have been synthesized by Crossed-Aldol condensation of 1-acetylpyrene and substituted benzaldehydes. The purities of these chalcones have been checked by their physical constants, UV, IR, NMR and MASS spectral data. The spectral data of these chalcones have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral group frequencies have been discussed. The anti-microbial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 5; 21-38
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectral correlation studies of some (E)-N′-1-(substituted benzylidene) benzohydrazides
Autorzy:
Manikandan, V.
Balaji, S.
Senbagam, R.
Vijayakumar, R.
Rajarajan, M.
Vanangamudi, G.
Arulkumaran, R.
Sundararajan, R.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1162032.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-N’-1-(substituted benzylidene) benzohydrazides
IR and NMR spectra and Correlations
UV
Opis:
About ten substituted (E)-N’-1-(substituted benzylidene) benzohydrazides have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. The effects of substituent on these data have been studied using Hammett equation.
Źródło:
World Scientific News; 2018, 111; 26-39
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thionylchloride catalyzed aldol condensation: Synthesis, spectral correlation and antibacterial activities of some 3,5-dichloro-2-hydroxyphenyl chalcones
Autorzy:
Arulkumaran, R.
Vijayakumar, S.
Sundararajan, R.
Sakthinathan, S. P.
Kamalakkannan, D.
Suresh, R.
Ranganathan, K.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/411825.pdf
Data publikacji:
2012
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
chlorek tionylu
widma IR i NMR
korelacja Hammeta
aktywność antybakteryjna
wpływ podstawników
styrylo 3,5-dichloro-2-hydroksy fenylo ketony
thionyl chloride
styryl 3,5-dichloro-2-hydroxyphenyl ketones
IR and NMR spectra
Hammett correlation
substituent effects
antimicrobial activities
Opis:
A series of substituted styryl 3,5-dichloro-2-hydroxyphenyl ketones [1-(3, 5-dichloro-2-hydroxy)- 3-phenylprop-2-en-1-one] were synthesized using thionyl chloride assisted Crossed Aldol reaction. The yields of chalcones were more than 80%. The synthesized chalcones were characterized by analytical and spectroscopic data. From the spectroscopic data the group frequencies were correlated with Hammett substituent constants, F and R parameters. From the results of statistical analysis the effect of substituents were discussed. The antibacterial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2012, 4; 17-38
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral correlations in some substituted styryl (E)-4-((2-oxopropyl) diazenyl) benzoic acids
Autorzy:
Sathiyendiran, V.
Sekar, K. G.
Thirunarayanan, G.
Arulkumaran, R.
Sundararajan, R.
Kamalakkannan, D.
Suresh, R.
Manikanadan, V.
Vijayakumar, R.
Vanangamudi, G.
Powiązania:
https://bibliotekanauki.pl/articles/412199.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxo-propyl diazenyl benzoic acid chalcones
IR spectra
NMR spectra
Hammett equation
Regression analysis
Opis:
A series of titled compounds were prepared and analyzed their purities by literature method. The infrared and NMR spectral group frequencies of the compounds were assigned and correlated with Hammett substituent constants, F and R constants using single and multi linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral frequencies was discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 33-43
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrochemical reduction potential correlation of some insect antifeedant potent 2-phenothiazinyl chalcones
Autorzy:
Ranganathan, K.
Suresh, R.
Kamalakkannan, D.
Arulkumaran, R.
Sundararajan, R.
Sakthinathan, S. P.
Vijayakumar, S.
Thirumurthy, K.
Mayavel, P.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/411842.pdf
Data publikacji:
2012
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
elektrochemia
potencjał redukcji
analiza korelacji
2-phenothiazenyl
chalkony
2-Phenothiazenyl chalcones
electrochemistry
reduction potential
correlation analysis
insect antifeedant activities
Opis:
A series containing twelve substituted styryl 2-phenothiazenyl ketones have been synthesized. The electrochemical potentials of carbonyl and vinyl groups were measured. These potentials are correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effects of substituent on the group reduction potentials have been discussed. The insect antifeedant activities of these chalcones have been studied using 4th instar larvae Achoea Janata L with castor leaf discs.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2012, 4; 66-75
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of substituent effects and antimicrobial activities of some 2ʹ,5ʹ-dimethyl phenyl chalcones
Autorzy:
Joseph, S. J.
Kamalakkannan, D.
Arulkumaran, R.
Sakthinathan, S. P.
Suresh, R.
Sundararajan, R.
Vijayakumar, S.
Ranganathan, K.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412597.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 2
5ʹ-dimethyl phenyl chalcones
UV spectra
IR spectra
NMR spectra
substituent effects
antimicrobial activities
Opis:
Some 2ʹ,5ʹ-dimethyl phenyl chalcones have been synthesized by Crossed-Aldol condensation between 2,5-dimethyl acetophenone and various substituted benzaldehydes using catalytic amount of sodium hydroxide and ethanol. The yields of the chalcones are more than 93 %. The purities of these chalcones have been checked by their physical constants, UV, IR, NMR and MASS spectral data. The spectral data of these chalcones have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed. The anti-microbial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 5; 99-123
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Insect antifeedant potent halogen substituted phenyl chalcones
Autorzy:
Sundararajan, R.
Arulkumaran, R.
Vijayakumar, S.
Kamalakkannan, D.
Suresh, R.
John, J. S.
Ranganathan, K.
Sakthinathan, S. P
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412081.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Substituted styryl 2′,3′,4′-trichlorophenyl ketones
sulfated Titania
IR and NMR spectra
Insect antifeedant activities
Opis:
Some 2′,3′,4′-trichlorophenyl chalcones [(E)-1-(2,3,4-trichlorophenyl)-3-(substituted phenyl)-2-propen-1-ones] have been synthesised using sulfated Titania catalyzed solvent-free aldol condensation between 2,3,4-trichloroacetophenone and substituted benzaldehydes. The purities of synthesised chalcones were checked by their analytical, physical and spectroscopic data reported in literature. The insect antifeedant activities of these chalcones have been studied using 4th instar larvae Achoea Janata L by castor leaf disc bio-assay method. The chloro substituted chalcones shows significant insect antifeedant activity.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 1; 67-73
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł

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