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Wyświetlanie 1-10 z 10
Tytuł:
Investigation of iron selectivity behavior of copper smelter slag flotation tailing with hematitization baking and base metals leaching methods
Autorzy:
Kart, Elif Uzun
Yazğan, Zeynep Hazal
Gümüşsoy, Aleyna
Powiązania:
https://bibliotekanauki.pl/articles/2146871.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
iron selectivity
hematitization baking
copper smelter slag flotation tailing
base metal leaching
Opis:
In this study, iron selectivity behaviour of copper smelter slag (CSS) flotation tailings (38.08% Fe, 0.35% Cu, 4.48% Zn, 0.16% Co, 0.37% S) having fayalite and magnetite as major minerals was investigated with hematitization baking and base metals leaching methods using mineralogical and chemical analyses. For selectivity of iron, it was baked at temperatures of 650-690-700-710-730°C. The aim of the baking is to transform the almost all of the iron in the fayalite into the oxidized (non-soluble) form and the base metals into the sulphated (soluble) form. The temperature that had the lowest hematitization rate of iron was found to be 650°C, and the highest temperature was found to be 730°C. To examine the dissolution behaviour of baked CSS flotation tailing was leached at 50°C at a 1/10 (w/v) for 1 hour by using water. After baking at 690°C calcine and leaching residue, S values were determinated to be approximately 17% and 9%, respectively. Baking made at 700⁰C, amount of sulfate also decreased to 10% and S content was measured as 4% of its leaching residue. As a result of this study, 690⁰C/700⁰C was determined as optimum conditions of hematitization baking and base metals were extracted selectively when the iron was remained at leaching residue in Fe2O3 phase. It was determined that, hematitization is high and the sulphates of the base metals are preserved at 700⁰C temperature. The fayalite phase completely decomposed into Si-O/Fe-O/Zn-S-O/Co-S-O compounds at 700⁰C baking which was the highest iron selective and base metals dissolute temperature.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 164--175
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of additives on heavy metal immobilization during vitrification of tannery sewage sludge
Autorzy:
Bień, J.
Celary, P.
Morzyk, B.
Sobik-Szołtysek, J.
Wystalska, K.
Powiązania:
https://bibliotekanauki.pl/articles/208067.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heavy metals
flotation
sewage sludge
vitrification
metal leaching
tannery sewages
metale ciężkie
flotacja
osady ściekowe
witryfikacja
odcieki
ługowanie metali
ścieki garbarskie
Opis:
The aim of this study was to evaluate the effect of additives such as waste moulding sands (WMS) and dolomite flotation waste (F) on heavy metal immobilization during vitrification of tannery sewage sludge. Sewage sludge with addition of waste moulding sands of 25-45 vol. % and flotation waste of 5-25 vol. % was used in the vitrification process. The study demonstrated a direct correlation between the WMS fraction in the vitrified formulations and heavy metal immobilization in the obtained vitrificates. Vitrification of sewage sludge with these additives resulted in obtaining vitreous products with reduced heavy metal leaching properties; the lowest content of heavy metals in the leachates was found in the vitrificates with the highest content of waste moulding sands.
Źródło:
Environment Protection Engineering; 2013, 39, 2; 33-40
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics and metal leachability of natural contaminated soil under acid rain scenarios
Autorzy:
Tan, Wenfa
Li, Yuan
Ding, Lei
Wang, Yachao
Li, Jiangxiang
Deng, Qinwen
Guo, Feng
Xiao, Xue
Powiązania:
https://bibliotekanauki.pl/articles/205435.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
heavy metal
soil pollution
fraction analysis
soil leaching
Opis:
Contamination of soil with heavy metals has become a worldwide environmental problem, and receives great attention. In this study, we aim to investigate soil pollution level affected by an industrial district nearby. The total amount of typical heavy metals in the soils (Hengyang Songmu Industrial Park, Hunan Province, China) was analyzed. In addition, the fraction analysis and laboratory simulation leaching via different pH rainwater was carried out to study the migration and transformation of heavy metals. The main results show that the contents of Cu, Zn, Pb, Cr and Cd in the samples were higher than the soil background values in Hunan Province. The heavy metals forms, analyzed by sequential extraction method, show that the proportion of the unstable form of Cd, Zn and Pb was more than 50%. Igeo values indicate that the heavy metal pollution degree of soil sample #5 at the investigated area is recorded in the order of Cd(6.42), Zn(2.28), Cu(1.82), Pb(1.63), and Cr(0.37). Cu, Zn, Pb, Cr and Cd in this area could pose a potential leaching risk to the environment which may affect the food chain and constitute a threat to human health. It would be necessary to take steps to stabilize and monitor the heavy metals in soil.
Źródło:
Archives of Environmental Protection; 2019, 45, 2; 91-98
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Exploitation of spent nickel-metal hydride (Ni-MH) batteries as a source of value-added products
Autorzy:
Farghal, Fatma E.
Abdel-Khalek, Mohamed A.
Powiązania:
https://bibliotekanauki.pl/articles/2146864.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
nickel–metal hydride
batteries
nickel
recovery
cementation
leaching
recycling
Opis:
Spent Nickel–metal hydride batteries can be sources of valuable metals such as nickel, cobalt, manganese, rare earths and toxic chemicals. The recycling of these materials is necessary from both economic and environmental points of view. In this study the nickel is leached in acid solution followed by precipitation and thermal decomposition or by cementation. The affecting parameters such as acid type and concentration, time, temperature and solid/liquid ratio were investigated. The maximum of leached nickel could be obtained in 3M sulfuric acid at 65°C for 60 min with solid-to-liquid ratio of 30 g L-1. The liquid film is a more suitable model for demonstrating the kinetics of the nickel leaching. Thermal decomposition of the precipitated nickel dimethyl-glyoxime was employed in preparation of nickel oxide. Nickel was separated from aqueous solution by cementation on zinc. The cementation process follows pseudo first-order kinetics and diffusion controlling steps. The yield was 91% of the original nickel content.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 6; 95--101
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct conversion of alkaline earth metal hydroxides and sulfates to carbonates in ammonia solutions
Autorzy:
Ehsani, Ilhan
Ehsani, Arman
Ucyildiz, Ayse
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/2146856.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline earth metal
ammonia leaching
direct conversion
dissolved carbonate
smithsonite
Opis:
In this study, the direct conversion behaviors of different alkaline earth metal solids (the hydroxides and the sulfates of alkaline earth metals Ca, Sr, Ba and Mg) to their corresponding carbonates in dissolved carbonate-containing pregnant solutions obtained by direct leaching of a smithsonite (ZnCO3) ore sample in aqueous ammonia solutions having different concentrations (4 M, 8 M and 13.3 M NH3) were investigated by using X-ray diffraction analyses at alkaline earth metal to dissolved carbonate mole ratios of 1:1 and 1:2, for revealing the conversion possibilities of dissolved carbonate in the pregnant solutions to solid carbonate by-products. The results of direct conversion experiments showed that Ca(OH)2, CaSO4•2H2O, Sr(OH)2•8H2O and Ba(OH)2•8H2O converted to their corresponding carbonates, SrSO4 partially converted to SrCO3 as observed by the presence of unreacted SrSO4 peaks in X-ray diffraction patterns of the converted solids, and BaSO4 did not convert to BaCO3 because of its lower solubility with respect to BaCO3. On the other hand, it was observed that Mg(OH)2 did not convert to MgCO3, but MgSO4•7H2O converted dominantly to an uncommon phase, which was tentatively identified as Mg5Zn3(CO3)2(OH)12•H2O. In the study, a complete discussion on the conversion behaviors of alkaline earth metal solids to their corresponding carbonates was given considering the differences between their solubility product constants and the changes in the free energies of the theoretical conversion reactions. In addition, infrared spectra and scanning electron microscope images of some of the converted solids were also presented for characterization purposes.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 169--180
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of Chemosorbent Based on Metallic Waste for Cleaning Mine Water from Molybdenum
Autorzy:
Isakov, A. E.
Matveeva, V. A.
Chukaeva, M. A.
Powiązania:
https://bibliotekanauki.pl/articles/125049.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
molybdenum
leaching
mine waters
hydrochemical anomaly
metal waste
chemical adsorbent
Opis:
The article presents the results of hydrochemical studies of water objects, located in the impact zone of one of the largest mining enterprises in the Russian Federation – JSC “Apatite”. According to the monitoring studies, the source of surface water pollution with molybdenum was determined, geochemical assessment of the molybdenum transformation in the system “ore-bearing rocks – mine water – surface water” was performed. In order to reduce the technogenic load on the surface water located in the considered area, the way of large-tonnage mine waters purification from molybdenum was proposed. The method involves using the chemical sorbent based on waste metals. The method of sewage purification will allow solving one of the key environmental problems of the considered enterprise and, in addition, to improve the environmental situation in the considered area as well as the quality of the local population life.
Źródło:
Journal of Ecological Engineering; 2018, 19, 1; 42-47
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Immobilizacja metali ciężkich w zawiesinach twardniejących z popiołami z termicznego przekształcania komunalnych osadów ściekowych w świetle dynamicznych badań krótkoterminowych
Immobilization of heavy metals in hardening slurries with ash from thermal treatment of municipal sewage sludge in the light of dynamic short-term research
Autorzy:
Kledyński, Z.
Wojtkowska, M.
Falaciński, P.
Szarek, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/392172.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
odpad komunalny
osad ściekowy
obróbka cieplna
wykorzystanie popiołu
metal ciężki
zawiesina twardniejąca
immobilizacja
wymywanie
municipal sewage
sewage sludge
thermal treatment
ash utilization
heavy metal
hardening slurry
immobilization
leaching
Opis:
Rosnąca liczba oczyszczalni ścieków komunalnych w Polsce, pożądanych z ekologicznego punktu widzenia, rodzi problem zagospodarowania rosnącej ilości osadów ściekowych. Metoda termicznego przekształcania osadów ściekowych, znacznie redukując objętość odpadu, powoduje wzrost koncentracji metali ciężkich w żużlu i popiołach – produktach końcowych procesu przekształcania. Z uwagi na specyficzne właściwości popiołu lotnego z termicznego przekształcania komunalnych osadów ściekowych (TPKOŚ), m.in. niską aktywność, wysoką wodożądność, wysoką zawartość fosforu i metali ciężkich, odpad ten jest trudny do szerszego zagospodarowania w przemyśle budowlanym. Poszukiwania metod utylizacji popiołu lotnego z TPKOŚ zaowocowały próbami wykorzystania go w zawiesinach twardniejących wykorzystywanych w budownictwie hydrotechnicznym, w realizacji przesłon przeciwfiltracyjnych. Ze względu na charakter pracy tego materiału w przesłonie (ekspozycja na przepływ filtracyjny wód gruntowych) jedną z kluczowych kwestii jest stopień związania w nim metali ciężkich.
The growing number of municipal sewage treatment plants in Poland, ecologically desirable, raises the problem of manaing more and more sludge. Among others legal regulations have contributed to dissemination of the sewage sludge thermal treatment method, which significantly reduces the volume of waste, results in an increase in the concentration of heavy metals in the slags and ashes – the final products of the transformation process. Due to the specific properties of fly ash from thermal treatment of municipal sewage sludge (TTMSS) such as: low activity, high water demand and high content of phosphorus and heavy metals, the waste is difficult to use in the construction industry. The search for methods of utilization of fly ash from TTMSS resulted in attempts to use it in hardening slurries used in hydrotechnical engineering, in the implementation of cut-off walls. Due to the nature of the application of this material in the cut=off walls (exposure to groundwater flow) one of the key issues is the degree of heavy metal immobilization. The paper attempted to determine the degree of leaching of selected heavy metals from the matrix of the hardened hardening slurry, composed of cement, bentonite and fly ash from TTMSS. For this purpose, the eluates were prepared from samples, after various periods of curing, using a dynamic short-term method called “Batch test”. The liquid used for leaching was: distilled water and 0.1 molar hydrochloric acid solution. The results show the possibility of the safe usage of fly ash TTMSS as an additive for hardening slurries. The proposed direction of using the fly ash from TTMSS is part of the broad policy of sustainable development and circular economy.
Źródło:
Prace Instytutu Ceramiki i Materiałów Budowlanych; 2017, R. 10, nr 30, 30; 79-92
1899-3230
Pojawia się w:
Prace Instytutu Ceramiki i Materiałów Budowlanych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enrichment fractions of trace metals in the five sludges collected from Pomerania
Wzbogacanie frakcji metali śladowych w osadach filtracyjnych Pomorza
Autorzy:
Janukowicz, H.
Wira, J.
Powiązania:
https://bibliotekanauki.pl/articles/84901.pdf
Data publikacji:
1999
Wydawca:
Akademia Pomorska w Słupsku
Tematy:
trace metal
sludge
Pomeranian region
filtration plant
determination
aluminium
silver
cadmium
manganese
zinc
lead
copper
tin
cobalt
nickel
iron
distribution
waste water sludge
leaching technique
Źródło:
Baltic Coastal Zone. Journal of Ecology and Protection of the Coastline; 1999, 03
1643-0115
Pojawia się w:
Baltic Coastal Zone. Journal of Ecology and Protection of the Coastline
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of metals from electronic waste by bacterial leaching
Autorzy:
Willner, J.
Fornalczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/208166.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
metal recovery
bioleaching
electronic scrap
electronic waste
Acidithiobacillus ferrooxidans
bacterial leaching
biohydrometallurgy
recovering metals
odzysk metali
bioługowanie
ługowanie bakteryjne
biohydrometalurgia
odzyskiwanie metali
złom elektroniczny
odpady elektroniczne
Opis:
Electronic waste is usually processed by means of classical methods, i.e. in pyro- and hydro-metallurgical processes. However, new solutions for more economically and ecologically efficient recovery of metals are constantly being searched for. Biohydrometallurgy can become a promising technology of recovering metals from industrial waste. Bioleaching - one of the methods applied in that technology - is the subject of particular interest of many scientific centres. The paper presents the results of laboratory tests of bacterial leaching of metals from electronic scrap. It describes the mechanisms of this process and the factors influencing the chemical reaction. The paper also presents preliminary results of experimental studies on the copper bioleaching from electronic waste with the participation of Acidithiobacillus ferrooxidans bacteria.
Źródło:
Environment Protection Engineering; 2013, 39, 1; 197-208
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wymywanie wybranych metali ciężkich z betonów zawierających popiół z termicznego przekształcania osadów ściekowych
Elution of selected heavy metals from concretes containing ashes produced in thermal conversion of sludge
Autorzy:
Wichowski, P.
Rutkowska, G.
Nowak, P.
Powiązania:
https://bibliotekanauki.pl/articles/40795.pdf
Data publikacji:
2017
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:
materialy budowlane
beton
beton C16/20
komponenty
popiol lotny z termicznego przeksztalcania osadow sciekowych
metale ciezkie
wymywanie pierwiastkow
building material
concrete
component
fly ash
sewage sludge
thermal conversion
heavy metal
element leaching
Źródło:
Acta Scientiarum Polonorum. Architectura; 2017, 16, 1
1644-0633
Pojawia się w:
Acta Scientiarum Polonorum. Architectura
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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