- Tytuł:
- Dissolution of alkaline batteries in reductive acidic media
- Autorzy:
- Zeytuncu, B.
- Powiązania:
- https://bibliotekanauki.pl/articles/110179.pdf
- Data publikacji:
- 2016
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
alkaline battery
manganese
zinc
reductive leaching
sulfur - Opis:
- In this paper, recovery of manganese and zinc from alkaline battery paste by leaching under atmospheric condition using elemental sulfur as a reductive agent and sulfuric acid was investigated. Different dissolution parameters, acid concentrations, liquid-to-solid ratios, reaction temperatures, leaching times and amounts of elemental sulfur were studied in detail. According to results, the Mn dissolution in reductive acidic media was an intermediate-controlled process with activation energy of 10.21±2.60 kJ/mol. After the leaching step, Mn and Zn were selectively precipitated from the leaching solution using sodium hydroxide. After solid/liquid separation, manganese(II,III) oxide (Mn3O4) was obtained by drying at 105 °C in air. Next, Mn3O4 was converted to manganese(IV) oxide (MnO2) by heating at 800 °C in air. After that the solution containing Zn(OH)42- was treated with sulfuric acid to form zinc hydroxide, separated and next converted to zinc oxide by heating at 600 °C in air. The final products were characterized by XRD. The results showed that the proposed process can be effectively used for recovery of Mn and Zn from alkaline batteries.
- Źródło:
-
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 437-450
1643-1049
2084-4735 - Pojawia się w:
- Physicochemical Problems of Mineral Processing
- Dostawca treści:
- Biblioteka Nauki
Artykuł