- Tytuł:
- Electron Paramagnetic Resonance and Superposition Model Analysis of Zero Field Splitting for Mn$\text{}^{2+}$ in Double Nitrates
- Autorzy:
-
Jain, V. K.
Prakash, V. - Powiązania:
- https://bibliotekanauki.pl/articles/1929829.pdf
- Data publikacji:
- 1993-12
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 76.30.Fc
- Opis:
- Electron paramagnetic resonance of Mn$\text{}^{2+}$ in La$\text{}_{2}$Zn$\text{}_{3}$(NO$\text{}_{3}$)$\text{}_{12}$ • 24H$\text{}_{2}$O single crystals is studied at ≈ 9.45 GHz. Mn$\text{}^{2+}$ substitutes for Zn$\text{}^{2+}$ sites. The spin-Hamiltonian parameters are evaluated at 290 K. The superposition model has been applied to the zero-field splitting parameter D for Mn$\text{}^{2+}$ in Ce$\text{}_{2}$Mg$\text{}_{3}$(NO$\text{}_{3}$)$\text{}_{12}$ • 24H$\text{}_{2}$O and La$\text{}_{2}$Mg$\text{}_{3}$ (NO$\text{}_{3}$)$\text{}_{12}$ • 24D$\text{}_{2}$O at both sites. It is shown that the calculated values of D are in agreement with the experimental values if local relaxation effects are taken into account.
- Źródło:
-
Acta Physica Polonica A; 1993, 84, 6; 1111-1115
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł