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Tytuł:
The effect of changing injection temperature on some mechanical and morphological properties for polypropylene material (PP)
Autorzy:
Al-Zubiedy, Ali
Muneer, Ruaa M.
Powiązania:
https://bibliotekanauki.pl/articles/111895.pdf
Data publikacji:
2019
Wydawca:
Stowarzyszenie Menedżerów Jakości i Produkcji
Tematy:
polypropylene PP
injection molding
mechanical properties of polymers
polipropylen PP
formowanie wtryskowe
właściwości mechaniczne
Opis:
This is a study of a medical injection factory-Babylon carried out in order to achieve proper mechanical and morphological properties, PP has been injection molded by using cold runner injection molding machine with temperature variation (198, 200, 203……2200C) for ten samples. The physical and mechanical properties of PP product were examined. It has been found that the Shore hardness decreases linearly with injection molding temperature increasing. The tensile strength has a similar behavior to the hardness. However, it has been found that the MIF (Melt Index Flow) rates increases with the increase of injection molding temperature. The density of PP has been found for both virgin PP and the samples, it has been found that the density decreases with increasing operation temperature. FTIR (Fourier Transmission Infrared) spectra were taken for both samples with high and low operation temperature. Besides the SEM (Scanning Electronic Microscopy) test shows the difference in the morphology of the product surface and the PP product at high and low operation temperature. Moreover, for all these properties, the PP product exhibits good mechanical properties (hardness, tensile strength, density) for the samples produced at temperature lower than 2070C. While the physical properties such as MIF improved with injection temperature increasing, additionally, the SEM images show that the sample produced in low temperature have surface damage.
Źródło:
Production Engineering Archives; 2019, 24; 20-24
2353-5156
2353-7779
Pojawia się w:
Production Engineering Archives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of Microplastic Detection Methods in Wastewater Treatment Plants
Autorzy:
Biyik, Yudum
Baycan, Neval
Powiązania:
https://bibliotekanauki.pl/chapters/31234001.pdf
Data publikacji:
2021
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
microplastics
wastewater
FT-IR
quality assurance/quality control (QA/QC)
polypropylene (PP)
polyethylene (PE)
Opis:
A plastic can be turn to millions fragments of microplastic particles by anthropogenic activities and environmental events (such as wind, UV light, the water wave action). Due to their surface hydrophobicity, adsorb persistent organic pollutants, the potential to transport contaminants and persistent properties, microplastics have the potential to become widely dispersed in the water environment via hydrodynamic processes and water currents. Plastic materials are durable and rather than decomposing, they break down into small plastic particles over time. These small particles that are less than 5 mm usually defined as microplastic. As a consequence of large plastic production rates, plastic waste accumulation in natural environment rapidly increased all over the World. However, the effects of plastic wastes in different ecosystems are still largely unknown. Water and wastewater treatment plants are important facilities to estimate plastic waste release or retention amount to the environment. The field of microplastic pollution is in its infancy, and there are not yet widely accepted standards for sample collection, laboratory analyses, quality assurance/quality control (QA/QC) or reporting of microplastics in environmental samples. Up to date, few studies have quantified microplastics in wastewater. Moreover, the lack of a standardized and applicable method to identify microplastics in complex samples, such as wastewater, has limited the accurate assessment of microplastics and may lead to an incorrect estimation. In this study, microplastic sampling techniques, extraction methods and identification methods of microplastics in wastewater were compared. It was concluded that studies were mostly done with grap type sampling, wet peroxite oxidation and identification methods with microscope and Fourier Transform Infrared Spectrophotometer (FT-IR). In the FT-IR analysis to determine the polymer structure of microplastics, the most common type of polymer was found to be polypropylene (PP) and polyethylene (PE).
Źródło:
Innovations – Sustainability – Modernity – Openness. Modernity in engineering; 9-22
9788366391901
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rzeczywiste wartości współczynnika oporów miejscowych podczas przepływu wody przez zgrzewane kolana z polipropylenu
Real values of local resistance coefficient during flow of water through welded polypropylene elbows
Autorzy:
Kalenik, Marek
Powiązania:
https://bibliotekanauki.pl/articles/237331.pdf
Data publikacji:
2019
Wydawca:
Polskie Zrzeszenie Inżynierów i Techników Sanitarnych
Tematy:
przepływ wody
współczynnik oporów miejscowych
zgrzewane kolano z PP
różnica ciśnień
instalacja wodociągowa
water flow
local resistance coefficient
welded polypropylene (PP) elbow
pressure difference
water supply
Opis:
Przedstawiono wyniki badań wartości współczynnika oporów miejscowych (ζ) zgrzewanych kolan z polipropylenu (PP) o kącie nachylenia 90° i średnicy 0,02 m. Do tego celu wybudowano laboratoryjne stanowisko pomiarowe. Zakres badań obejmował trzy rodzaje kolan z PP – prawidłowo zgrzane i prawidłowo dociśnięte (zgrzewane przy właściwej temperaturze i wciskane na rurę z właściwą siłą), zbyt słabo zgrzane i zbyt słabo dociśnięte oraz zbyt mocno zgrzane i za mocno dociśnięte. Wyznaczone wartości współczynnika ζ otrzymane z pomiarów zgodnie z normą PN-EN 1267 porównano z wartościami obliczonymi według normy PN-76/M-34034. Średnia wartość współczynnika oporów miejscowych wyznaczonych z pomiarów w przypadku kolan prawidłowo zgrzanych i prawidłowo dociśniętych wyniosła ζ1p=0,806, kolan zbyt słabo zgrzanych i zbyt słabo dociśniętych – ζ2p=1,341, a kolan zbyt mocno zgrzanych i za mocno dociśniętych – ζ3p=2,941, natomiast z obliczeń wg normy PN-76/M-34034 – tylko ζ4=0,157. Badania wykazały, że metody obliczania wartości współczynnika oporów miejscowych zaproponowane w normie PN-76/M-34034 zaniżają wyniki otrzymane w przypadku zgrzewanych kolan z PP, w porównaniu z wartościami doświadczalnymi wyznaczonymi z pomiarów. Wykorzystując wyniki pomiarów zaproponowano równania, na podstawie których opracowano do celów projektowych, zgodnie z wymaganiami normy PN-92/B-01706, nomogram do wyznaczania wartości współczynnika ζ w zależności od prędkości przepływu wody w kolanach z PP o średnicy DN20. Otrzymane rezultaty wskazują na potrzebę opracowania dokładnych metod obliczeniowych oraz przygotowania nowej normy do wyznaczania wartości współczynnika oporów miejscowych. Ponieważ rzeczywista wartość współczynnika oporów miejscowych zgrzewanych kolan z PP zależy od czasu zgrzewania i siły docisku, dlatego niezbędne jest precyzyjne określenie przez producentów kształtek czasu ich zgrzewania i siły docisku oraz wyposażenie zestawów do zgrzewania kształtek w dynamometry do pomiaru siły docisku podczas łączenia zgrzewanych kształtek.
The paper presents the results of investigations of local resistance coefficients (ζ) in welded polypropylene (PP) elbows of 0.02 m in diameter, angled at 90°. The investigations were performed on the purpose-built laboratory measurement stand. The scope of the research encompassed the elbows which were: properly warmed up and properly pressed (welded at the proper temperature and pressed with proper force onto the pipe); insufficiently warmed up and insufficiently pressed (welded at too low temperature and pressed with too low force onto the pipe); excessively warmed up and excessively pressed (welded at too high temperature and pressed with too high force onto the pipe). The local resistance coefficients ζ determined in measurements according to the PN-EN 1267 standard were compared to those calculated in accordance with the PN-76/M-34034 standard. The average value of the local resistance coefficient ζ, determined in measurements for properly welded and properly pressed elbows, was ζ1p = 0.806, for insufficiently warmed up and insufficiently pressed elbows – ζ2p = 1.341 and for excessively warmed up and excessively pressed elbows − ζ3p = 2.941, whereas only ζ4 = 0.157 was obtained from calculations according to PN-76/M-34034 standard. It was demonstrated that the local resistance coefficient values calculated for the welded PP elbows as per the PN-76/M-34034 standard were underestimated when compared with the ones experimentally measured. Based on these values, the formulas for the project purposes and in accordance with the PN- 92/B-01706 standard were proposed to develop a nomogram for local resistance coefficient ζ determination in function of water flow velocity in DN 20 PP elbows. The results justified a need to develop precise calculation techniques and a new standard for local resistance coefficient determinations. As the real value of local resistance coefficients ζ in welded polypropylene elbows strongly depends on the welding time and pressing force, it is necessary for pipe fittings manufacturers to precisely determine the welding time and pressing forces as well as to equip the welding sets with dynamometers to measure the pressing force during the welding process.
Źródło:
Ochrona Środowiska; 2019, 41, 1; 23-30
1230-6169
Pojawia się w:
Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of PP Fabric with Polyols by the Plasma Composite Technique
Autorzy:
Ma, Wen-Xiao
Hu, Bing-Nan
Bai, Yun
Powiązania:
https://bibliotekanauki.pl/articles/2171960.pdf
Data publikacji:
2022
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
polypropylene fabric
polyols
crosslinker
antistatic properties
hydrophilicity
Opis:
In order to endow polypropylene (PP) fabric with hydrophilic and antistatic properties, PP was grafted with polyols (sorbitol, maltitol and polyethylene glycol (PEG)) by the oxygen plasma treatment and subsequent bridging process, where ethylene glycol diglycidyl ether (EGDE) and trimethylolpropanetris (2-methyl-1-aziridinepropionate) (TTMA) were used as crosslinkers. The highest grafting rate was 7.48%. The chemical structure changes were analysed by Fourier transform infrared spectroscopy (FTIR). A scanning electron microscope (SEM) was used to observe the changes in polypropylene fiber surface morphology. The hydrophilicity was characterized by testing loose fiber suspension and moisture retention. The modified PP was more easily immersed in water and the desorption behaviour continued for 2h without equilibrium. The half-life of the grafted PP was reduced to 7s. The results showed that the modified PP with polyols possessed hydrophilicity and antistatic properties.
Źródło:
Fibres & Textiles in Eastern Europe; 2022, 2 (151); 90--98
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of coupling agent on antioxidant properties and structure of PP/ cotton stalk lignin composites
Autorzy:
He, Mingyu
Musajian, Dilhumar
Hasan, Gvlmira
Hou,, Gongbo
Yimit, Mamatjan
Powiązania:
https://bibliotekanauki.pl/articles/780085.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
polypropylene
coupling agent
cotton stalk lignin
composite material
Opis:
In this paper, the effects of coupling agent and lignin extracted from waste cotton stalks in Xinjiang on thermaloxygen aging properties of polypropylene (PP) composites were studied. The melt index test and indoor thermal oxygen aging test was carried out on the samples treated with coupling agent. The mechanical properties, surface micromorphology, rheological properties and element composition of the materials before and after 30 days of aging were studied. The results showed that the titanate coupling agent was the best for improving the melt index and mechanical properties of PP/cotton stalk lignin composites. After the 30-day thermal oxygen aging test, the samples with 2% lignin had the best impact strength and retention rate of fracture elongation, reaching 68.9% and 77.3% respectively. The sample with 3% lignin content had the smoothen surface, no crack appeared. After aging, the increase of C=O was the least, and the crystal peak area decreased less.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 2; 78-85
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free radical scavenging ability of sodium lignosulfonate and its application in food grade polypropylene
Autorzy:
Musajian, Dilhumar
Hasan, Gvlmira
He, Mingyu
Yimit, Mamatjan
Powiązania:
https://bibliotekanauki.pl/articles/777895.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
cotton lignin
sodium lignosulfonate
free radical scavenging
antioxidant properties, food
grade PP
Opis:
Sodium lignosulfonate (SL) was prepared from waste of cotton lignin (CL) through hydrothermal reaction method. Orthogonal experiment was designed with value of OIT as objective function. Polypropylene (PP) is a polymer produced by the addition polymerization of propylene. It is a white waxy material with a transparent and light appearance, which is widely used in food and pharmaceutical packaging. The results of GPC and TG analysis revealed that SL has stable thermal properties, which means that SL has the potential to be an antioxidant for PP materials. In addition, the scavenging effects of CL and SL were studied. The obtained results exhibited that the SL can obviously increase the scavenging effect on free radicals and it is a kind of new synthetic antioxidant with antioxidant property, which could effectively delay the oxidation of PP. Subsequent rheological experiments proved that the SL/PP sample can improve the heat-resistant oxygen performance of PP under the thermal oxygen shearing environment. Combined with the effect of SL on the mechanical properties of PP before aging, SL has a stabilizing effect on PP thermal oxygen aging.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 2; 56-66
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polypropylene Crystallisation in the Presence of Inorganic Additives
Krystalizacja polipropylenu w obecności dodatków nieorganicznych
Autorzy:
Ujhelyiová, Anna
Horbanová, Ľuba
Petková, Mária
Ryba, Jozef
Annus, Július
Powiązania:
https://bibliotekanauki.pl/articles/232376.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
polypropylene fibre
PP
inorganic additives
modification
crystallisation
włókna polipropylenowe
dodatki nieorganiczne
modyfikacja
krystalizacja
Opis:
The physical modification of polypropylene (PP) fibres with inorganic additives ensures more intense anchoring of PP fibres in constructional composites, which leads to great improvement of the function of PP fibres in relation to the transmission and absorption of deformation energy in the formation and loading of composites. This work focuses on the preparation of PP fibres modified with untreated and treated CaCO3 and SiO2 for constructional composites. It investigated the effect of inorganic additives on the thermal, thermo-mechanical and sorption properties of these fibres. Melting and crystallisation temperatures as well as the melting and crystallisation enthalpies of PP and modified PP fibres depend on the additives and conditions of preparation of PP fibres applied. A lower amount of inorganic additives improves and a higher amount of inorganic additives worsened the dimensional stability of the PP fibres observed. The addition of inorganic fillers increased the water vapour sorption of the modified PP fibres in comparison with the pure PP fibre.
Fizyczna modyfikacja włókien polipropylenowych (PP) za pomocą nieorganicznych dodatków zapewnia bardziej intensywne umocowanie włókien PP w kompozytach konstrukcyjnych, co powoduje znaczną poprawę funkcji włókien PP w stosunku do przenoszenia i absorpcji energii odkształcenia i obciążenia kompozytów. Przeprowadzone prace koncentrowały się na przygotowaniu włókien PP modyfikowanych nieoczyszczonymi i poddanymi obróbce CaCO3 i SiO2 do zastosowania w kompozytach konstrukcyjnych. Zbadano wpływ nieorganicznych dodatków na właściwości termiczne, termo-mechaniczne i sorpcyjne włókien. Stwierdzono, ze temperatury topnienia i krystalizacji oraz entalpie topnienia i krystalizacji PP i modyfikowanych włókien PP są zależne od dodatków i warunków wytwarzania włókien PP. Mniejsza ilość nieorganicznych dodatków poprawia, a większa ilość pogarsza stabilność wymiarową obserwowanych włókien PP. Dodatek nieorganicznych wypełniaczy zwiększył sorpcję pary wodnej modyfikowanych włókien PP w porównaniu z czystymi włóknami PP.
Źródło:
Fibres & Textiles in Eastern Europe; 2019, 2 (134); 30-38
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Morphology and Electromagnetic Shielding Effectiveness of PP Nonwovens Modified with Metallic Layers
Morfologia i skuteczność ekranowania elektromagnetycznego włóknin polipropylenowych modyfikowanych warstwami metalicznymi
Autorzy:
Koprowska, J.
Dobruchowska, E.
Reszka, K.
Szwugier, A.
Powiązania:
https://bibliotekanauki.pl/articles/233154.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
polypropylene nonwoven
metallic thin layers
magnetron deposition
surface morphology
crystalline structure
EM shielding effectiveness
polipropylenowa włóknina
cienkie warstwy metaliczne
osadzanie magnetronu
morfologia powierzchni
struktura krystaliczna
skuteczność elektromagnetycznego (EM) ekranowania
Opis:
Polypropylene (PP) nonwoven was used as a substrate for CuSn and CuZnNi deposited layers. Nonwoven metallization was carried out using the DC magnetron sputtering process at various process parameters (e.g. effective power dissipated in the target, velocity of the substrate drift, number of cycles). The studies aimed at defining the surface morphology of PP nonwoven modified by metallic deposition, the crystallographic structure of the thin metallic layers and the effect of the layers’ crystallinity on the electromagnetic (EM) shielding effectiveness of the two-component metal/PP composites. The morphology studies were covered by scanning electron microscopy. Furthermore the crystalline character of components CuSn and CuZnNi was examined in grazing-incidence angle X-ray diffraction experiments. It was found that CuSn/PP composites with a crystalline structure of the metallic layer exhibit the highest values of shielding effectiveness (44-45 dB at 27,12 MHz and 38-39 dB at 1795 MHz).
Do napylania warstw CuSn i CuZnNi jako podłoże (substrat) użyto włókninę polipropylenową (PP). Metalizację włókniny prowadzono stosując proces rozpylania magnetronowego DC przy różnych parametrach procesowych (takich, jak na przykład: moc efektywna wydzielana na targecie, prędkość przesuwu podłoża, ilość cykli). Badania miały na celu określenie: morfologii powierzchni włókniny PP modyfikowanej przez osadzania metali, krystalograficznej struktury cienkich warstw metalicznych i wpływu efektu krystalizacji warstw na skuteczność elektromagnetycznego (EM) ekranowania dwuskładnikowych kompozytów metal/PP. Badania morfologiczne zostały wykonane za pomocą skaningowego mikroskopu elektronowego. Ponadto, krystaliczną postać CuSn i CuZnNi składników i skład fazowy warstw metalicznych osadzonych na podłożu z włókniny polipropylenowej oceniano w oparciu o pomiary dyfrakcji rentgenowskiej. Stwierdzono, że kompozyty CuSn/PP o strukturze krystalicznej warstwy metalicznej wykazują najwyższe wartości skuteczności ekranowania (44 - 45 dB przy 27,12 MHz i 38 - 39 dB przy 1795 MHz).
Źródło:
Fibres & Textiles in Eastern Europe; 2015, 5 (113); 84-91
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Polarization Processes on the Morphology and Photoluminescence Properties of PP/TiO₂ Polymer Nanocomposites
Autorzy:
Ramazanov, M.
Hajiyeva, F.
Maharramov, A.
Hasanova, U.
Ahmadova, A.
Rahimli, A.
Shirinova, H.
Powiązania:
https://bibliotekanauki.pl/articles/1032328.pdf
Data publikacji:
2017-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
photoluminescence
corona discharge
nanocomposites
polypropylene
titanium dioxide
Opis:
The paper reports of synthesis and investigation of polymeric nanocomposites based on isotactic polypropylene and titanium dioxide nanoparticles PP+TiO₂ (PPT). The structure of the PPT nanocomposites was studied by scanning electron and atomic force microscopy. There was also studied the influence of the polarization process by corona discharge on the structure and photoluminescence properties of PPT nanocomposites. It was found that intensity of the photoluminescence after the polarization increases, and this depends on the concentration of titan dioxide nanoparticles in the polymer matrix. It was shown that rms roughness for non-polarized sample compositions is 60-100 nm, whereas for polarized samples after the corona discharge polarization, makes 20-40 nm, i.e. there takes place grinding of the structural elements. It is supposed that, in the composite there forms sufficiently high internal local field, due to the boundary charges, so under the influence of this field there were excited additional luminescent centers, and as a result, after the polarization there was observed the increase of luminescence intensity.
Źródło:
Acta Physica Polonica A; 2017, 131, 6; 1540-1543
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza wpływu wysokiej temperatury na zmianę wybranych parametrów wytrzymałościowych fibrobetonu z dodatkiem włókien polipropylenowych
Analysis of influence of high temperature on changes of the selected strength parameters of fiber reinforced concrete with polypropylene fibers
Autorzy:
Bednarek, Z.
Drzymała, T.
Powiązania:
https://bibliotekanauki.pl/articles/136914.pdf
Data publikacji:
2013
Wydawca:
Szkoła Główna Służby Pożarniczej
Tematy:
pożar
fibrobeton
włókna polipropylenowe (PP)
wytrzymałość
moduł sprężystości
fire
fibers reinorced concerete (FRC)
polypropylene fibre
elastic modul
Opis:
W niniejszym referacie autorzy zaprezentowali wyniki badań wytrzymałościowych, których celem była analiza oddziaływania wysokich temperatur występujących podczas pożaru na wytrzymałość fibrobetonu z włóknami polipropylenowymi oraz oszacowanie wielkości spadku wytrzymałości na ściskanie w porównaniu z betonem tej samej klasy bez dodatku włókien. Dodatkowo omówiono procedury badawcze oraz wyniki badań modułu sprężystości fibrobetonu z dodatkiem włókien polipropylenowych poddanego oddziaływaniu wysokiej temperatury zbliżonej do temperatury występującej w środowisku pożaru. Podczas badań stwierdzono korzystny wpływ dodatku włókien polipropylenowych w ilości 1,2 kg/m3 oraz dozowanych do mieszanki betonowej powyżej 1,2 kg/m3 na właściwości wytrzymałościowe betonu w wysokich temperaturach.
In construction engineering practice impact of high temperatures occurring during fire on the concrete structures is an important issue. An unfavorable phenomenon associated with high temperature is surface spalling of large concrete parts, which has a significant impact on the safety of the whole building structure, users and rescue teams. “Concrete thermal spalling” phenomenon in the foreign literature is called “spalling“. One of the possibilities of preventing this negative phenomenon is a technological method consisting in addition of polypropylene fibers to concrete mix. The method results in the increase of resistance of the concrete structure to the explosive spalling in the conditions of increased humidity. In the road tunnels and other non-heated compartments, concrete is characterized by the relatively high water content. The results of many tests prove that the addition of polypropylene fibers (PP) can have a positive impact on the concrete structures subjected to high temperatures and can reflect to the reduction of “spalling” effect. Investigations of high temperatures impact occurring during the fire, on the basic strength parameters of the concrete with addition of polypropylene fibers, were carried out in Poland, at Cracow University of Technology and Main School of Fire Services, among the others. Zoja Bednarek and Tomasz Drzymala conducted investigations at the Main School of Fire Services. During the studies advantageous effect of the addition of 1.2 kg/m3 and above of polypropylene fibers to the concrete mix on the concrete strength properties at high temperatures have been demonstrated. In the presented paper the results of strength tests are shown, which aimed at analyzing the impact of high temperatures occurring during the fire on the strength of fiber reinforced concrete with polypropylene fibers, as well as estimating reduction of compressive strength compared to the concrete of the same class but without addition of fibers. Additionally, the applied research methods are discussed and elasticity modulus test results of fiber reinforced concrete subjected to high temperatures close to fire temperatures are presented. Taking into account the undoubtedly positive influence of PP fibers addition on the reduction of concrete “spalling”, the authors investigated the manner in which such addition influences different strength properties of the concrete at high temperatures conditions. From this point of view the impact of high temperatures on the compressive strength and elasticity modulus were investigated. Samples were prepared with the use of normal C30/37 class concrete and high strength C60/75 class concrete. For the concrete mix three different types of polypropylene fibers were used, differing in length and thickness of single fibers, in the following amount: 0.6 kg/m3, 0.9 kg/m3, and 1.2 kg/m3. The selected fibers used as the additives to concrete mix are easily available on the European market. Preliminary studies were carried out to deter-mine the influence of fire temperatures on the flammable properties of fibers in oxygen and nitrogen atmosphere. The conducted studies have demonstrated a significant impact of the atmosphere, in which degradation of samples take place, on the results of TG and DTG analysis. The atmosphere had a crucial effect on the initial temperature of degradation, temperature of the partial mass loss, temperature of termination of degradation, temperature of maximum mass loss rate and nondegradable residues mass remaining in the concrete. The results of the studies allow assuming that in the condi-tions of oxygen depletion, degradation of PP fibers in the concrete would occur much slower. The above assumption has been confirmed by the observations of the concrete structure, by means of scanning microscope (SEM), with regards to the fibers condition inside the concrete samples. Based on the obtained results the following conclusions have been formulated: 1. The addition of PP fibers has a negative impact on the compressive strength of C30/37 class concrete, especially in normal temperatures and temperatures raised to about 200ºC. Above 300ºC a reduction of strength of this concrete is identical to the strength reduction of the concrete without PP fiber addition. 2. In case of fiber reinforced concrete and C60/75 class concrete, compressive strength reduction in the whole temperature range can be considered as identical. 3. No significant influence of the type of the applied PP fibers on the reduction of compressive strength for both classes of fiber reinforced concrete has been demonstrated. 4. In case of both classes of fiber reinforced concrete the compressive strength is reduced in high temperatures. Moreover, the strength reduction of C30/37 concrete proceeds faster. At 800ºC the strength of normal concrete and fiber reinforced concrete of C30/37 class decreases of about 90%, whereas in case of concrete and fiber reinforced concrete of C60/75 class such reduction occurs at 1000ºC. 5. Analyzing the results with regards to the impact of PP fibers addition to the concrete in the quantities above 1.2 kg/m3, it can be concluded that such addition does not enhance strength reduction of the concrete in fire temperatures. Therefore, in case of fiber reinforced concrete the identical principles can be applied for strength determination, as in case of the concrete without PP fibers in fire temperatures. The reduced compressive strength of the concrete with addition of PP fibers in temperature T can be described by the following formula: fck(T) = kc (T) ... fck ---- (1) where: fck – specific compressive strength of fiber reinforced concrete at normal temperature (20ºC) kc(T) – assumed reduction coefficient as for the corresponding class concrete without addition of fibers. 6. Based on the results analysis a positive impact of PP addition on the elasticity modulus of C30/37 and C60/75 class concrete in high fire temperatures can be concluded. 7. In both cases higher growing tendencies have been observed for C30/37. In normal temperature no impact of PP fibers addition on the elasticity modulus values can be noticed. 8. At the elevated and high temperatures a slightly lower elasticity modulus reduction in case of fiber reinforced concrete with PP fibers can be observed. It is especially evident at 300ºC. Summing up: addition of 1.2 kg/m3 of polypropylene fibers to the concrete, in order to reinforce the concrete against dangerous explosive spalling during the fire, is advantageous also from the point of view of the concrete strength at fire temperatures.
Źródło:
Zeszyty Naukowe SGSP / Szkoła Główna Służby Pożarniczej; 2013, 3, 47; 127-138
0239-5223
Pojawia się w:
Zeszyty Naukowe SGSP / Szkoła Główna Służby Pożarniczej
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 23

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