- Tytuł:
- Cleaning of pesticides from aqueous solution by a newly synthesized organoclay
- Autorzy:
- Baysal, Gülay
- Powiązania:
- https://bibliotekanauki.pl/articles/205085.pdf
- Data publikacji:
- 2019
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
adsorption isotherms and kinetics
1-methyl-di-octyl-1 phenyl ammonium iodide
toxic compounds
organoclay - Opis:
- In the present study, the novel quaternary ammonium salt (QAS+), 1-methyl-di-octyl-1 phenyl ammonium iodide (QAS1), was synthesized by complete alkylation reaction. Sodium montmorillonite (Mt) was modified via an ion-exchange reaction with QAS1+. The modified material and quarternary ammonium salt (Mt1 and QAS1) were analyzed by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Removal capacity of hydrophobic organic pollutants such as 4-nitrophenol (4-NP) and 2,4-dinitrophenol (2,4-DNP) from solution media of synthesized organoclay was evaluated. The optimum conditions and batch kinetics of adsorption of 4-nitrophenol and 2,4-dinitrophenol from aqueous solutions are reported. It was shown that the adsorption capacity decreased in the order 4-NP> 2,4-DNP. The total mass loss during the drying process was 66% and 78%, respectively. Thermodynamic parameters enthalpy (ΔH0) and entropy (ΔS0) and the mean free energy (E) for the adsorption of nitrophenol compounds (NCP) were determined.
- Źródło:
-
Archives of Environmental Protection; 2019, 45, 3; 21-30
2083-4772
2083-4810 - Pojawia się w:
- Archives of Environmental Protection
- Dostawca treści:
- Biblioteka Nauki
Artykuł