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Wyświetlanie 1-3 z 3
Tytuł:
Analiza widm emisyjnych procesów spalania jako zagadnienie odwrotne w pomiarach pośrednich
Flame emission spectrum analysis as an inverse problem in indirect measurements
Autorzy:
Wójcik, W.
Cięszczyk, S.
Kisała, P.
Komada, P.
Powiązania:
https://bibliotekanauki.pl/articles/151671.pdf
Data publikacji:
2009
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
pomiary pośrednie
zagadnienie odwrotne
OP-FTIR
procesy spalania
indirect measurements
inverse problem
combustion processes
Opis:
Artykuł przedstawia problem pomiarów in situ zawartości gazów oraz temperatury w procesach spalania. Pomiary takie przeprowadzone być mogą z wykorzystaniem spektrometru FTIR o otwartej ścieżce pomiarowej. Analizę widm transmisyjnych oraz emisyjnych procesów o zmieniającej się temperaturze potraktować można jako rozwiązanie zagadnienia odwrotnego. Zagadnienie proste jest wtedy modelowaniem widm w zależności od temperatury oraz zawartości składników. Przedstawiono pomiary promieniowania procesu spalania oraz ich analizę ilościową z wykorzystaniem opisanej metody.
The paper presents a problem of in-situ measurements of gas concentration and temperature of combustion processes. Such measurements can be carried out by using an open path FTIR. The analysis of transmission and emission spectra of changeable temperature processes can be treated as an inverse problem. Modelling of the spectrum as a function of temperature and species concentration is then a direct problem. In this paper there are presented combustion process measurements and the quantitative analysis as an inverse problem is performed. In the introduction the need for investigations of the combustion process is discussed. Recently biomass gasification and combustion have been playing a significant role due to the environmental protection. What is important, the process should be analysed by an in-situ method. The access to some processes can be so difficult that only remote measurements are possible. In those cases an OP-FTIR spectrometer (Open Path Fourier Transform Infrared Spectrometer) can be used. The analysis of the classical FTIR spectrum is shown in Section 2. This method consists in using a set of calibration samples for preparing the calibration curve. Unknown concentration of species is determined with this curve. Calibration and measurements have to be carried out in the same temperature. Section 3 describes the problem of simultaneous analysis of concentration and temperature of gases based on infrared spectrum measurements. The inverse problem method is one of the solutions of this problem. The direct problem consists in modeling the spectrum modeling of known temperature and concentration. There are two kinds of methods for modeling the synthetic spectrum of gases - physical (line by line) and statistical one. The spectra in Fig. 3 are calculated for the temperature profiles of Fig. 2. The misfit minimisation between the synthetic and measurement spectrum by means of an optimization method is called the inverse problem. Section 4 describes the measurements of the process infrared spectrum. The spectrum measurements based on the spectral gas models and the inverse problem are analysed. The FTIR spectra measured are shown in Figs. 7 and 9, whereas the adequate analyses are depicted in Figs. 6 and 8. The paper is summarised with some conclusions.
Źródło:
Pomiary Automatyka Kontrola; 2009, R. 55, nr 2, 2; 121-125
0032-4140
Pojawia się w:
Pomiary Automatyka Kontrola
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optyczna metoda diagnostyki gazu syntezowego z biomasy
Optical Method for Biomass Syngas Monitoring
Autorzy:
Komada, P.
Cięszczyk, S.
Zhirnova, O.
Askarova, N.
Powiązania:
https://bibliotekanauki.pl/articles/1818001.pdf
Data publikacji:
2016
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
spektroskopia
gaz syntezowy
diagnostyka
spectroscopy
synthesis gas
diagnostics
Opis:
One of the methods of increasing the overall biomass share in the electricity and heat production is its gasification and subsequent co-combustion of the obtained syngas in conventional power boilers. The process of biomass gasification is relatively well controlled and understood. It does not change the fact that the syngas composition depends on many process factors, as well as the composition of the charge batch. Unfortunately, it means that the obtained product is not homogeneous in time. Consequently, the use of such fuel for electricity production may present a number of problems from the control point of view. Therefore, both during the syngas production and the co-firing process, it is advisable to use information on the composition of produced syngas, or at least its main components. It is possible to use optical methods, which are an interesting alternative to classical methods, even despite unfavorable measurement conditions. The article presents selected optical method for the synthesis gas monitoring. The results of simulation studies are presented, confirming the possibility of determining the concentration of interesting components in the syngas mixture.
Źródło:
Rocznik Ochrona Środowiska; 2016, Tom 18, cz. 2; 271-283
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metoda analizy widm mierzonych z wykorzystaniem spektrometrów OP-FTIR w monitorowaniu powietrza atmosferycznego oraz gazów w procesach przemysłowych
Open Path FT-IR Spectra Analysis Method for Monitoring of Environment and Processes with Varying Conditions
Autorzy:
Cięszczyk, S.
Komada, P.
Akhmetova, A.
Mussabekova, A.
Powiązania:
https://bibliotekanauki.pl/articles/1817978.pdf
Data publikacji:
2016
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
otwarta ścieżka
FTIR
analiza widm
wpływ temperatury
open path
spectrum analysis
temperature influence
Opis:
Open-Path Fourier Transform Infrared (OP-FTIR) can be used for monitoring of atmospheric environment. The open path technique is based on the measurement of the absorption along the atmosphere path between radiation source and spectrometer. Measurement paths used in this method have a considerable length – from tens of meters to several kilometers. The main advantage of OP-FTIR spectrometry is the possibility of continuously and simultaneously measuring concentrations of multiple compounds. Unfortunately, quantitative analysis of the spectra of such measurements is a difficult issue due to the changing atmospheric conditions and overlapping of the absorption spectra of various components. Numerous algorithms used for the interpretation of the measured spectra have been proposed. They can be classified into methods using classical chemometric calibration and iterative algorithms. Classical Least Square CLS and Partial Least Square PLS are the most commonly used methods of OP-FTIR spectrometry. Iterative methods are based on comparing measured data with synthetic spectra, that is computational models of investigated optical path transmission. For this purpose, databases such as HITRAN are used. Transmission model must take into account not only the spectral characteristics of gases, but also the measuring instrument influence on the measured spectrum. As an example of modeling the spectra of NH3 and HCl gas are used. Modeling of gas spectra with different resolution is shown. Classical methods of building a chemometric calibration model require appropriate reference samples. This is usually associated with considerable cost and time-consuming calibration process. In addition, correct calibration requires maintaining the same conditions during the calibration, as in practical measurements. This is possible only in the case of laboratory measurements. In particular, it is necessary to maintain a constant temperature and pressure of examined substances. It is connected with changes in width and intensity of gas rotational lines. In classical spectroscopy, changing environmental conditions require new calibration measurements. In the open path spectroscopy, changes in conditions occur naturally along with the changes in the examined environment (object, process). If the measurement conditions in the environment differ from those in calibration measurements, significant errors in determining the content of the ingredients may appear. Greater changes in conditions may occur in a variety of chemical or physical processes. Sometimes it is not possible to perform measurements in conditions similar to those occurring in a particular industrial facility. In such cases, synthetic spectra may be used in two ways: in an iterative process to compare with measured spectra or to form a chemometric calibration models. In the latter case, the problem of changing conditions can be solved in several ways. The simplest method is to build separate calibration models for all conditions that can occur during the measurement. However, in order to use this method, it is necessary to measure the existing conditions and choose an appropriate local model. Another method is to correct the measured spectra and to adapt them to the standard conditions. The third option is to build global models. The spectra of all the conditions that may occur during the measurement are then used for building a calibration model. Then, the effect of temperature on the determination of gas content for local calibration models is investigated. Finally, a global calibration model insensitive to temperature changes in 10-40°C range is built.
Źródło:
Rocznik Ochrona Środowiska; 2016, Tom 18, cz. 2; 218-234
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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