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Wyświetlanie 1-15 z 49
Tytuł:
Density functional theory study of H2O adsorption on different sphalerite surfaces
Autorzy:
Deng, Zheng-bin
Tong, Xiong
Huang, Ling-yun
Xie, Xian
Powiązania:
https://bibliotekanauki.pl/articles/110593.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
density functional theory
sphalerite
water adsorption
hydrophobicity
Opis:
Effects of In, Ge, Fe substitution in the lattice of sphalerite on wettability were usually ignored, therefore the optimal flotation condition could be difficult to find due to lacking of sufficient theoretical study on water adsorption, resulting lower recoveries of different sphalerites. Adsorption of H2O on different sphalerite surfaces was studied using density functional theory (DFT) method. All computational models were built in a vacuum environment to eliminate the effects of oxygen and other factors. H2O molecule prefers to stay with ideal sphalerite, indium-beard sphalerite, germanium-beard sphalerite and marmatite surfaces rather than water. Compared with ideal sphalerite surface, Fe atom improves the hydrophilicity of surface, while In and Ge atoms reduce the hydrophilicity.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 82-88
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
UV-crosslinkable photoreactive self-adhesive hydrogels based on acrylics
Autorzy:
Czech, Z.
Antosik, A.K.
Bednarczyk, P.
Powiązania:
https://bibliotekanauki.pl/articles/778227.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
self-adhesive hydrogels
acrylics
UV-crosslinking
tack
peel adhesion
water adsorption
Opis:
Hydrogels are a unique class of macromolecular networks that can hold a large fraction of an aqueous solvent within their structure. They are suitable for biomedical area including controlled drug delivery and for technical applications as self-adhesive materials for bonding of wet surfaces. This paper describes photoreactive self-adhesive hydrogels based on acrylics crosslinked using UV radiation. They are prepared in ethyl acetate through radical polymerization of monomers mixture containing 2-ethylhexyl acrylate (2-EHA), butyl acrylate (BA), acrylic acid (AA) and copolymerizable photoinitiator 4-acryloyloxy benzophenone (ABP) at presence of radical starter 2.2’-azobis-diisobutyronitrile AIBN. The synthesized acrylic copolymers were determined by viscosity and GPC analysis and later modified using ethoxylated amines. 4-acryloyloxy benzophenone (ABP) was used as crosslinking monomer. After UV crosslinking the properties of these novel synthesized hydrogels, such as tack, peel adhesion, shears strength, elongation and water adsorption were also studied.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 126-130
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Water vapour adsorption by soil aggregate fractions
Autorzy:
Kharitonova, G.V.
Shein, E.V.
Vityazev, V.G.
Lapekina, C.I.
Powiązania:
https://bibliotekanauki.pl/articles/25490.pdf
Data publikacji:
2005
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
water sorption
soil
water vapour
soil aggregate
water vapour adsorption
Źródło:
International Agrophysics; 2005, 19, 1
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of the specific surface area of Vertisols from the Gezira Region in Sudan
Autorzy:
Sokolowska, Z.
Hajnos, M.
Elias, E.A.
Alaily, F.
Powiązania:
https://bibliotekanauki.pl/articles/24248.pdf
Data publikacji:
2004
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
Vertisol
soil
specific surface area
Sudan
water vapour adsorption
Źródło:
International Agrophysics; 2004, 18, 1
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic model of water vapour adsorption by gluten-free starch
Autorzy:
Ocieczek, A.
Kostek, R.
Ruszkowska, M.
Powiązania:
https://bibliotekanauki.pl/articles/973244.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
kinetic model
water vapour adsorption
gluten-free starch
sorption isotherm
starch
Opis:
This study evaluated the kinetics of water vapour adsorption on the surface of starch molecules derived from wheat. The aim of the study was to determine an equation that would allow estimation of water content in tested material in any time-point of the adsorption process aimed at settling a balance with the environment. An adsorption isotherm of water vapour on starch granules was drawn. The parameters of the Guggenheim, Anderson, and De Boer equation were determined by characterizing the tested product and adsorption process. The equation of kinetics of water vapour adsorption on the surface of starch was determined based on the Guggenheim, Anderson, and De Boer model describing the state of equilibrium and on the model of a first-order linear inert element describing the changes in water content over time.
Źródło:
International Agrophysics; 2015, 29, 1; 115-119
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Analysis of Knits from Peat Fibre and its Combinations with Other Natural Fibres
Analiza porównawcza dzianin z włókien torfowych i ich kombinacji z innymi włóknami naturalnymi
Autorzy:
Mikučioniené, D.
Čepukonė, L.
Powiązania:
https://bibliotekanauki.pl/articles/233403.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
knitted structure
peat fibre
shrinkage
air permeability
static water adsorption
parametry strukturalne
włókna naturalne
włókna torfowe
ścisłość
przepuszczalność powietrza
adsorpcja wody
Opis:
Natural and man-made fibres of natural origin are more and more widely used, while consideration of sustainability is constantly increasing. The properties and processing behaviour of newly introduced fibres of natural origin are usually compared and often predicted on the basis of widely investigated fibres; however, this prediction sometimes does not have any confirmed basis. Structural parameters and the majority of mechanical and physical properties of knitted fabrics depend on technical characteristics of the knitting machine, on the properties of yarns as well as on the origin of the raw material. This study attempts to develop knits from new natural peat fibres and their combination with widely used woollen, cotton and elastomeric Lycra yarns and to investigate the influence of peat fibre’s nature on structural parameters such as loop length, wale and course spacing, area density, the tightness factor and on main physical properties such as dimensional stability, air permeability and water adsorption.
Włókna naturalne i sztuczne pochodzenia naturalnego są coraz szerzej stosowane. Właściwości i sposób przetwarzania nowych włókien pochodzenia naturalnego są często przewidywane na podstawie dobrze znanych włókien, jednak ta prognoza czasami nie ma żadnych potwierdzonych podstaw. Parametry strukturalne i większość właściwości mechanicznych i fizycznych dzianin zależą od właściwości technicznych maszyn dziewiarskich i właściwości przędzy, a także od pochodzenia surowca. W pracy podjęto próbę otrzymania dzianin z włókien torfowych i ich kombinacji z wełną, bawełną i Lycrą. Badano wpływ włókna torfowego na parametry strukturalne, takie jak: długość nitki w oczku, ścisłość kolumienkową i rządkową, ścisłość, stabilność wymiarów, przepuszczalność powietrza i adsorpcję wody.
Źródło:
Fibres & Textiles in Eastern Europe; 2017, 2 (122); 24-29
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the sorption properties of different soils using water vapour adsorption and potentiometric titration methods
Autorzy:
Skic, K.
Boguta, P.
Sokolowska, Z.
Powiązania:
https://bibliotekanauki.pl/articles/25797.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
sorption property
soil
water vapour adsorption
potentiometric titration
cation exchange capacity
surface area
physicochemical characteristics
Źródło:
International Agrophysics; 2016, 30, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of phosphates on dissolved organic matter release from peat-muck soils
Autorzy:
Sokolowska, Z.
Szajdak, L.
Boguta, P.
Powiązania:
https://bibliotekanauki.pl/articles/24997.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
amino acid content
ash
bulk density
calcium form
dissolved organic matter
humic acid
muck
organic matter
peat bog soil
pH
peat soil
peat-muck soil
phosphate
surface property
water adsorption index
Źródło:
International Agrophysics; 2011, 25, 2
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental study on the adsorption refrigeration device built on a water-silica gel working pair
Autorzy:
Szelągowski, Adam
Trzcinkowski, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/132051.pdf
Data publikacji:
2019
Wydawca:
Centrum Rzeczoznawstwa Budowlanego Sp. z o.o.
Tematy:
adsorption refrigeration
adsorption
water-silicagel
Opis:
Due to increasing restriction put on compressor based cooling, adsorption cooling has been increasing its popularity. Abovementioned restrictions forces usage of ecological refrigerants, such as water. Additional advantage of adsorption devices is possibility to use low-grade waste heat source or solar energy as the main driving energy instead of electricity. This trend has lead to significant development of adsorption based branch in cooling industry over past 30 years. The paper presents the results of experimental research for an adsorption refrigeration device built of two deposits. Water-silica gel was chosen as the working pair, because this solution allows to work at the lowest drive temperatures. As a result of the experiment, EER coefficients were obtained at the level of 0.57-0.82 and SCP coefficients in the range from 8 to 21 W/kg. The results allow to conclude that adsorption devices can, in many cases compete with compressor solutions.
Źródło:
Modern Engineering; 2019, 1; 42-54
2450-5501
Pojawia się w:
Modern Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of marine surfactant adsorption at an air-water interface. Baltic Sea studies
Autorzy:
Pogorzelski, S.J.
Kogut, A.D.
Powiązania:
https://bibliotekanauki.pl/articles/48394.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
coastal water
water interface
surface adsorption
marine film
kinetics
Baltic Sea
adsorption barrier
adsorption
Opis:
The paper contains the results of studies of natural surface film adsorption kinetics carried out in inland waters and in shallow offshore regions of the Baltic Sea during 2000–01 under calm sea conditions. The novel approach presented here for the adsorption dynamics is based on the mixed kinetic-diffusion model and analyses of the surface pressure-time plots at short (t → 0) and long (t→∞) adsorption time intervals. Values of the effective relative diffusion coefficient Deff/D (= 0.008 − 0.607) and energy barrier for adsorption Ea/RT (= 0.49 − 7.10) agree well with the data reported for model non-ionic surfactant solutions of pre-cmc concentrations. Wind speed is one of the factors affecting the adsorption barrier via the increased surface pressure of the natural film exposed to wind shear stress (∼ U10 2),a nd enters the relation Ea/RT = 1.70U10 1/3.
Źródło:
Oceanologia; 2001, 43, 4
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Conceptual adsorption system of cooling and heating supplied by solar energy
Autorzy:
Turski, M.
Powiązania:
https://bibliotekanauki.pl/articles/952679.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solar cooling
solar heating
solar energy
adsorption chiller
adsorption ice water
generator
chłodzenie słoneczne
ogrzewanie słoneczne
energia słoneczna
adsorpcja wody lodowej
Opis:
This paper presents the possibility of reducing the demand for nonrenewable primary energy for buildings using a new conceptual adsorption system of cooling and heating supplied by solar energy. Moreover, the aim of this study is to shorten the payback time of investment in the standard adsorption cooling system through its integration with the heating system. Research has been carried out for an energy-efficient medium-sized single-family building with a floor area of 140 m 2 and a heat load of 4.2 kW and cold load of 4.41 kW. It has been shown that the use of an adsorption system of cooling and heating supplied by solar energy decreased the demand for nonrenewable primary energy by about 66% compared to the standard building that meets the current requirements.
Źródło:
Chemical and Process Engineering; 2016, 37, 2; 293-304
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
First-principles study on the adsorption structure of water molecules on a pyrite (100) surface
Autorzy:
Liu, Yingchao
Chen, Jianhua
Li, Yuqiong
Zhang, Junjie
Kang, Duan
Powiązania:
https://bibliotekanauki.pl/articles/1447970.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
water molecules
adsorption
Opis:
The hydration structure of water molecule adsorption at different coverages of a monolayer on a pyrite (100) surface were simulated using the density functional theory (DFT) method. The results demonstrate that the Fe-O interaction weakens and the adsorption energy per water molecule decreases with increasing water coverage, except at a monolayer coverage of 12/12 (i.e., full coverage). H-S and H-O hydrogen bonds were formed on the nearest surface layer. When large amounts of water molecules adsorb onto the surface, the adsorbed water molecules can be divided into three layers: the layer nearest to the surface, the second nearest to the surface, and the layer farthest from the surface. The thickness of the former two layers is approximately 5.5 Å. The three layers have water densities of 1.12 g/cm3, 1.08 g/cm3, and 0.95 g/cm3, respectively, suggesting that there is a strong interaction between the pyrite surface and water molecules and the influence of surface structure on water adsorption reaches a distance of more than 10 Å. Dynamics simulations suggest that the water molecules close to the mineral surfaces are in an orderly arrangement while those far from the surface are disordered.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 121-130
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sorption properties of selected dietary fibers
Autorzy:
Ocieczek, A.
Makala, H.
Powiązania:
https://bibliotekanauki.pl/articles/2083635.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
fibre preparations
water-binding
water-holding capacities
adsorption properties
Opis:
The aim of this study was to characterize and compare the water-binding and water -holding capacities of fibre preparations based on an evaluation of their adsorption properties. The scope of the work included the determination of the water content and activity in the tested material, the determination of adsorption isotherms at 20ºC, a mathematical description of sorption isotherms using the theoretical GAB sorption model as well as an estimation of the microstructural parameters of the tested fibre samples. The following commercial fibre preparations were examined: wheat – WF 200, WF 400, WF 600, potato – KF 200, apple – BJ, oats – BO and carrot – BM. The water content in the analysed fibre preparations covered the range from 6.604 g 100 g–1 for BO fibre to 10.81 g 100 g–1 for BM fibre while their water activity ranged between 0.495 for KF200 fibre and 0.564 for WF200 fibre. The fraction of free water present in carrot (BM) and potato (KF200) fibres was significantly more tightly bound to the product matrix than the fraction of free water in oats fibre (BO). Based on the studies conducted it was established that both the genetic variety and the technological process of micronization had an impact on the water-binding and holding capacities. This was proven on the basis of the evaluation of the adsorption properties and the differences in the surface microstructure of the preparations under examination. Not only the components present in the complex fraction of fibres, but also their physical state are of the utmost importance.
Źródło:
Acta Agrophysica; 2019, 26, 2; 5-18
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on the Efficiency of Grundwater Treatment Process With Adsorption on Activated Alumina
Autorzy:
Szatyłowicz, E.
Skoczko, I.
Powiązania:
https://bibliotekanauki.pl/articles/123695.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
activated alumina
water treatment
adsorption
popular pollutants
Opis:
One of inorganic sorbents used in water treatment technology is activated alumina. It is recommended by the European Commission to remove inorganic impurities, such as arsenic, fluoride, selenium and silicates. The adsorbent is usually applied in a granular form, under flow conditions. It can become absorbent material, increasingly used due to the presence of arsenic beside iron and manganese in groundwater intakes. The aim of the study was to evaluate the effectiveness of groundwater treatment in the technological system containing adsorption on activated alumina. The experiment was performed on test model CE 581 manufactured by G.U.N.T. Hamburg, in which four treatment stages can be extracted. The first stage is used in a gravel filter of grain size 1–2 mm, in the second sand filter of grain size 0.4–0.8 mm. The third and fourth phase includes two adsorbers. The first adsorber comprises activated alumina (Al,sub>2O3) and the other comprises a granular activated carbon. The study was conducted at different speeds of filtration: 5, 10 and 15 m/h. In the raw water samples and the purified water samples after each treatment step the following parameters were determined: pH, O,sub>2 concentration, electrolytic conductivity, SO42-, concentration, NO3- concentration, PO43- concentration, Cl- concentration, color, turbidity, iron and manganese concentration, CODMn, total hardness, calcium hardness, magnesium hardness, content of dissolved substances. The conducted research indicates that optimum filtration rate for most pollution is 15 m/h. Moreover, the presence of activated alumina has contributed to increasing the efficiency of nitrate (V) and phosphate (V) ions removal.
Źródło:
Journal of Ecological Engineering; 2017, 18, 4; 211-218
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of saline water on the synergistic interaction between diesel and Triton X-100 in the flotation of oxidized coal
Autorzy:
Chang, Ziyong
Diallo, Lancine
Feng, Bo
Powiązania:
https://bibliotekanauki.pl/articles/1448948.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
saline water
surfactants
adsorption
flotation
coal oxidation
Opis:
In this study, the effect of medium saline water on the synergistic interaction between diesel and Triton X-100 in the flotation of oxidized coal was investigated. The results showed that the flotation yield of oxidized coal in saline water was higher than that in de-ionized (DI) water due to the promotion of diesel adsorption, which was attributed to the screening of electrostatic repulsion between diesel droplets and coal particles in saline water. Meanwhile, the flotation of oxidized coal could be significantly improved when Triton X-100 was added with diesel as a composite collector, and less Triton X-100 was required in saline water than that in DI water to achieve the same true flotation yield, indicating that saline water could increase the effectiveness of Triton X-100 in improving oxidized coal flotation. A mechanism study revealed that Triton X-100 was able to promote diesel adsorption on oxidized coal through emulsification, thus increasing the surface hydrophobicity of oxidized coal through hydrogen bonding between the headgroups of Triton X-100 and the oxygenated groups on coal surfaces. The non-ionic characteristic of Triton X-100 ensured its capability of enhancing oxidized coal flotation in both DI water and saline water.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 216-225
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 49

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