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Tytuł:
Spectroscopic characteristics of FeI-phthalocyanine
Autorzy:
Kaczmarzyk, T.
Jackowski, T.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/148333.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron phthalocyanine
reduction process
Mössbauer spectroscopy
EPR
DTF
Opis:
Results of Mössbauer and EPR study of a univalent-iron phthalocyanine complex (FeIPc) are presented in this paper. FeIPc has been obtained from FeIIPc by the chemical reduction method in tetrahydrofuran (THF) and dimethoxyethan (DME) solutions. Like in the case of FeI-porphyrin complexes, Mössbauer and EPR data as well as quantum calculations of electronic absorption spectra confirm in this case a low-spin configuration of FeI ions with an unpaired electron located at dz2 orbital. Interaction between FeIPc and THF molecules does not change significantly the electron configuration of FeI ions coordinated to phthalocyanine ligand.
Źródło:
Nukleonika; 2007, 52, supl. 1; 99-103
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Numerical investigation of heat exchange in rotary furnace
Autorzy:
Kolczyk, E.
Miczkowski, Z.
Czernecki, J.
Powiązania:
https://bibliotekanauki.pl/articles/354348.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
numerical simulation
heat exchange
rotary furnace
slag reduction process
Opis:
Process of heat exchange in a rotary furnace during converter slag reduction was modelled.Temperature distribution in the furnace and temperature of the charge (slag) only were examined. Influence of modification of the process gas supply method by changing the number of nozzles on the course of the reduction process was analyzed. It has been found out that application of a nozzle as a submerged flame burner provides possibilities to reach higher charge temperature. Application of more nozzles in the process of converter slag reduction can increase temperature of reduced slag and provide better uniformity of charge heating.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 149-153
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Selected Parameters on Reduction of Converter Slag - Studies with CFD Method
Autorzy:
Kolczyk, E.
Miczkowski, Z.
Czernecki, J.
Powiązania:
https://bibliotekanauki.pl/articles/354046.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
numerical modelling
reduction process
converter slag
Cu-Pb-Fe alloys
Opis:
In this study influence of selected parameters on the process of reduction of converter slag from refining of Cu-Pb-Fe alloy was numerically examined. The process of the slag reduction is carried out in Q 80 converters of Hoboken type for copper removal. Converter slags show high concentration of lead therefore they can be seen as an important component for further processing in rotary-rocking furnaces together with other lead-bearing materials. Three-dimensional simulation was performed using the IPSA (Inter Phase Slip Algorithm) module of two-phase flow from PHOENICS package. Numerical simulations have forecasted influence of changes in the slag chemical composition and the process time on the process course.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 4; 2165-2170
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental investigation of N2O formation in selective non-catalytic NOx reduction processes performed in stoker boiler
Autorzy:
Krawczyk, P.
Powiązania:
https://bibliotekanauki.pl/articles/779234.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
selective non-catalytic reduction process
nitrous oxide emissions
stocker boiler
Opis:
Stoker fired boiler plants are common throughout Eastern Europe. Increasingly strict emission standards will require application of secondary NOx  abatement systems on such boilers. Yet operation of such systems, in addition to reducing NOx  emissions, may also lead to emission of undesirable substances, for example N2O. This paper presents results of experimental tests concerning N2O formation in the selective non-catalytic NOx  emission reduction process (SNCR) in a stoker boiler (WR 25 type). Obtained results lead to an unambiguous conclusion that there is a dependency between the NOx  and N2O concentrations in the exhaust gas when SNCR process is carried out in a coal-fired stoker boiler. Fulfilling new emission standards in the analysed equipment will require 40–50% reduction of NOx  concentration. It should be expected that in such a case the N2O emission will be approximately 55–60 mg/m3, with the NOx  to N2O conversion factor of about 40%.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 4; 104-109
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy of reduced forms of a Fe-tetraphenylporphyrine complex
Autorzy:
Kaczmarzyk, T.
Rutkowska, I.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/148211.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
DFT calculations
electronic structure
iron-(tetraphenyl)porphyrin
Mössbauer spectroscopy
reduction process
Opis:
Molecular and electronic structure changes during successive reduction of a Fe-tetraphenylporphyrin chloride [Fe(III)(TPP):Cl] complex are reported on the basis of Mössbauer spectroscopy and DFT calculations. It is established that the attachment of additional electrons to a neutral Fe(III)(TPP):Cl molecule leads to signifi cant shortening of Fe-N distances at the fi rst stage of the reduction Fe(III)(TPP):Cl →Fe(II)(TPP) and lengthening of these bonds at the second stage Fe(II)(TPP)→Fe(I)(TPP). Changes of other bond lengths of the porphyrin ring also appear but in less degree. Interaction of Fe(II) and Fe(I)(TPP) with tetrahydrofuran (THF) solvent is considered. Electron configuration of Fe(II)(TPP) corresponds to intermediate-spin (S = 1) state and in the case of Fe(I)(TPP) low-spin state (S = ½) is observed. Electron density distribution in Fe(II)- and Fe(I)(TPP) complexes, in association with Mössbauer data, is analyzed. Good correlation between experimental and theoretical results was obtained.
Źródło:
Nukleonika; 2015, 60, 1; 51-55
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Designing a More Effective Supply Chain
Autorzy:
Wild, Tony
Powiązania:
https://bibliotekanauki.pl/articles/504543.pdf
Data publikacji:
2019
Wydawca:
Międzynarodowa Wyższa Szkoła Logistyki i Transportu
Tematy:
inventory
supply chain
inventory reduction
supply chain efficiency
process mapping
time analysis
Opis:
Supply chain can be considered as a series of linked inventories. This paper considers the impact of inventory on the economics of the businesses and the whole chain and discusses causes of inefficiency. In most supply chains the goods are inactive for the majority of the time, and this leads to longer term and therefore less accurate forecasting. The result is typically excess inventory, shortages, and inflexibility. By analysing the wasted time and costs in the supply chain, a clearer view of the whole process can be created. Total supply time can be considered as three components, namely value added time, non-value added process time, and waste time. This basic approach shows where improvements should be focussed. Using this time-based measurement enables more relevant comparison between supply chains than the normal supply chain efficiency ratio.
Źródło:
Logistics and Transport; 2019, 42, 2; 35-40
1734-2015
Pojawia się w:
Logistics and Transport
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical Foundations and Technological Capabilities of Hydrocarbonyl Process while Recovering Copper from Technogenic Wastes
Autorzy:
Fedoseev, I. V.
Barkan, M. S.
Kornev, A. B.
Danilov, A. S.
Powiązania:
https://bibliotekanauki.pl/articles/123296.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
polymetallic sulphide ores
high purity copper
hydrocarbonyl process
reduction ratio
producer gas
Opis:
Secondary processing of waste from metallurgical and other industries becomes an urgent issue in the face of increasing anthropogenic pressure and a shortage of sources of materials. The paper shows the results of chemical and technological studies of processes, executing in the Cu(II) – Cu(I) – Cl- – CO – H2О system. The processing technology of copper-bearing intermediate products multicomponent leaching solutions, permitting high purity copper production at the least economic cost, is proposed.
Źródło:
Journal of Ecological Engineering; 2018, 19, 5; 33-37
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the burnishing process testing by the methods – BRP
Autorzy:
Dyl, T. C.
Powiązania:
https://bibliotekanauki.pl/articles/247792.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
burnishing rolling–pressuring process
BRP
degree of relative strain hardening
surface roughness reduction ratio
surface layer
Opis:
The paper presents choice results of experimental testing of burnishing process by methods BRP – burnishing rolling – pressuring. The burnishing process is a technology of surface plastic forming of machine parts. The plastic deformations are called out by arrangement of strengths causing the superficial crossing the value of tension pressure of the materials. They set the on cold causing except moving the unevenness also the cold work in top layer of workpiece. Studies were conducted for burnishing process of the external cylindrical surfaces. Burnishing carried out for stainless steels. Burnishing technology was proposed using burnished roller (BR-01) in order to give adequate operational characteristics of the shafts neck centrifugal pumps. An important issue to resolve in the article of the research was to obtain appropriate technological quality, and because of the economic aspect of the production and regeneration of machine parts, burnishing applied in exchange for abrasive processing. In experimental studies were obtained in the surface layer increase in hardness and the Abbott-Firestone curve a convex shaped, which given load capacity of the surface will be directly affected by its resistance to wear and corrosion. The burnishing rolling – pressuring process (BRP) were decreased in surface roughness of the top outer cylindrical layer of stainless steel, which can be applied to the centrifugal pump shafts ship.
Źródło:
Journal of KONES; 2016, 23, 3; 121-126
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The burnishing process of the stainless steel in aspect of the reduction roughness and surface hardening
Autorzy:
Dyl, T. C.
Powiązania:
https://bibliotekanauki.pl/articles/246904.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
burnishing rolling–pressuring process
BRP
surface roughness reduction ratio
degree of relative strain hardening
stainless steel
Opis:
In the article were presented influence of technological parameters of burnishing process on the degree of hardness and reduction roughness. Burnishing process carried out for stainless steels X2CrNiMo17-12-2. The experimental research were obtained in the surface layer increase in hardness and the material ratio curve a convex shaped, which, taking into account the load capacity of the surface will be directly affected by its resistance to wear and corrosion. The experimental research by application of the burnishing rolling – pressuring process (BRP) method were made in the Laboratory of Production Engineering at the Department of Marine Maintenance at the Faculty of Marine Engineering at the Gdynia Maritime University. After the studies it was found that the hardness of the surface layer and the roughness of the shaft necks an important influenced by technological parameters of processing (burnishing speed, feed and depth of burnishing). The objective of applying burnishing process may be, for example, the need to increase surface smoothness and dimensional accuracy of part. To achieve the objectives strengthen and smooth of burnishing stainless steel should be used the one pass burnisher roller and feed fn = 0.2 mm/rev and disk burnishing tool feed an = 1.0 mm and burnishing speed vn = 70 m/min.
Źródło:
Journal of KONES; 2017, 24, 3; 63-69
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of processing parameters on surface roughness and strain hardening of two-phase stainless steel
Autorzy:
Dyl, Tomasz Cyryl
Charchalis, Adam
Stradomski, Grzegorz
Rydz, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/242598.pdf
Data publikacji:
2019
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
burnishing process
index of surface roughness reduction
degree of relative strain hardening
two-phase stainless steel
Opis:
Products used in the construction of machines and shipbuilding as well as petrochemical industry, such as shafts, bars, pipes and the like from two-phase stainless steel are currently very popular. It is required that they meet certain quality criteria. They must be characterized by suitable properties of the surface layer to meet the requirements of potential buyers. In the article impact of processing parameters on the degree of relative strain hardening and index of surface roughness reduction were presented. The burnishing process was carried out for two-phase stainless steel. Burnishing process of the shafts neck was performed using burnisher roller. The experimental research were obtained in the surface layer increase in hardness and the material ratio curve a convex shaped, which, taking into account the load capacity of the surface will be directly affected by its resistance to wear and corrosion. The experimental research by application of the burnishing process was made in the Laboratory of Production Engineering. After the studies it was found that the hardness of the surface layer and the roughness of the shaft necks an important influenced by technological parameters of processing (burnishing speed, feed rate and depth of burnishing). The objective of applying burnishing process may be, for example, the need to increase surface smoothness and dimensional accuracy of part.
Źródło:
Journal of KONES; 2019, 26, 2; 37-44
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Consciousness: effect of coaching process and specifics through AI usage
Autorzy:
Movsumova, Ekaterina
Alexandrov, Vasily
Rudenko, Larisa
Aizen, Valeria
Sidelnikova, Svetlana
Voytko, Mikhail
Powiązania:
https://bibliotekanauki.pl/articles/1827698.pdf
Data publikacji:
2020-11
Wydawca:
Szkoła Główna Handlowa w Warszawie
Tematy:
AI-assisted tool
coaching process
stress reduction
clarity increase
coaching effectiveness
confidential request
human coach-bot
Opis:
The main purpose of the article is to investigate how coaching itself affects a person and evaluate it as an effective tool. The second goal is to find out what the features of coaching with the use of an AI-based assistant are. The problem of studying the effectiveness of coaching is indicated by the purpose of finding out, based on the results of the work in the session, to what extent the result obtained will lead the respondent to specific actions. To this end, the main measurable metrics were stress level, willingness to act, and clarity regarding the request. The study confirmed that the majority of sessions had a “positive” dynamic in at least one of the consciousness components (an increase of clarity or willingness to act and decrease of stress). The key implication is that it is important to keep a coachee away from stress to create space for clarity and willingness to act. The research results show that an AI-based tool is more effective in new requests with high importance for a client regarding willingness to act and clarity, confidential requests in terms of privacy, and sensitivity regarding clarity. A coach is perceived as overall stronger in usefulness, effectiveness, and stress reduction. Analyzing the results of the coach-AI-assistant interaction, the study shows that AI broadens the vision of coaches. From the point of view of the threat of the coach-bot interaction, there is a bottleneck that emerged during the feedback process during the study. In several sessions, coaches were not able to develop an emotional connection well enough through written dialogue – due to the absence of face-to-face contact. One of the key outcomes regarding the “client-coach” interaction is the high importance of emotional contact.
Źródło:
e-mentor. Czasopismo naukowe Szkoły Głównej Handlowej w Warszawie; 2020, 86, 4; 79-86
1731-6758
1731-7428
Pojawia się w:
e-mentor. Czasopismo naukowe Szkoły Głównej Handlowej w Warszawie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of the hazard rate function with a reduction of bias and variance at the boundary
Autorzy:
Janiszewska, Bożena
Różański, Roman
Powiązania:
https://bibliotekanauki.pl/articles/729696.pdf
Data publikacji:
2005
Wydawca:
Uniwersytet Zielonogórski. Wydział Matematyki, Informatyki i Ekonometrii
Tematy:
hazard rate function
multiplicative intensity point process model
Ramlau-Hansen kernel estimator
reduction of the bias
reflection
transformation
Opis:
In the article, we propose a new estimator of the hazard rate function in the framework of the multiplicative point process intensity model. The technique combines the reflection method and the method of transformation. The new method eliminates the boundary effect for suitably selected transformations reducing the bias at the boundary and keeping the asymptotics of the variance. The transformation depends on a pre-estimate of the logarithmic derivative of the hazard function at the boundary.
Źródło:
Discussiones Mathematicae Probability and Statistics; 2005, 25, 1; 5-37
1509-9423
Pojawia się w:
Discussiones Mathematicae Probability and Statistics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Random projections and Hotelling’s T2 statistics for change detection in high-dimensional data streams
Autorzy:
Skubalska-Rafajłowicz, E.
Powiązania:
https://bibliotekanauki.pl/articles/331099.pdf
Data publikacji:
2013
Wydawca:
Uniwersytet Zielonogórski. Oficyna Wydawnicza
Tematy:
change detection
multidimensional control charts
dimensionality reduction
random projections
process monitoring
wykrywanie zmian
karta kontrolna
redukcja wymiarowości
monitorowanie procesu
Opis:
The method of change (or anomaly) detection in high-dimensional discrete-time processes using a multivariate Hotelling chart is presented. We use normal random projections as a method of dimensionality reduction. We indicate diagnostic properties of the Hotelling control chart applied to data projected onto a random subspace of Rn. We examine the random projection method using artificial noisy image sequences as examples.
Źródło:
International Journal of Applied Mathematics and Computer Science; 2013, 23, 2; 447-461
1641-876X
2083-8492
Pojawia się w:
International Journal of Applied Mathematics and Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zero waste: an innovation for less polluting emission processes, resource management practices and policies
Autorzy:
Ekanem, C.H.
Ekanem, H.E.
Eyenaka, F.D.
Isaiah, E.A.
Powiązania:
https://bibliotekanauki.pl/articles/11311.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
waste reduction
innovation
pollution
emission process
resource management
management practice
management policy
greenhouse gas
climate change
municipal solid waste
biodegradation
Opis:
The rising levels of greenhouse gases (GHGs) in the Earth‟s atmosphere have the potential to cause changes in our climate. Some of these emission increases can be traced directly to solid waste. Landfills are among the largest emitters of carbon dioxide and methane, the key GHGs. Thus, effective mitigation of these emissions through formalization of waste reduction into the waste management system to reduce land filling could provide environmental benefits of reducing the adverse impacts of climate change. This paper therefore proposes waste prevention and recycling-jointly referred to as waste reduction as better and most potent strategies for the management of solid waste and for reducing greenhouse gases and calls on both the government and private agencies to check or control the increasing pollution or abuse of the environment by enforcing compliance with the laid out Policies, Pronouncements, Regulations and enacted Legislation especially in the developing countries. The study concludes that by choosing to prevent waste and recycle, less waste will be generated, the need for landfill will be minimal, energy demand will decrease, fewer fossil fuels will be burned and less methane and carbon dioxide will be emitted to the atmosphere which helps to curb climate change.
Źródło:
International Letters of Natural Sciences; 2013, 05
2300-9675
Pojawia się w:
International Letters of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of the type of quench aging after hyperquenching on the mechanical strength properties of AW-7020 alloy
Autorzy:
Hajdukiewicz, G.
Powiązania:
https://bibliotekanauki.pl/articles/247335.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
AW-7020 alloy
age hardening
natural aging
artificial aging
hyperquenching strength limit
rupture elongation
fracture area reduction
intermediate state
age process hardening
Opis:
The article attempts to determine the influence of selected types of the heat treatment on the strength properties of the AW-7020 alloy used in the shipbuilding industry. The text presents information on the applied types of heat treatment. There are presented the results of the static tensile test of the material after its earlier hyperquenching and aging (natural and artificial) as well as comparison to the test results of the alloy without heat treatment. To illustrate the nature of the supersaturation and aging process, a test was carried out for a series of samples in a transitional state. During the tests for all the samples were determined: elongation at rupture and reduction of area at fracture, strength limit Rm and proof stress Re0.2. The results of the tests showed that the choice of the type of aging after saturation has significant importance for the strength properties of the AW-7020 alloy. It has been shown that it is possible to significantly accelerate the achievement of higher strength properties of the tested alloy, replacing the natural aging of the material with artificial aging.
Źródło:
Journal of KONES; 2018, 25, 2; 141-148
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
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