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Tytuł:
Combustion in a supercharged biomass gas engine with micro-pilot ignition - effects of injection pressure and amount of diesel fuel
Autorzy:
Tomita, E.
Fukatani, N.
Kawahara, N.
Maruyama, K.
Komoda, T.
Powiązania:
https://bibliotekanauki.pl/articles/243110.pdf
Data publikacji:
2007
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
internal combustion engine
cogeneration
pyrolysis gas
biomass gas
visualization
Opis:
It is one of the solutions to use biomass as fuel in order to realize a sustainable society and to reduce carbon dioxide emission .A single cylinder with supercharged and micro-pilot gas engine operated with four kinds of pyrolysis gas as fuel for cogeneration use. The effects of injection pressure and amount of diesel fuel on engine performance and exhaust emissions were investigated. The combustion periods of initial and main stages were determined from the analysis of mass fraction burned. The combustion process was also visualized with a colour highspeed video camera. Main results obtained in this study are as follows: When the amount of diesel fuel increased in the same injection pressure, smoke was exhausted. However, the smoke was reduced with higher injection pressure. The period of the initial combustion is almost the same even if injection pressure and amount of diesel fuel increases. Therefore, it is enough to ignite the mixture with small amount of diesel fuel. For the case with lower calorific gas, the period of main combustion was shortened owing to the combustion of diesel fuel when the amount of diesel fuel increases. When the mixture contains much hydrogen, the period of main combustion does not become small in higher injection pressure and larger amount of diesel fuel. On the other hand, when the mixture does not contain much hydrogen, the effect of diesel fuel becomes strong.
Źródło:
Journal of KONES; 2007, 14, 2; 513-520
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Use of HPLC, Py-GCMS, FTIR methods in the studies of the composition of soil dissolved organic matter
Wykorzystanie HPLC, Py-GCMS i FTIR w badaniach składu rozpuszczalnej materii organicznej gleb
Autorzy:
Rosa, E.
Debska, B.
Banach-Szott, M.
Tobiasova, E.
Powiązania:
https://bibliotekanauki.pl/articles/905677.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
soil
organic matter
soil composition
analysis method
high performance liquid chromatography
Py-GCMS zob.pyrolysis gas chromatography mass spectrometry
dissolved organic matter
FTIR method
pyrolysis gas chromatography mass spectrometry
Opis:
The study has determined the composition of dissolved organic matter in Luvisols, Fluvisols and Histosols using spectroscopic (FTIR) and chromatographic (HPLC and Py-GCMS) methods. It has been found that aliphatic hydrocarbons (linear) containing from 4 to 12 atoms of carbon constitute the dominant group of compounds included in the dissolved organic matter (DOC). The preparations isolated from Histosols and Luvisols demonstrated a higher proportion of hydrophobic fraction with a longer retention time probably containing more compounds with long-chain aliphatic and simple aromatic structure than the DOC of Fluvisols. The differences in infrared spectra are evident particularly in the wave number between 1650–1030 cm⁻¹. The DOC of Histosols is richer in aromatic compounds (range 1620 cm⁻¹) but the DOC of Luvisols and Fluvisols is richer in alkene chains and hydroxyl (OH) and methoxy (OCH₃) groups. The results showed differences in the composition of the DOM across the soils, caused their genesis.
W pracy badano skład rozpuszczalnej materii organicznej (RMO) gleb (Luvisols, Fluvisols and Histosols) przy zastosowaniu metod spektroskopowych (FTIR) oraz chromatograficznych (HPLC i Py-GCMS). Stwierdzono, że dominującą grupą związków wchodzących w skład RMO są węglowodory alifatyczne (łańcuchowe) zawierające od 4 do 12 atomów węgla. Preparaty RMO wyizolowane z torfu i gleby płowej charakteryzujące się wyższym udziałem frakcji hydrofobowych o najdłuższym czasie retencji, zawierały najprawdopodobniej więcej związków o długich łańcuchach alifatycznych oraz proste struktury aromatyczne w porównaniu z RMO mady. Przebieg widm w podczerwieni wyraźnie wskazał różnicę w składzie badanych preparatów RMO, szczególnie w zakresie liczb falowych między 1650-1030 cm⁻¹. Preparaty RMO wyizolowane z torfu były bogatsze w związki aromatyczne (pasmo 1620 cm⁻¹) a frakcja RMO wyizolowana z gleby płowej i mady ciężkiej była bogatsza w łańcuchy alkenowe i grupy hydroksylowe (OH) i metoksylowe (OCH₃). Otrzymane wyniki badań wykazały różnice w składzie RMO pomiędzy glebami, wynikające z ich genezy.
Źródło:
Polish Journal of Soil Science; 2015, 48, 1
0079-2985
Pojawia się w:
Polish Journal of Soil Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermogenic gases generated from coals and shales of the Upper Silesian and Lublin basins : hydrous pyrolysis approach
Autorzy:
Kotarba, Maciej J.
Bilkiewicz, Elżbieta
Jurek, Krzysztof
Waliczek, Marta
Więcław, Dariusz
Zych, Hieronim
Powiązania:
https://bibliotekanauki.pl/articles/2059608.pdf
Data publikacji:
2021
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
hydrous pyrolysis gas
gaseous hydrocarbon
carbon dioxide
molecular nitrogen
stable C, H, N isotopes
Upper Silesian
Lublin Coal basins
Opis:
In order to provide a better characterization of the origin and volume of thermogenic gas generation hydrous pyrolysis (HP) experiments were performed on coals and shales at 330 and 360oC for 72 hours. The maturity range of coals and shales used for HP varies from 0.57 to 0.92% Ro. The maturity increase caused by HP at 330 and 360oC ranges from 1.32 to 1.39% and from 1.71 to 1.83%, respectively. δ13C of CH4, 2H6, C3H6 and n-C4H10 in HP gases versus their reciprocal C-number have a concave relationship, and therefore do not follow a linear trend. δ2H of CH4, 2H6 and C3H6 in HP gases versus their reciprocal H-number show both linear and convex-concave relationships. The growth of CO2 yields during HP was higher for shales than for coals. H2S yields from shales are higher than from coals, which can be connected with catalytic and adsorbed influence of shale matrix. H2 was also generated in notable quantities from water and organic matter of coals and bigger amounts from shales. N2 yields grow with the increase of Ro after 3oC HP and it is more enriched in 15N isotope than after 330C.
Źródło:
Geological Quarterly; 2021, 65, 2; 65: 26
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physico-chemical characteristics of fuel gas mixtures
Charakterystyka fizykochemiczna mieszanek gazów paliwowych
Autorzy:
Pavlenko, Anatoliy
Slowak, Anna Maria
Powiązania:
https://bibliotekanauki.pl/articles/402551.pdf
Data publikacji:
2019
Wydawca:
Politechnika Świętokrzyska w Kielcach. Wydawnictwo PŚw
Tematy:
properties of combustible gas mixtures
pyrolysis gas
artificial gas
combustion of gas
mixture
generator gas
właściwości palnych mieszanek gazów
gaz pirolityczny
gaz sztuczny
spalanie mieszaniny gazów
gaz generatorowy
Opis:
The article presents data on changes in physical and chemical properties of mixtures of generator gases with natural gas and the issue of the optimal ratio of these gases in the mixture. The results of research on the basic properties of flammable mixture of generator gases and natural gas are presented, on the basis of which the optimal composition of the mixture was proposed.
W artykule przedstawiono dane dotyczące zmian właściwości fizycznych i chemicznych mieszanin gazów generatorowych z gazem ziemnym oraz zagadnienie optymalnego stosunku tych gazów w mieszaninie. Przedstawiono wyniki badań podstawowych właściwości palnych mieszaniny gazów generatorowych i gazu ziemnego, na podstawie których zaproponowano optymalny skład mieszaniny.
Źródło:
Structure and Environment; 2019, 11, 3; 227-234
2081-1500
Pojawia się w:
Structure and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of pyrolysis process in processing of mixed food wastes
Autorzy:
Grycová, B.
Koutník, I.
Pryszcz, A.
Kaloč, M.
Powiązania:
https://bibliotekanauki.pl/articles/778553.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
pyrolysis
gas chromatography
food waste
Opis:
The food industry produces large amounts of solid and also liquid wastes. Different waste materials and their mixtures were pyrolysed in the laboratory pyrolysis unit to a final temperature of 800°C with a 10 minute delay at the final temperature. After the pyrolysis process of the selected wastes a mass balance of the resulting products, off-line analysis of the pyrolysis gas and evaluation of solid and liquid products were carried out. The highest concentration of methane, hydrogen and carbon monoxide were analyzed during the 4th gas sampling at a temperature of approx. 720–780°C. The concentration of hydrogen was measured in the range from 22 to 40 vol.%. The resulting iodine numbers of samples CHFO, DS, DSFW reach values that indicate the possibility of using them to produce the so-called “disposable sorbents” in wastewater treatment. The WC condensate can be directed to further processing and upgrading for energy use.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 1; 19-23
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimisation of the performance of a pyrolysis reactor for G50 chips
Autorzy:
Dhaundiyal, Alok
Singh, Suraj
Powiązania:
https://bibliotekanauki.pl/articles/240925.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
biomass
thermal analysis
pyrolysis
gas yield
performance index
Opis:
The aim of any industrial plant, which is dealing in the energy sector, is to maximise the revenue generation at the lowest production cost. It can be carried out either by optimizing the manpower or by improving the performance index of the overall unit. This paper focuses on the optimisation of a biomass power plant which is powered by G50 hardwood chips (Austrian standard for biomass chips). The experiments are conducted at different operating conditions. The overall effect of the enhanced abilities of a reactor on the power generation is examined. The output enthalpy of a generated gas, the gas yield of a reactor and the driving mechanism of the pyrolysis are examined in this analysis. The thermal efficiency of the plant is found to vary from 44 to 47% at 400°C, whereas it is 44 to 48% for running the same unit at 600°C. The transient thermal condition is solved with the help of the lumped capacitance method. The thermal efficiency of the same design, within the constraint limit, is enhanced by 5.5%, whereas the enthalpy of the produced gas is magnified by 49.49% through nonlinear optimisation. The temperature of biomass should be homogenous, and the ramping rate must be very high. The 16% rise in temperature of the reactor is required to reduce the mass yield by 20.17%. The gas yield of the reactor is increased by up to 85%. The thermal assessment indicates that the bed is thermally thin, thus the exterior heat transfer rate is a deciding factor of the pyrolysis in the reactor.
Źródło:
Archives of Thermodynamics; 2020, 41, 1; 245-263
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of hygienisation of sewage sludge on the process of pyrolysis
Autorzy:
Cizkova, A.
Juchelkova, D.
Raclavska, H.
Powiązania:
https://bibliotekanauki.pl/articles/185279.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
wapno
gaz
osad
pyrolysis
sewage sludge
pyrolytic gas
lime
Opis:
The aim of this work was to determine the influence of liming on the process of pyrolysis. Three samples of sludge from two wastewater treatment plants were selected for this study on pyrolysis: sludge without liming and limed sludge from the Central Wastewater Treatment Plant in Ostrava and sludge from the Wastewater Treatment Plant in Sviadnov. The samples had different content of calcite (CaCO3). The limed sludge contained 7% of CaCO3, sludge without liming 3.8% and sludge without liming from WWTP Sviadnov contained 0.5% of calcite. The results of laboratory pyrolysis proved that limed sludge released the maximum amount of carbon - 55.46 %, while sludge without liming from WWTP Sviadnov released only 48.92%. Calcite produces during its decomposition CaO and the product influences the pyrolysis process because it supports cracking of volatile organic compounds.
Źródło:
Chemical and Process Engineering; 2011, 32, 1; 57-68
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Innovative Method of Forecasting the Generator Gas Composition after the Process of Pyrolysis and Gasification
Autorzy:
Slowak, Anna Maria
Powiązania:
https://bibliotekanauki.pl/articles/2174900.pdf
Data publikacji:
2022
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
gasification
pyrolysis
biomass
regenerative energy
synthetic gas
mathematical modeling
Gibbs energy
Opis:
The article presents a new approach to forecasting producer gas composition. Thermochemical treatment of biomass was presented as an effective method of producing flammable gas. The methods of predicting the gas composition of the generator are described, and then its efficiency depends on the device’s parameters. In order to create a method for forecasting gas composition, the authors’ works were used as the basis on which the energy characteristics of the gases obtained were assessed. It was assumed in this paper that it is essential to understand the influence of each parameter on the energy characteristics of the gas. It made it possible to optimize the composition and predict thermal characteristics. This article presents the results of experimental studies on biomass gasification and a mathematical model based on Gibbs free energy.
Źródło:
Rocznik Ochrona Środowiska; 2022, 24; 97--109
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanostructured CdO thin films for LPG and CO2 gas sensor prepared by spray pyrolisis technique
Autorzy:
Bari, R. H.
Patil, S. B.
Powiązania:
https://bibliotekanauki.pl/articles/411726.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
spray pyrolysis techniques
LPG
CO2 sensor
nanostructured CdO
gas response
Opis:
Nanostructured CdO thin films were deposited by spray pyrolysis techniques at different spray deposition time on glass substrates. Nanostructured CdO thin films was prepared using 0.05 M of cadmium acetate dehydrate (CH3COO) 2Cd•2H2O) was dissolved in the deionised water. These thin films were annealing in air at temperatures 500 °C for 60 min. The thickness of the films, crystallite and grain size were observed to increase with the increase in spray deposition time. As prepared thin films were characterized using XRD, FE-SEM and EDAX. The XRD analysis shows that CdO films were cubic structured. The electrical and gas sensing properties of these films were investigated. Prepared nanostructure CdO thin films show LPG (S = 1600) and CO2 (S = 435) gas response at different operating temperature. Gas response, selectivity, response and recovery time of the sensor were measured and presented.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 18; 31-46
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of single wood particle pyrolysis using particle image velocimetry
Autorzy:
Kluska, J.
Ronewicz, K.
Kardaś, D.
Powiązania:
https://bibliotekanauki.pl/articles/240493.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pyrolysis
particle image velocimetry
gas cushion
piroliza
anemometria obrazowa
poduszka gazowa
Opis:
This study examines the pyrolysis of a single cylindrical wood particle using particle image velocimetry (PIV). The pyrolysis was conducted inside a pyrolysis reactor designed for this purpose. The experimental setup presented in this paper is capable of effectively characterizing the intensity of pyrolysis based on velocity distribution in the vicinity of wood particles. The results of the gas velocity distribution show that evaporation of moisture has as a major impact on the formation of the gas cushion as devolatilization.
Źródło:
Archives of Thermodynamics; 2018, 39, 2; 3-13
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prediction of coking dynamics for wet coal charge
Autorzy:
Kardaś, D.
Polesek-Karczewska, S.
Ciżmiński, P.
Stelmach, S.
Powiązania:
https://bibliotekanauki.pl/articles/185719.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pyrolysis
devolatilisation
vaporisation
internal gas pressure
piroliza
odparowanie
wewnętrzne ciśnienie gazu
Opis:
A one-dimensional transient mathematical model describing thermal and flow phenomena during coal coking in an oven chamber was studied in the paper. It also accounts for heat conduction in the ceramic oven wall when assuming a constant temperature at the heating channel side. The model was solved numerically using partly implicit methods for gas flow and heat transfer problems. The histories of temperature, gas evolution and internal pressure were presented and analysed. The theoretical predictions of temperature change in the centre plane of the coke oven were compared with industrialscale measurements. Both, the experimental data and obtained numerical results show that moisture content determines the coking process dynamics, lagging the temperature increase above the water steam evaporation temperature and in consequence the total coking time. The phenomenon of internal pressure generation in the context of overlapping effects of simultaneously occurring coal transitions – devolatilisation and coal permeability decrease under plastic stage – was also discussed.
Źródło:
Chemical and Process Engineering; 2015, 36, 3; 291-303
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of operating parameters on production of bio-oil from fast pyrolysis of maize stalk in bubbling fluidized bed reactor
Autorzy:
Ali, N.
Saleem, M.
Shahzad, K.
Hussain, S.
Chughtai, A.
Powiązania:
https://bibliotekanauki.pl/articles/779892.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
fast pyrolysis
bio-oil
temperature
particle size
carrier gas flow rate
maize stalk
Opis:
The yield and composition of pyrolysis products depend on the characteristics of feed stock and process operating parameters. Effect of particle size, reaction temperature and carrier gas flow rate on the yield of bio-oil from fast pyrolysis of Pakistani maize stalk was investigated. Pyrolysis experiments were performed at temperature range of 360-540°C, feed particle size of 1-2 mm and carrier gas flow rate of 7.0-13.0 m3/h (0.61.1 m/s superficial velocity). Bio-oil yield increased with the increase of temperature followed by a decreasing trend. The maximum yield of bio-oil obtained was 42 wt% at a temperature of 490°C with the particle size of around 1.0 mm and carrier gas flow rate of 11.0 m3/h (0.9 m/s superficial velocity). High temperatures resulted in the higher ratios of char and non-condensable gas.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 3; 88-96
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energy Balance Sheet of a Semi Operational Thermic System
Autorzy:
Honus, S.
Sassmanová, V.
Frantík, J.
Bukowski, P.
Juchelková, D.
Powiązania:
https://bibliotekanauki.pl/articles/185341.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bilans energetyczny
piroliza
odpady
spalanie
gaz procesowy
energy balance
pyrolysis
waste
combustion
process gas
Opis:
The article is focused onthe energetical balance of a technical system for the conversion of crushed tyres by pyrolysis. Process temperatures were set in the range from 500 to 650°C. Mass input of the material was 30 kg per hour. The aim of the article is to answer the following questions as regards the individual products: Under which process conditions can the highest quality of the individual products related to energy be reached? How does the thermal efficiency of the system change in reaction to various conditions of the process? On the basis of the experimental measurements and calculations, apart from other things, it was discovered that the pyrolysis liquid reaches the highest energetic value, i.e. 42.7 MJ.kg-1, out of all the individual products of the pyrolysis process. Generated pyrolysis gas disposes of the highest lower calorific value 37.1 MJ.kg-1 and the pyrolysis coke disposes of the maximum 30.9 MJ kg-1. From the energetic balance, the thermal efficiency of the experimental unit under the stated operational modes ranging from about 52 % to 56 % has been estimated. Individual findings are elaborated on detail in the article.
Źródło:
Chemical and Process Engineering; 2014, 35, 3; 317-329
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on spray pyrolised nanostructured SnO2 thin films for H2 gas sensing application
Autorzy:
Bari, R. H.
Patil, S. B.
Powiązania:
https://bibliotekanauki.pl/articles/411918.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Spray Pyrolysis
Nanostructured SnO2
thin films
H2 gas sensor
Microstrain
Electrical conductivity
Opis:
The objective of this work is to study the influence of pyrolysis temperature on structural, surface morphology and gas sensing properties of the nanostructured SnO2 thin films prepared by spray pyrolysis technique. These films were characterized for the structural, morphological and elemental composition carried by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrophotometer (EDAX). The information of crystallite size, dislocation density and microstrain is obtained from the full width-at half- maximum (FWHM) of the diffraction peaks. Effect of sprayed deposition temperature on H2 gas sensing performance and electrical properties were studied using static gas sensing system. The sensor (Tpyr. = 350 °C) showed high gas response (S = 1200 at 350 °C) on exposure of 500 ppm of H2 and high selectivity against other gases The results are discussed and interpreted.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 17, 2; 125-141
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Temperature Pyrolysis Process of Used Tires on the Quality of Output Products
Autorzy:
Jasminská, N.
Brestovič, T.
Čarnogurská, M.
Powiązania:
https://bibliotekanauki.pl/articles/386859.pdf
Data publikacji:
2013
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
piroliza
zużyte opony
temperatura
gaz pirolityczny
olej pirolityczny
pyrolysis
used tires
temperature
pyrolytic gas
pyrolytic oil
solid residue
Opis:
Pyrolysis together with gasification and combustion create a group of so called thermic processes. Unlike the combustion it is based on thermic decomposition of organic materials without any access of oxidative media. Within the pyrolytic process, three main fractions are created: solid residue, pyrolytic gas and organic liquid product - pyrolytic oil. The presented article examines the effects of pyrolysis operational conditions (above all, temperature) on gas products, solid residues and liquid fractions.
Źródło:
Acta Mechanica et Automatica; 2013, 7, 1; 20-25
1898-4088
2300-5319
Pojawia się w:
Acta Mechanica et Automatica
Dostawca treści:
Biblioteka Nauki
Artykuł
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