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Wyszukujesz frazę "pyrochlores" wg kryterium: Temat


Wyświetlanie 1-4 z 4
Tytuł:
Synthesis and Characterization of Thermal Properties of Type Eu2O3-ZrO2 Sinters
Autorzy:
Jucha, S.
Moskal, G.
Mikuśkiewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/352258.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pyrochlores
europium zirconates
thermal diffusivity
TBC
Opis:
The oxides with pyrochlore or defected fluorite structure are a potential alternative ceramic materials for now widely used yttria-stabilized zirconia 8YSZ in the application for the insulation layer of thermal barrier coatings systems. This paper presents a procedure of synthesis of europium zirconate of Eu2Zr2O7 type, by the method of high temperature sintering under pressure. The analysis of the effect of the powders` homogenization methods on homogeneity of final sintered material showed that the highest homogeneity can be obtained after mechanical mixing in alcohol. Moreover, the DSC investigation carried out on a mixture of powders before the sintering process and on the material after high temperature sintering under pressure, suggest the synthesis of a new phase an europium zirconate Eu2Zr2O7 with the pyrochlore structure. Obtained phase was characterized by stability over the entire range of tested temperature, i.e. to 1450°C. The resulting material based on europium zirconate has a lower coefficient of thermal diffusivity than the now widely used 8YSZ.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2B; 1121-1128
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solid State Synthesis of Europium Zirconate Based Material
Autorzy:
Mikuśkiewicz, M.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/353816.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
europium zirconates
solid-state synthesis
pyrochlores
TBC
Opis:
In the article, the characterization of the microstructure, phase composition and distribution of elements in the Eu2 O3 -ZrO2 sintered materials obtained by four different ways of powders’ homogenization (mixing) process and different temperature of sintering process is shown. The feedstock powders with an average mole ratio of ZrO2 to Eu2 O3 equal 74% to 26% were used as an initial material. The principal aim of the investigation was characterization of differences in the microstructure of the same type of ceramics, however, prepared via different mixing and manufacturing processes. The range of the investigation covered a characterization of these materials via phase identification of all samples by XRD (X-ray diffraction) and characterization of internal morphology of the specimens with detailed analysis of elements distributions by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometry). The aim of the following investigation is to characterize the possibilities of the solid state synthesis of the europium zirconate based materials, dedicated for TBC applications.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1343-1352
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization and Thermal Diffusivity of Holmium and Praseodymium Zirconates
Autorzy:
Stopyra, M.
Niemiec, D.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/352244.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pyrochlores
synthesis
polymerized-complex method
holmium zirconate
praseodymium zirconate
thermal diffusivity
Opis:
A2B2O7 oxides with pyrochlore or defected fluorite structure are among the most promising candidates for insulation layer material in thermal barrier coatings. The present paper presents the procedure of synthesis of holmium zirconate Ho2Zr2O7 and praseodymium zirconate Pr2Zr2O7 via Polymerized-Complex Method (PCM). Thermal analysis of precursor revealed that after calcination at relatively low temperature (700°C) fine-crystalline, single-phase material is obtained. Thermal diffusivity was measured in temperature range 25-200°C, Ho2Zr2O7 exhibits lower thermal diffusivity than Pr2Zr2O7. Additionally, PrHoZr2O7 was synthesized. The powder in as-calcined condition is single-phase, but during the sintering decomposition of solid solution took place and Ho-rich phase precipitated. This material exhibited the best insulating properties among the tested ones.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2B; 1249-1254
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The formation of pyrochlores during plasma spraying of REO and zirconia oxides powder mixture
Autorzy:
Kubaszek, Tadeusz
Nowak, Wojciech J.
Pędrak, Paweł
Góral, Marek
Rybus, Kinga
Ślemp, Karol
Powiązania:
https://bibliotekanauki.pl/articles/95173.pdf
Data publikacji:
2019
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
thermal barrier coatings
plasma spraying
ceramic coating
rare earth oxides
pyrochlores
porosity
powłokowe bariery cieplne
natryskiwanie plazmowe
powłoki ceramiczne
tlenki metali ziem rzadkich
pirochlory
porowatość
Opis:
The pyrochlores are the promising low-thermal conductive materials for Thermal Barrier Coatings applications. In present work the concept of pyrochlore formation during APS spraying of ZrO2 and ReO was analyzed. The specially prepared agglomerated mixtures of ZrO2 with Nd2O3, Yb2O3, Er2O3 and Gd2O3 oxides were plasma sprayed using A60 plasma torch on NiCoCrAlY-type bond coat. The influence of plasma gasses composition on coatings’ microstructure was investigated. The results of XRD phase analysis proved formation of pyrochlores from Gd2O3 +ZrO2 and Nd2O3+ZrO2 mixtures. The formation of Er4O12Zr3 from Er2O3+ ZrO2 mixture as well as Zr3Yb4 from Yb2O3+ ZrO2 powder was detected. The presence of pure rare earth oxides (REO) and zirconia oxides was observed in all types of sprayed coatings. The microstructural assessment showed differences in porosity and thickness of obtained ceramic coatings depending of type of REO oxides. The analysis of results showed that it is possible to obtain pyrochlore ceramic coatings from pure oxides mixture. The plasma energy was not efficient for full formation of pyrochlores, therefore the presence of pure oxides was observed.
Źródło:
Journal of Mechanical and Energy Engineering; 2019, 3, 2; 141-147
2544-0780
2544-1671
Pojawia się w:
Journal of Mechanical and Energy Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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