- Tytuł:
- Isotope effects on selected physicochemical properties of nitromethane and 1-pentanol
- Autorzy:
-
Makowska, A.
Szydłowski, J. - Powiązania:
- https://bibliotekanauki.pl/articles/148594.pdf
- Data publikacji:
- 2006
- Wydawca:
- Instytut Chemii i Techniki Jądrowej
- Tematy:
-
deuterium
isotope effects
density
viscosity
speed of sound
nitromethane
1-pentanol - Opis:
- Densities, kinematic viscosities, speed of sound and refractive indices of nitromethane and 1-pentanol and their deuterated derivatives CD3NO2 and C5H11OD were measured. The data obtained allowed to calculate molar volumes, dynamic viscosities, isentropic compressibilities and isobaric thermal expansion. Deuterium isotope effect on the selected physicochemical properties of both nitromethane and 1-pentanol has been determined. Large isotope effects characterizing density, viscosity and speed of sound are observed for nitromethane and much smaller for 1-pentanol. Isotope effects on molar volume are small both for nitromethane and 1-pentanol, but of the opposite sign. These observations are in agreement with the expectations.
- Źródło:
-
Nukleonika; 2006, 51,suppl.2; 81-85
0029-5922
1508-5791 - Pojawia się w:
- Nukleonika
- Dostawca treści:
- Biblioteka Nauki
Artykuł