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Wyszukujesz frazę "nuclear spectroscopy" wg kryterium: Temat


Wyświetlanie 1-10 z 10
Tytuł:
Working parameters of the electron - beam-generated ion source for ISOL facilities
Autorzy:
Yushkevich, Y. V.
Turek, M.
Mączka, D.
Pyszniak, K.
Słowiński, B.
Vaganov, Y. A.
Zubrzycki, J.
Powiązania:
https://bibliotekanauki.pl/articles/146648.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
on-line isotope separation
short-lived nuclides
nuclear spectroscopy
ion sources
Opis:
An electron-beam generated plasma (EBGP) ion source for nuclear spectroscopy purposes at YASNAPP (YAdernaya Spektroskopya NA Putchkah Protonov - nuclear spectroscopy using proton beams) isotope separation on-line facility is presented. Working conditions both in on- and off-line mode are presented and discussed. Formation of a potential trap inside a discharge chamber is an advantage of the presented construction, enabling relatively high ionization efficiencies (2-5%) even for hard-to-ionize elements like Be, Ti, V, Zr, Nb, Mo, Tc, Ru, Rd, Hf, Ta, W, Re, Os, Ir, Pt. The paper presents estimation of critical values of working parameters that enable formation of the ion trap leading in consequence to high efficiency of ionization. The optimal temperature of the discharge chamber and cathode walls is found to be in the range 2600-2800 K. Calculations of the output rates of ions produced in the on-line mode are also presented as well as the constraints on the half-life time of obtained nuclides imposed by construction details like the target material and its thickness.
Źródło:
Nukleonika; 2012, 57, 3; 351-356
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New application of D-π-A molecules as a sensor for recognition of Cu2+ in polluted water
Autorzy:
Niu, H.
Zhu, G.
Zhu, M.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/207782.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
polluted water
nuclear magnetic resonance spectroscopy
Cu(II)
woda zanieczyszczona
spektroskopia magnetycznego rezonansu jądrowego
Opis:
Novel chromophore GZP1 with D-π-A structure was designed and prepared for its application as a sensor for the recognition of Cu2+ ions in polluted water. Reaction of aldimine condensation was used to synthesize chromophore GZP1. Its chemical structure of was characterized by mass spectrum, nuclear magnetic resonance spectroscopy and ultraviolet-visible absorption spectrum. Cu2+ ions were recognized via fluorescence spectra. Chromophore GZP1 showed specific detection ability of Cu2+. 14 other metal ions were used as reference. The detection limit was estimated to be 0.06 μmol/dm3 in aqueous solution, which was significantly lower than the typical concentration of blood Cu2+ in normal individuals and the limit of copper(II) in drinking water.
Źródło:
Environment Protection Engineering; 2017, 43, 4; 67-72
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Temperature dependence of the short-range order parameter for Fe0.90Cr0.10 and Fe0.88Cr0.12 alloys
Autorzy:
Idczak, R.
Konieczny, R.
Powiązania:
https://bibliotekanauki.pl/articles/147636.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron alloys
Mössbauer spectroscopy
nuclear materials
short-range order
Opis:
The 57Fe Mössbauer spectra for the iron-based solid solutions Fe0.90Cr0.10 and Fe0.88Cr0.12 were measured at different temperatures ranging from 300 K to 900 K. Analysis of the obtained spectra shows that the distribution of impurity atoms in the two first coordination shells of 57Fe nuclei is not random and it cannot be described by the binomial distribution. Quantitatively, the effects were described in terms of the atomic short-range order (SRO) parameters and the pair-wise interaction energy with the help of a quasi-chemical type formulation introduced by Cohen and Fine. The obtained results reveal strong clustering-type correlations in the studied samples (a predominance of Fe-Fe and Cr-Cr bonds). Moreover, the changes in SRO values observed during thermal processing suggest that the distribution of Cr atoms in an α-iron matrix is strongly temperature dependent.
Źródło:
Nukleonika; 2015, 60, 1; 35-38
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass
Autorzy:
Stoch, P.
Ciecińska, M.
Zachariasz, P.
Suwalski, J.
Górski, L.
Wójcik, T.
Powiązania:
https://bibliotekanauki.pl/articles/147350.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron phosphate glass
Mössbauer spectroscopy
nuclear waste
waste glass
Opis:
A 57Fe Mössbauer spectroscopy study is presented. The main goal of the research was to investigate the structural information of the glass-like the coordination numbers and redox ratio of the iron. Most of the iron, about 80%, is present in the glass as Fe3+, which is composed of tetrahedral (57%) and octahedral (23%) coordinated iron. The rest of the iron, about 20%, is in the oxidation state Fe2+. This iron could be mostly present as VIFe2+, but five-fold coordinated iron is also possible. Finally, the structural model of the synthesized 60P2O5-40Fe2O3 glass was proposed.
Źródło:
Nukleonika; 2013, 58, 1; 63-66
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of nuclear techniques for characterization of materials surfaces : own investigations examples
Autorzy:
Sartowska, B.
Piekoszewski, J.
Waliś, L.
Starosta, W.
Barlak, M.
Nowicki, L.
Ratajczak, R.
Powiązania:
https://bibliotekanauki.pl/articles/146726.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
conversion electron Mössbauer spectroscopy (CEMS)
nuclear reaction analysis (NRA)
nuclear techniques
surface characterization
surface modification
Opis:
Different methods and techniques for material characterization are often used as a standard procedure for the determination of material properties. Nuclear techniques provide new and more detailed information about the investigated materials. The main goal of the carried out experiments was to improve surface properties including wear, corrosion and high temperature oxidation resistance. Modification processes were carried out using high intensity pulsed plasma beams - HIPPB (106-108 W.cm-2) generated in a rod plasma injector (RPI). In most solid materials such treatment leads to a fast transient melting of the surface layer of the substrate followed by rapid crystallization. Heating and cooling processes are of non-equilibrium type. Initial and modified materials were characterized using different investigation methods including nuclear techniques. Results of the used nuclear techniques such as nuclear reaction analysis (NRA), Rutherford backscattered spectroscopy (RBS) and conversion electron Mössbauer spectroscopy (CEMS) are presented in the paper.
Źródło:
Nukleonika; 2012, 57, 4; 521-528
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mass spectrometry approaches in proteomic and metabolomic studies
Autorzy:
Rodziewicz, P.
Swarcewicz, B.
Chmielewska, K.
Powiązania:
https://bibliotekanauki.pl/articles/80650.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
proteomics
metabolomics
genomic DNA
nuclear magnetic resonance
mass spectrometry
Fourier transform infrared spectroscopy
Raman spectroscopy
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2014, 95, 3
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass crystallization
Autorzy:
Stoch, P.
Stoch, A.
Powiązania:
https://bibliotekanauki.pl/articles/146169.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
crystallization
iron phosphate glass
Mössbauer spectroscopy
nuclear waste
waste glass
Opis:
60P2O5-40Fe2O3 glass was synthesized and 57Fe Mössbauer spectroscopy study was presented. The main goal of the research was to investigate structural changes of local environment of iron ions during gradual crystallization of the glass. It was observed that some changes were evidenced at temperature of heat treatment higher than 400°C, above which content of tetrahedrally coordinated Fe3+ was increased in cost of octahedral sites. This led to formation of areas of nucleation of α-FePO4. Crystallization of α-Fe3(P2O7)2 and Fe2P2O7 was also observed.
Źródło:
Nukleonika; 2015, 60, 1; 133-136
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
How to study G-quadruplex structures
Autorzy:
Malgowska, M.
Gudanis, D.
Teubert, A.
Dominiak, G.
Gdaniec, Z.
Powiązania:
https://bibliotekanauki.pl/articles/80131.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
guanine
DNA molecule
RNA molecule
molecular structure
intramolecular structure
intermolecular structure
G-quadruplex structure
circular dichroism spectroscopy
ultraviolet spectroscopy
electrospray ionization mass spectrometry
nuclear magnetic resonance
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2012, 93, 4
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The gyrotron for DNP-NMR spectroscopy: A review
Autorzy:
Nowak, Kacper
Powiązania:
https://bibliotekanauki.pl/articles/2173563.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
DNP-NMR spectroscopy
gyrotron stability
gyrotron tuning
dynamic nuclear polarization
spektroskopia magnetycznego rezonansu jądrowego
stabilność żyrotronu
strojenie żyrotronu
Opis:
This paper outlines the principle of the DNP-NMR technique. The gyrotron, as a very promising microwave source for NMR spectroscopy, is evaluated. Four factors: power stability, power tuning, frequency stability, and frequency tuning determine the usability of the gyrotron device. The causes of instabilities, as well as the methods of overcoming limitations and extending usability are explained with reference to the theory, the numerical and experimental results reported by gyrotron groups.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2022, 70, 1; e140354, 1--13
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical footprint of the solvent soluble extraterrestrial organic matter occluded in Sołtmany ordinary chondrite
Autorzy:
Schmitt-Kopplin, P.
Harir, M.
Kanawati, B.
Tziozis, D.
Hertkorn, N.
Gabelica, Z.
Powiązania:
https://bibliotekanauki.pl/articles/411511.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
ordinary chondrite
extraterrestrial organic matter
carbon
nitrogen
sulphur
meteorite
Sołtmany
nuclear magnetic
resonance spectroscopy (NMR)
Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
Opis:
By characterizing organic molecules of extra-terrestrial origin included in the Sołtmany meteorite, we also present the first results of the non-targeted chemical analysis of the methanol soluble organic matter present in an L6 ordinary chondrite. The structural characterization by means of ultrahigh resolution Fourier transform ion cyclotron mass spectrometry (FT-ICR-MS) with electrospray ionization (ESI) in negative and positive modes demonstrated an unexpected and astonishing chemical diversity with several thousand mass peaks that could be converted into C, H, N, O, S, and P elemental compositions. Molecular signatures were typically those of considerably oxygenated CHO and CHOS molecular series of primarily aliphatic character. 1H nuclear magnetic resonance (NMR) spectroscopy confirmed the prevalent existence of pure and functionalized aliphatic spin systems of intermediate chain length (C3-4 units), oxygenated aliphatics and a considerable diversity of oxygenated aromatics in the proton-based abundance ratio near 24 : 2 : 1. Although only residual organic matter allegedly survives in highly thermally altered L6 chondrites, the physical protection of organic matter in microcavities and traps between mineral surfaces might have supported and governed the chemistry with an apparent recalcitrance of extraterrestrial organic matter (EOM). Future studies of the organic matter in ordinary chondrites and its composition and structure in various regimes of (e.g.) temperature, radiation, pressure, and water content could shed light on these meteorites’ formation and evolution.
Źródło:
Meteorites; 2012, 2, No. 1-2; 79-92
2299-0313
2299-1220
Pojawia się w:
Meteorites
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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