- Tytuł:
- The effect of cathode materials on the electrochemical reduction of nitric acid
- Autorzy:
- Vasudevan, D.
- Powiązania:
- https://bibliotekanauki.pl/articles/778362.pdf
- Data publikacji:
- 2010
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
elektroredukcja
kwas azotowy
hydroksylamina
amoniak
katoda
electroreduction
nitric acid
hydroxylamine
ammonia
conventional and modified cathodes
mechanism - Opis:
- Electrochemical or chemical reduction of nitric acid is a well studied area in literature due to the importance of the products formed. The present work focuses on the effect of conventional cathode materials including PbO2, amalgamated Cu, graphite, Pb, Pt and a modified electrode material Ti/TiO2 on the reduction of nitric acid. Ammonia and hydroxylamine are the main products which are estimated by conventional titration methods. Other conditions being similar, the product distribution varies quite drastically as a function of the electrode material and Ti/TiO2 is found to favor a higher ratio of hydroxylamine to ammonia formation compared to other electrodes. The conditions have also been optimized based on the maximum yield of the product.
- Źródło:
-
Polish Journal of Chemical Technology; 2010, 12, 1; 35-37
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł