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Wyszukujesz frazę "catalytic activity" wg kryterium: Temat


Wyświetlanie 1-12 z 12
Tytuł:
Synthesis, characterization and catalytic properties of SAPO-11 molecular sieve synthesized in hydrothermal media using di-isopropylamine as template
Autorzy:
Chellappa, T.
Costa, M. J. F.
Nascimento, W. A.
Ferreira De Lima, L.
Bassan, I. A.
Tavares, M.
Fernandes, V. J.
Menezes, A.
Guilherme Meira, L.
Telesforo Nóbrega De Medeiros, J.
Maribondo Do Nascimento, R.
Powiązania:
https://bibliotekanauki.pl/articles/200372.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
microporous materials
SAPO-11
characterization
catalytic activity
molecular sieves
Opis:
A microporous SAPO-11 Molecular sieve was successfully synthesized by the hydrothermal method, using a single agent, as an organic template: di-isopropylamine (DIPA). The obtained solid was calcined at 550C for three hours, after which the flow of nitrogen was exchanged for that of synthetic air and submitted for another ten hours of calcination, so as to remove the single agent: di-isopropylamine, which after the removal of the template could be observed by the high crystallization of the sample. Furthermore, the molecular sieve was characterized by XRD, SEM, TG-DTG and N2 adsorption desorption (BET analysis). The obtained catalyst proved to have a high potential catalytic activity and selectivity, through the obtained characterization results, exhibiting good hydrothermal stability. The catalytic performance of SAPO-11 was tested by the deactivation/regenerability of the coked sample, furthered by cracking of n-hexane reaction and high olefins selectivity was obtained.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2014, 62, 3; 481-488
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Catalytic Properties of Iron Oxides in the Reaction of Low-Temperature Ozone Decomposition
Autorzy:
Rakitskaya, T.
Truba, A.
Ennan, A.
Baumer, V.
Volkova, V.
Powiązania:
https://bibliotekanauki.pl/articles/1030914.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
iron oxides
synthesis
thermal treatment
ozone decomposition
catalytic activity
Opis:
Two sets of iron oxide samples were synthesized applying different iron(III) precursors (FeCl₃ and Fe₂(SO₄)₃) and calcination temperature (200, 300, and 500°C). The samples were characterized by powder X-ray analysis and the Fourier transform infrared spectroscopy. Depending on the synthesis conditions, samples of iron oxides with different phase composition were obtained: polyphase (α -Fe₂O₃, γ -Fe₂O₃, Fe₃O₄, and α -FeO(OH)) and monophase (γ -Fe₂O₃ or α -Fe₂O₃) ones. For the samples of homogeneous composition, it has been found that the activity of γ -Fe₂O₃ in the reaction of ozone decomposition at ozone concentration in gaseous phase of 1 mg/m³ is much higher than the activity of α -Fe₂O₃.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1079-1083
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrocatalytical Properties of Palladium-Decorated Cobalt Coatings Obtained by Electrodeposition and Galvanic Displacment
Autorzy:
Skibińska, K.
Kutyła, D.
Kołczyk, K.
Kwiecińska, A.
Kowalik, R.
Żabiński, P.
Powiązania:
https://bibliotekanauki.pl/articles/354000.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
linear voltammetry
electrodeposition
palladium
cobalt
galvanic displacement reaction
catalytic activity
Opis:
This work presents the studies on the electrochemical process of thin palladium layers formation onto electrodeposited cobalt coatings. The suggested methodology consists of the preparation of thick and smooth cobalt substrate via galvanostatic electrodeposition. Cobalt coatings were prepared under different cathodic current density conditions from acidic bath containing cobalt sulphate and addition of boric acid. Obtained cobalt layers were analyzed by x-ray diffraction to determine their phase composition. Freshly prepared cobalt coatings were modificated by the galvanic displacement method in PdCl2 solution, to obtain smooth and compact Pd layer. The comparison of electrocatalytic properties of Co coatings with Co/Pd ones enabled to determine the influence of Palladium presence in cathodic deposits on the hydrogen evolution process.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1517-1521
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cloning, purification and enzymatic characterization of recombinant human superoxide dismutase 1 (hSOD1) expressed in Escherichia coli
Autorzy:
Lin, Feng
Yan, Dandan
Chen, Yawen
E, Fletcher
Shi, Haifeng
Han, Bangxing
Zhou, Yang
Powiązania:
https://bibliotekanauki.pl/articles/1038395.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
superoxide dismutase 1
Escherichia coli
soluble expression
metal ions
catalytic activity
Opis:
Superoxide dismutase 1 (SOD1) is a metalloenzyme that catalyzes the disproportionation of superoxide into molecular oxygen and hydrogen peroxide. In this study, the human SOD1 (hSOD1) gene was cloned, expressed and purified. The hSOD1 gene was amplified from a pool of Bxpc3 cell cDNAs by PCR and cloned into expression vector pET-28a (+). The recombinant soluble hSOD1 was expressed in E. coli BL21 (DE3) at 37°C and purified using nickel column affinity chromatography. Soluble hSOD1 was produced with a yield of 5.9 μg/mL medium. As metal ions can have a certain influence on protein structure and activity, we researched the influences of different concentrations of Cu2+ and Zn2+ on hSOD1 activity at induction and the time of activity detection. The results implied that Cu2+ and Zn2+ do not enhance SOD1 expression and solubility; they can, however, improve the catalytic activity at induction. Meanwhile, Cu2+ and Zn2+ also enhanced the enzyme activity at the time of detection. Furthermore, most other bivalent cations had the potential to replace Zn2+ and Cu2+, and also improved enzyme activity at the time of detection.
Źródło:
Acta Biochimica Polonica; 2018, 65, 2; 235-240
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of permeabilization on the catalytic activity of yeast cells Yarrowia lipolytica KKP 379 in the synthesis of plasticizer - dioctyl adipate
Wpływ permeabilizacji na aktywność katalityczną komórek drożdży Yarrowia lipolytica KKP 379 w syntezie plastyfikatora - adypinianu dioktylu
Autorzy:
Małajowicz, J.
Wacławek, W.
Try, S.
Powiązania:
https://bibliotekanauki.pl/articles/13925539.pdf
Data publikacji:
2019
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:
plasticizer
polymer
dioctyl adipate
yeast biomass
Yarrowia lipolytica
transesterification
permeabilization
catalytic activity
Źródło:
Zeszyty Problemowe Postępów Nauk Rolniczych; 2019, 596; 23-32
0084-5477
Pojawia się w:
Zeszyty Problemowe Postępów Nauk Rolniczych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Use of MgO to Promote the Oxyethylation Reaction of Lauryl Alcohol
Autorzy:
Pilarska, A.
Lukosek, M.
Siwińska-Stefańska, K.
Pilarski, K.
Jesionowski, T.
Powiązania:
https://bibliotekanauki.pl/articles/779641.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
magnesium hydroxide and oxide
precipitation
dispersive and structural properties
oxyethylation
catalytic activity
Opis:
Synthesis of magnesium hydroxide was performed by the precipitation method with the use of magnesium sulfate and sodium hydroxide. The infiuence of temperature and ratio of reagents was studied. Magnesium hydroxides, and the magnesium oxides obtained from them by thermal decomposition, were analyzed to determine their bulk density, polydispersity and particle size. The magnesium oxide with the largest surface area was tested as a catalyst in the oxyethylation of lauryl alcohol, and shown to be selective but poorly reactive in comparison with commercially available catalysts. Further studies are needed to improve its reactivity.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 2; 36-42
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of TSA technique in localization of snRNP-rich cytoplasmic bodies
Autorzy:
Hyjek, M.
Wojciechowska, N.
Kolowerzo, A.
Smolinski, D.J.
Powiązania:
https://bibliotekanauki.pl/articles/80402.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
RNA maturation
eukaryotic cell
biogenesis
TSA technique
microsporocyte
catalytic activity
horseradish peroxidase
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 3
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer study of a tetrakis (pentafl uorophenyl) porphyrin iron (III) chloride in comparison with the fluorine unsubstituted analogue
Autorzy:
Kaczmarzyk, T.
Dziedzic-Kocurek, K.
Rutkowska, I.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/146091.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
catalytic activity
DFT calculations
electronic structure
iron(III)-[tetrakis (pentafl uorophenyl)]
Mössbauer spectroscopy
porphyrin chloride
Opis:
Mössbauer investigations, in association with density functional theory (DFT) calculations, have been conducted for the molecular and electronic structures of iron (III) [tetrakis (pentafl uorophenyl)] porphyrin chloride [(F20TPP)Fe:Cl], as a Fe(III)-tetraphenylporphyrin complex containing chloride axial ligand and substituted hydrogen atoms by fl uorine ones in the four phenyl rings, in comparison with its fl uorine unsubstituted analogue [(TPP)Fe:Cl]. It was found that the parameters of Mössbauer spectra of both complexes are close to one another, and correspond to the high-spin state of Fe(III) ions, but they show the different temperature dependence and the quadrupole doublets in Mössbauer spectra show different asymmetry at low temperatures. Results of DFT calculations are analyzed in the light of catalytic activity of the halogenated complex.
Źródło:
Nukleonika; 2015, 60, 1; 57-61
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Propylene oxide polymerization in the presence of layered double hydroxides
Polimeryzacja tlenku propylenu w obecności warstwowych wodorotlenków podwójnych
Autorzy:
Dan, O.
Butenko, E.
Kapustin, A.
Powiązania:
https://bibliotekanauki.pl/articles/106634.pdf
Data publikacji:
2018
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
propylene oxide
layered double hydroxides
polymerization
catalytic activity
tlenek propylenu
podwójne warstwowe wodorotlenki
polimeryzacja
aktywność katalityczna
Opis:
Propylene oxide polymerization in the presence of layered double hydroxides with different concentration of basic sites on their surface has been studied. It is shown that the polymerization can be catalyzed by both basic and acidic sites. On the basis of kinetic experiments the mechanisms of reaction undergoing were proposed.
W artykule badano polimeryzację tlenku propylenu w obecności warstwowych wodorotlenków podwójnych o różnej ilości centrów zasadowych na powierzchni. Wykazano, że kataliza polimeryzacji zachodzi zarówno w centrach zasadowych, jak i kwasowych. Na podstawie doświadczeń kinetycznych zaproponowano mechanizmy reakcji.
Źródło:
Chemistry-Didactics-Ecology-Metrology; 2018, 23, 1-2; 137-142
2084-4506
Pojawia się w:
Chemistry-Didactics-Ecology-Metrology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and activity evaluation of Ce-Mn-Cu mixed oxide catalyst for selective oxidation of co in automobile engine exhaust: effect of Ce/Mn loading content on catalytic activity
Autorzy:
Bilal, Yasir
Nasir, Muhammad Ali
Nasreen, Sadia
Akhter, Niaz Ahmed
Pasha, Riffat Asim
Noor, Muhammad Farhan
Powiązania:
https://bibliotekanauki.pl/articles/101992.pdf
Data publikacji:
2018
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
base metal oxide catalyst
catalytic converter
CO sensor
CO-precipitation
catalytic activity
katalizator tlenku metalu zasadowego
katalizator
czujnik CO
strącanie CO
aktywność katalityczna
Opis:
A series of Mn-doped CeO2-CuO catalyst (CeO2-MnOx-CuO) (Ce/Mn molar ratio of 0.5, 1.0 2.0 and 3.0) were prepared using co-precipitation method for the selective oxidation of CO in automobile engine exhaust. The content of copper was 5.0 wt. % in each sample. Catalysts were installed on the automobile engine exhaust and CO amount was recorded with help of CO sensor, with and without the catalyst. The catalytic converter efficiency was estimated for each catalyst through efficiency formula. It was observed that Ce/Mn catalyst with a molar ratio of 2.0 shows the maximum efficiency (88.35%). Stability of conversion process was analyzed by plotting the CO amount with respect to time. The catalyst with Ce/Mn molar ratio of 2.0 performed the most streamline conversion process with least deviations.
Źródło:
Advances in Science and Technology. Research Journal; 2018, 12, 1; 260-266
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Survival in extremes
Autorzy:
Malecki, P.H.
Rypniewski, W.
Powiązania:
https://bibliotekanauki.pl/articles/80335.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
survival
extremophilic organism
natural source
enzyme
biotechnology
X-ray crystallography
psychrophilic chitina
marine bacteria
Moritella marina
chitinase
catalytic activity
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 1
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hiring cell gatekeepers – ABC transporters in plant biotechnology
Autorzy:
Szewczak, A.
Ziomkiewicz, I.
Jasinski, M.
Powiązania:
https://bibliotekanauki.pl/articles/80332.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ATP-binding cassette
catalytic activity
drought resistance
membrane transport
molecular structure
phytoremediation
plant biotechnology
plant hormone
plant physiology
secondary metabolite
transmembrane domain
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2011, 92, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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