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Wyszukujesz frazę "antimony" wg kryterium: Temat


Tytuł:
Elemental and mineral inventory of tailing impoundments near Pezinok, Slovakia and possible courses of action for their remediation
Autorzy:
Majzlan, Juraj
Brecht, Björn
Lalinska, Bronislava
Chovan, Martin
Moravansky, Daniel
Uhlik, Peter
Powiązania:
https://bibliotekanauki.pl/articles/2086503.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
impoundments
Pezinok
remediation
arsenic
antimony
Opis:
An effective remediation strategy for a polluted site should take the absolute amount of the pollutant(s) into account. Here, we present an elemental budget for As, Sb and Fe in two tailing impoundments of the former Sb-Au deposit near Pezinok, Slovakia. The two impoundments contain 5,740 X103 kg As, 6,360 X103 kg Sb and 50,105 X103 kg Fe. An estimated total Au content in the impoundments is 132 kg. The most abundant minerals in the tailings are quartz, illite, and chlorite. The content of carbonates in the tailings is 3.5-10.5 wt% calcite equivalent and we estimate that the carbonates are sufficiently abundant to buffer the pH at circumneutral values, up to the point when all pyrite decomposes. The possible courses of action are i) do nothing, ii) build an active barrier to capture the released As and Sb, iii) isolate the impoundments from rain and ground water and iv) use the impoundments as a source of Sb and redeposit the waste in a safer form. The simplest approach is to do nothing, which seems to be the most likely course of events, given the current economic, political and societal state of the Slovak Republic. Although this action costs nothing in the short term, it may cause significant damage to the environment, especially to the alluvial sediments and associated water resources in the long term.
Źródło:
Mineralogia; 2010, 41, 1/2; 55--74
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elemental and mineral inventory of tailing impoundments near Pezinok, Slovakia and possible courses of action for their remediation
Autorzy:
Majzlan, J.
Brecht, B.
Lalinska, B.
Chovan, M.
Moravansky, D.
Uhlik, P.
Powiązania:
https://bibliotekanauki.pl/articles/2086530.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
impoundments
Pezinok
remediation
arsenic
antimony
Opis:
An effective remediation strategy for a polluted site should take the absolute amount of the pollutant(s) into account. Here, we present an elemental budget for As, Sb and Fe in two tailing impoundments of the former Sb-Au deposit near Pezinok, Slovakia. The two impoundments contain 5,740 X103 kg As, 6,360 X103 kg Sb and 50,105 X103 kg Fe. An estimated total Au content in the impoundments is 132 kg. The most abundant minerals in the tailings are quartz, illite, and chlorite. The content of carbonates in the tailings is 3.5-10.5 wt% calcite equivalent and we estimate that the carbonates are sufficiently abundant to buffer the pH at circumneutral values, up to the point when all pyrite decomposes. The possible courses of action are i) do nothing, ii) build an active barrier to capture the released As and Sb, iii) isolate the impoundments from rain and ground water and iv) use the impoundments as a source of Sb and redeposit the waste in a safer form. The simplest approach is to do nothing, which seems to be the most likely course of events, given the current economic, political and societal state of the Slovak Republic. Although this action costs nothing in the short term, it may cause significant damage to the environment, especially to the alluvial sediments and associated water resources in the long term.
Źródło:
Mineralogia; 2010, 41, 1/2; 55--74
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation of antimony ores with high arsenic content
Autorzy:
Özer, Mustafa
Powiązania:
https://bibliotekanauki.pl/articles/2146881.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
antimony
arsenic
flotation
rougher
clearing
Opis:
Efficient evaluation of antimony ores, which are on the critical raw materials list due to the supply risk by the European Union, is an important necessity. In this context, ore preparation and enrichment processes are very important during the process from ore to metal. Especially for sulfide antimony ores, the most common beneficiation method is flotation. Therefore, antimony ore consisting of stibnite mineral obtained from Tokat-Turkey region was used in this study. Due to the low antimony (5.06%Sb) and the high Arsenic (1.38%As) content, it is an important requirement to increase the Sb content of this ore by flotation, as well as to reduce the As content to certain levels. Stibnite as an antimony mineral and arsenopyrite as arsenic mineral, are minerals that have a sulphurous structure in mineralization and their flotation properties are quite close to each other. Therefore, in this study, it is aimed to selectively separate the bulk concentrate taken from rougher flotation by cleaning steps. A bulk sulfur concentrate with 24.54% Sb and 3.69% As content obtained as a result of the rougher flotation was obtained with a recovery of 98.9%. This product was subjected to 6 stages of cleaning flotation and a concentrate with a content of 63.8% Sb and 0.31% As was produced with an antimony recovery of 83% Sb.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152865
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Orange Peels as a Sustainable Material for Treating Water Polluted with Antimony
Autorzy:
Hasan, Manar B.
Al-Tameemi, Israa M.
Abbas, Mohammed N.
Powiązania:
https://bibliotekanauki.pl/articles/1839075.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
antimony treatment
antimony adsorption
polluted water
orange peel
low-cost material
Opis:
Water pollution has increased due to human activities; consequently, it is essential to treat both surface water and ground water so they are suitable to meet the needs of the population. This study will discuss water treatment intended to remove antimony. Antimony (Sb) is classed as a high-priority toxic pollutant because of its adverse effects on ecosystems and human health. There are several methods for removing antimony from water, including adsorption, coagulation, ion exchange, and electrochemical treatment. This study focuses on the adsorption method as researchers have, in recent times, been seeking adsorbents that are environmentally friendly and cost-effective and that do not leave a residue. The study investigates the use of orange peels treated with acetic acid as an adsorbent to remove antimony ions from a simulated aqueous solution. The results revealed that 5 g of treated orange peels is 98.5% effective at treating water at a pH of 6, for a contact time of 150 minutes, at a mixing speed of 450 rpm.
Źródło:
Journal of Ecological Engineering; 2021, 22, 2; 25-35
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions
Autorzy:
Rudnik, E.
Kostępski, M.
Powiązania:
https://bibliotekanauki.pl/articles/352105.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
antimony
electrolysis
speciation
tin
voltammetry
Opis:
Codeposition of antimony and tin from acidic chloride and chloride-sulfate baths was investigated. The calculations of distribution of species showed domination of neutral SnCl2 and anionic SbCl4 - complexes in chloride solution, while in the presence of sulfate ions neutral SnSO4 and cationic SbCl2+ complexes were found. Cyclic voltammetry, anodic stripping analysis and potentiostatic measurements showed that antimony deposited favorably and the reaction run under limiting control. Analysis of chronoamperometric curves suggested instantaneous nucleation of the solid phase in the chloride bath, but progressive model was more probable in the presence of sulfate ions.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 709-717
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Basic theory and optimization of gold containing antimony concentrate leaching by alkaline sulfide
Autorzy:
Wu, Hao
Feng, Yali
Li, Haoran
Liao, Shengde
Wang, Hongjun
Powiązania:
https://bibliotekanauki.pl/articles/109524.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
antimony concentrate
leaching process
alkaline leaching
kinetics
Opis:
As sodium sulfide is easily oxidized to polysulfide and thiosulfate which have a gold leaching effect, gold would dissolve in leaching solution when extracting stibium from gold containing antimony concentrate by alkaline sulfide. Through leaching test and kinetics analysis, the decomposition regularity of sodium sulfide and leaching rate were studied under different leaching conditions. The results indicated that the gold content in antimony concentrate was 28.41g/Mg, and the content of antimony and sulfur was 36.01% and 14.04%, respectively. The main metallic minerals were native gold, arsenopyrite, stibnite, and the gangue minerals were mainly quartz. Anodic polarization curve shows reduced iron powder can increase the peak potential of the oxidation of the leaching solution and it can effectively prevent the decomposition of sodium sulfide and the dissolution of gold. Optimized stibium-extraction efficiency was achieved under the following conditions: a concentration of sodium sulfide and sodium hydroxide at 110g/dm³ and 20g/dm³, respectively; a ratio of iron powder to concentrate of 1:30; a ratio of liquid to solid of 5:1; agitation speed of 600rad/min; reaction temperature of 353.15K; and a reaction time of 3 h. Under the optimized conditions, high antimony recovery (97.35%) and low gold dissolution (1.32%) were achieved.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 248-257
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Sb-Modification on the Microstructure and Mechanical Properties of Secondary Alloy 319
Autorzy:
Medlen, D.
Bolibruchova, D.
Powiązania:
https://bibliotekanauki.pl/articles/357012.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
alloy 319
secondary alloy
microstructure
mechanical properties
modification
antimony
Opis:
319 alloy has been selected for the study in the present work due to its wide use in many applications. 319 alloy is used in automotive and aerospace industry for the complicated castings which must comply high strength requirements. In practice, the most common elements with the modifying effect are strontium, sodium and antimony. The addition of these elements leads to a change in the shape of eutectic silicon, resulting in an increase of the mechanical characteristics and the microstructure. An experimental program has been undertaken to explore the effect of antimony on chosen mechanical properties and the microstructure of investigated alloy. An analysis of the results of these experimental works is made in order to determine an optimum Sb (Al-10% Sb) addition to produce material exhibiting desirable properties. Experimental works have showed that the addition of the Al-10% Sb results in similar or even higher mechanical properties than the conventional 319 alloy. Based on the carried out experiments the best combination of mechanical properties has been achieved by the addition of 2 000 ppm Al-10% Sb.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 553-558
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process
Autorzy:
Radovanovic, D.
Kamberovic, Z.
Andjic, Z.
Ranitovic, M.
Markovic, B.
Powiązania:
https://bibliotekanauki.pl/articles/109711.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Jarosite
Waelz slag
arsenic
antimony
leaching test
microstructure
Opis:
Jarosite and neutral leaching residue (NLR) are the greatest environmental problems of hydrometallurgical zinc production due to their high quantity and hazardous content. Pyrometallur-gical processes, such as the Waelz process, could be applied to recover valuable metals present in this waste. The paper investigates the possibility of forming environmentally stable Waelz slag after the Waelz process of jarosite and NLR. Waelz slag, obtained using CaO as a conventional alkaline additive in the Waelz process, showed high As and Sb release after the EN 12457-4 standard leaching test. Multiphase equilibrium composition calculations indicated that As and Sb were present as volatile and migratory species in the slag. In order to obtain Waelz slag with more stable matrices that would encapsulate and immobilize pollutants, MgO additions to CaO and different cooling conditions of the slag were further investigated. The efficiency of modification in additives composition and cooling conditions was assessed by EN 12457-4 leaching test and chemical and microstructural characterization (XRF and SEM-EDS analyses) of the Waelz slags. The results show that addition of MgO does not reduce the efficiency of the process, even more it increases leaching resistance of the slags. Concentrations of all investigated metals (As, Ba, Cu, Mo, Pb, Sb, Zn) after the leaching test were below defined limits for non-hazardous waste. Microstructural analyses revealed that MgO remained inert during Waelz process, and thus favoring the formation of amorphous stable structure, which was enhanced by increased cooling rate. All investigated Waelz slags with MgO additions are suitable for further use or safe disposal.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 484-495
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
How to find a gold on the touristic path - a gold-mining in the Tatra Mts.
Jak znaleźć złoto na ścieżce turystycznej - kilka słów o górnictwie złota w Tatrach
Autorzy:
Gawęda, A.
Powiązania:
https://bibliotekanauki.pl/articles/344504.pdf
Data publikacji:
2010
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Stowarzyszenie Naukowe im. Stanisława Staszica
Tematy:
Tatry
granitoidy
złoto
antymonit
mylonit
Tatra Mts.
granitoids
gold
antimony
mylonite
Opis:
Gold mineralization is known in the Tatra Mts from the 15th century. The historical mining places could be indentified along the present-day touristic paths, which were used in the past as miner's roads. Both gold occurrence and genetically connected antimony mineralization are located in the flat-lying mylonitic zones, dipping 5-10 degree to NW, cutting the Tatra granite. Mylonites are mineralized by quartz and albite. The famous gold-mining galleries are known from Krywań Mt., where gold and antimonite could be found inside quartz veins straight on the touristic path until now. The important sources of gold were also the secondary fluvioglacial deposits. Gold from the Tatra Mts, regardless its origin - both primary and secondary - is of good quality, with Ag content in the range of 1.2-14.8 wt.%. Locally the veinlets of electrum are also observed. Gold in the Tatra Mts. is associated with antimonite. Its crystals are usually coated with secondary antimony oxides and hydroxides. The historical gold-mining places could be of special importance for geotouristic purposes, as they bring the information about both histories of human mining activity in the mountains and about the geological processes, forming the ores, which released the people's strongest emotions for a few thousand years.
Mineralizacja złotem znana jest w Tatrach od XV wieku. Ślady eksploatacji i zorganizowanej działalności górniczej można zaobserwować przy współczesnych ścieżkach turystycznych. Wiele z nich ma niemal identyczny przebieg do starych dróg górniczych. Mineralizacja zlotem oraz związana z nią genetycznie mineralizacja związkami antymonu ulokowane są w obrębie stref mylonitycznych, tnących granit tatrzański. Strefy te są silnie zmineralizowane kwarcem i albitem i zapadają płasko (5-10 stopni) na NW. Najsłynniejsze sztolnie poszukiwaczy złota znajdują się na Krywaniu. Złoto i antymonit tworzą wpryśnięcia w żyłach kwarcowych. Okruchy złotonośnego kwarcu znaleźć można nawet dziś na ścieżce turystycznej. Istotnym ekonomicznie źródłem złota były w przeszłości wtórne osady fluwioglacjalne u stóp Krywania. Złoto tatrzańskie - zarówno to ze źródeł pierwotnych, jak i wtórnych - miało dobrą jakość, a zawartość w nim srebra (Ag) mieściła się w granicach 1,2-14,8 % wag. Pod mikroskopem można lokalnie stwierdzić obecność żyłek i odmieszań elektrum. Kryształy antymonitu, związanego genetycznie ze złotem, są zwykłe pokryte wtórnymi tlenkami i wodorotlenkami antymonu. Miejsca historycznej eksploatacji górniczej w Tatrach pełnią niezwykłe ważną rolę geoturystyczną: są równocześnie źródłem informacji na temat aktywności ludzkiej w terenie górskim, jak również zawierają ważne dla geologów wskazówki na temat procesów geologicznych, prowadzących do powstania złóż, które wywoływały najsilniejsze ludzkie emocje przez wiele tysięcy lat.
Źródło:
Geoturystyka; 2010, 2; 59-64
1731-0830
Pojawia się w:
Geoturystyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of Antimony Telluride for Thermoelectric and Optoelectronic Applications
Autorzy:
Zybała, R.
Mars, K.
Mikuła, A.
Bogusławski, J.
Soboń, G.
Sotor, J.
Schmidt, M.
Kaszyca, K.
Chmielewski, M.
Ciupiński, L.
Pietrzak, K.
Powiązania:
https://bibliotekanauki.pl/articles/352428.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
antimony telluride
thermoelectric materials
thin films
PVD magnetron sputtering
topological insulator
Opis:
Antimony telluride (Sb2 Te3 ) is an intermetallic compound crystallizing in a hexagonal lattice with R-3m space group. It creates a c lose packed structure of an ABCABC type. As intrinsic semiconductor characterized by excellent electrical properties, Sb2 Te3 is widely used as a low-temperature thermoelectric material. At the same time, due to unusual properties (strictly connected with the structure), antimony telluride exhibits nonlinear optical properties, including saturable absorption. Nanostructurization, elemental doping and possibilities of synthesis Sb2 Te3 in various forms (polycrystalline, single crystal or thin film) are the most promising methods for improving thermoelectric properties of Sb2Te3.Applications of Sb2 Te3 in optical devices (e.g. nonlinear modulator, in particular saturable absorbers for ultrafast lasers) are also interesting. The antimony telluride in form of bulk polycrystals and layers for thermoelectric and optoelectronic applications respectively were used. For optical applications thin layers of the material were formed and studied. Synthesis and structural characterization of Sb2 Te3 were also presented here. The anisotropy (packed structure) and its influence on thermoelectric properties have been performed. Furthermore, preparation and characterization of Sb2 Te3 thin films for optical uses have been also made.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1067-1070
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improved Long-Term Stability of Transparent Conducting Electrodes Based on Double-Laminated Electrosprayed Antimony Tin Oxides and Ag Nanowires
Autorzy:
Koo, B.-R.
Bae, J.-W.
Ahn, H.-J.
Powiązania:
https://bibliotekanauki.pl/articles/355292.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
transparent conducting electrodes
Ag nanwories
antimony tin oxides
long-term stability
Opis:
We fabricated double-laminated antimony tin oxide/Ag nanowire electrodes by spin-coating and electrospraying. Compared to pure Ag nanowire electrodes and single-laminated antimony tin oxide/Ag nanowire electrodes, the double-laminated antimony tin oxide/Ag nanowire electrodes had superior transparent conducting electrode performances with sheet resistance ~19.8 Ω/□ and optical transmittance ~81.9%; this was due to uniform distribution of the connected Ag nanowires because of double lamination of the metallic Ag nanowires without Ag aggregation despite subsequent microwave heating at 250°C. They also exhibited excellent and superior long-term chemical and thermal stabilities and adhesion to substrate because double-laminated antimony tin oxide thin films act as the protective layers between Ag nanowires, blocking Ag atoms penetration.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1275-1279
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Spark Plasma Sintering Temperature on Microstructure and Tthermoelectric Properties of Cu-Doped Bi0.5Sb1.495Te3 Compound
Autorzy:
Lee, Chul-Hee
Dharmaiah, Peyala
Song, Jun-Woo
Jeong, Kwang-Yong
Hong, Soon-Jik
Powiązania:
https://bibliotekanauki.pl/articles/353226.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bismuth antimony telluride
gas atomization
spark plasma sintering
microstructure
thermoelectric materials
Opis:
Due to air pollution, global warming and energy shortage demands new clean energy conversion technologies. The conversion of industrial waste heat into useful electricity using thermoelectric (TE) technology is a promising method in recent decades. Still, its applications are limited by the low efficiency of TE materials in the operating range between 400-600 K. In this work, we have fabricated Cu0.005 Bi0.5Sb1.495Te3 powder using a single step gas atomization process followed by spark plasma sintering at different temperatures (623, 673, 723, and 773 K), and their thermoelectric properties were investigated. The variation of sintering temperature showed a significant impact on the grain size. The Seebeck coefficient values at room temperature increased significantly from 127 μVK to 151 μV/K with increasing sintering temperature from 623 K to 723 K due to decreased carrier concentration. The maximum ZT values for the four samples were similar in the range between 1.15 to 1.18 at 450 K, which suggest these materials could be used for power generation in the mid-temperature range (400-600 K).
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 3; 1105-1110
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antimony Influence on Shape of Eutectic Silicium in Al-Si Based Alloys
Autorzy:
Bolibruchová, D.
Brůna, M.
Powiązania:
https://bibliotekanauki.pl/articles/383239.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
antimony influence
alloy modification
aluminium alloy
wpływ antymonu
modyfikacja stopu
stop aluminium
Opis:
Liquid AI-Si alloys are usually given special treatments before they are cast to obtain finer or modified matrix and eutectic structures, leading to improved properties. For many years, sodium additions to hypoeutectic and eutectic AI-Si melts have been recognized as the most effective method of modifying the eutectic morphology, although most of the group IA or IIA elements have significant effects on the eutectic structure. Unfortunately, many of these approaches also have associated several founding difficulties, such as fading, forming dross in presence of certain alloying elements, reduced fluidity, etc. In recent years, antimony additions to AI-Si castings have attracted considerable attention as an alternative method of refining the eutectic structure. Such additions eliminate many of the difficulties listed above and provide permanent (i.e.,non-fading) refining ability. In this paper, the authors summarize work on antimony treatment of Al-Si based alloys.
Źródło:
Archives of Foundry Engineering; 2017, 17, 4; 31-34
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
2.1 žm emission of Tm3+/Ho3+ - doped antimony-silicate glasses for active optical fibre
Autorzy:
Żmojda, J.
Dorosz, D.
Dorosz, J.
Powiązania:
https://bibliotekanauki.pl/articles/200143.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
antimony-silicate glasses
Tm3+/Ho3+ glasses
active optical fibre
Opis:
Tm3+/Ho3+ – doped antimony-silicate optical fibre with 2.1 ěm emission has been presented. Luminescence corresponding to 5I7 --> 5I8 transition in holmium was obtained by energy transfer between Tm3+ and Ho3+ ions. The analysis of the luminescence mechanism showed a significant influence of the glass composition (low phonon content) on the emission intensity. Optimization of the active elements content, presented in the paper, allowed to indicate that a strong emission intensity at 2 ěm in the fabricated glasses was obtained for the molar composition of 1% Tm2O3 : 0.75% Ho2O3. According to the F¨orster-Dexter theory, the efficiency of energy transfer of the 3F4 (Tm3+) --> 5I7 (Ho3+) transition was calculated. Moreover, it was found that the full width at half maximum (FWHM) of luminescence in the range of 1.6 – 2.2 ěm strongly depends on the Tm3+/Ho3+ ratio. The optimization of Tm3+/Ho3+ transfer in antimony-silicate glasses allowed to fabricate optical fibre with narrowing and red-shifting of emission at 2.1 ěm.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2011, 59, 4; 381-387
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antimony speciation in soils in areas subjected to industrial anthropopressure
Autorzy:
Jabłońska-Czapla, Magdalena
Grygoyć, Katarzyna
Rachwał, Marzena
Powiązania:
https://bibliotekanauki.pl/articles/2173773.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
soil
Sb(III)
antimony speciation
Sb(V)
SbMe3
industrial anthropopressure
Opis:
The aim of the study was optimization of antimony speciation methodology in soils in areas subjected to industrial anthropopressure from traffic, metallurgy and recycling of electrowaste (e-waste) sources. Antimony speciation was carried out using the hyphenated HPLC-ICP-MS (High-Performance Liquid Chromatography- -Inductively Coupled Plasma-Mass Spectrometry) technique for the determination of antimony species ((Sb(III), Sb(V), SbMe3). The extraction and determination of antimony species in soil was optimized and validated, taking into account the matrix effects. The best results in antimony extraction from soils were obtained using a mixture of 100 mM citric acid and 20 mM Na2EDTA. Ions were successfully separated in 6 minutes on Hamilton PRPX100 column with 0.11 μg/L, 0.16 μg/L, 0.43 μg/L limit of detection for Sb(III), Sb(V), SbMe3 , respectively. The oxidized antimony form (Sb(V)) predominated in the soil samples. The reduced antimony form (Sb(III)) was present only in a few samples, characterized by the lowest pH. The methyl derivative of antimony (SbMe3 ) was present in the samples with the lowest redox potential from the area around WEEE (Waste of Electrical and Electronic Equipment) treatment plant. The methodology of extraction and determination of three antimony species in soils was developed, achieving low limits of quantification and very good recovery. The research showed a large variation in antimony content in the soils impacted by type of industrial anthroporessure. The antimony content was the highest in the area of the WEEE treatment plant, indicating this type of industrial activity as a significant source of soil contamination with antimony.
Źródło:
Archives of Environmental Protection; 2022, 28, 2; 42--52
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł

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