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    Wyświetlanie 1-3 z 3
    Tytuł:
    Swelling pressure of natural and modified smectite-bearing clay raw materials
    Autorzy:
    Panna, W.
    Wyszomirski, P.
    Szumera, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/110772.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    clay raw materials
    swelling pressure
    sodium activated smectites
    waterproofing materials
    Krakowiec clays
    Triassic clay
    Opis:
    Smectite clays, due to their barrier properties and swelling ability, are often applied for waterproofing purposes. A proper value of swelling pressure is one of the parameters, which must be met by the fillers used in hybrid waterproofing materials. The authors determined the swelling pressure of selected clay raw materials in their natural state and after chemical modification. This parameter was measured by the Komine method, as this procedure is more accurate than the standard edometric method. The authors introduced some changes in the method. The samples represent Krakowiec clays (Miocene) and a Triassic clay, collected in active pits of building clays, which are widely exploited in south Poland. The content of the smectite group minerals, determined from the sorption of methylene blue and copper(II) triethylenetetramine, ranges between 15 and 35%. Further characteristics of the clays were obtained with X-ray diffraction, chemical analyses (calcium carbonate content including) and pH measurements. It has been found that the activation of smectite clays with sodium lowers their swelling pressure as water penetrates easier the interlayer spaces of the smectites modified. This is important from the viewpoint of assessing the quality of bentonite fillers.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 1; 127-135
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Marine vs. terrestrial environments during Early Triassic deposition on the northeastern margin of the Central European Basin : a multidisciplinary study on the Middle Buntsandstein of the Bartoszyce IG 1 borehole, NE Poland
    Autorzy:
    Becker, Anna
    Fijałkowska-Mader, Anna
    Jasionowski, Marek
    Powiązania:
    https://bibliotekanauki.pl/articles/2060144.pdf
    Data publikacji:
    2020
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Lower Triassic
    northeastern Poland
    palynofacies
    clay mineralogy
    olite microfacies
    isotope geochemistry
    Opis:
    The Middle Buntsandstein Subgroup of the Lower Triassic of north-eastern Poland has been investigated in the context of possible marine ingressions into the Central European Basin. To better constrain these, palynofacies analysis and mineralogical analysis of mudstones were undertaken on samples taken from the Lidzbark and Malbork formations penetrated by the Bartoszyce IG 1 borehole, serving as stratotype section of both lithostratigraphic units. Microfacies and geochemical analyses, including C and O isotope analysis, were conducted additionally on oolitic limestones of the basal Lidzbark Formation (the lowermost Middle Buntsandstein), and the boron content was measured on all mudstone samples. Seven palynofacies types are distinguished: types 1 to 3 within the Malbork Formation and types 4 to 7 within the Lidzbark Formation. Types 1 and 2 originated on a floodplain, type 3 probably in a deltaic or barrier setting, and types 4 and 5 in a brackish lagoon or a more open basin, possibly of marine origin. Palynofacies type 6 reflects long transport and reworking, whereas palynofacies type 7 is interpreted as formed due to pedogenic processes. Clay minerals and quartz, accompanied by feldspars, calcite and dolomite are the main components of the mudstones investigated. The clay mineral association consists of illite or a mixture of illite and smectite, and chlorite. The Lidzbark Formation and the lowermost part of the Malbork Formation show less variability in mineralogical composition than the upper part of the Malbork Formation. Smectite admixtures were detected only in the upper part of the Malbork Formation (the uppermost Middle Buntsandstein). The boron content, achieved after aqua regia digestion, ranges from 70 to 121 mg/kg (96 mg/kg at average), oscillating generally around 90 mg/kg. A higher boron content, bound in silicate structure, is associated with the upper part of the Malbork Formation. All major mineralogical and geochemical changes coincide more or less with the transition from the supposed marine to the terrestrial environmental realm, interpreted from lithological and sedimentological observations within the lowermost part of the Malbork Formation. However, diagenetic alteration of the clay minerals, and of the boron content, could not be ruled out. The oolitic limestones, mainly grainstones, contain admixtures of quartz grains and rare bioclasts, the ooids nuclei being peloids or unrecognizable. The carbonates are almost exclusively composed of low-Mg calcite. A high content of Mg and the presence of small amounts of dolomite suggest that the ooids were primarily composed of high-Mg calcite and are comparable with similar Early Triassic deposits in Tethyan settings. The δ13C values range from -2 to +1%o VPDB, fitting well with the known ranges of Lower Triassic marine carbonates. An observed δ13C depletion towards the top of the oolite-bearing part of the section may reflect a local shallowing trend that led to overall salinity decrease. A possible connection with the one of the global oceanic geochemical episodes has to be tested further. The results obtained suggest a marine origin of the lower Middle Buntsandstein deposits studied and document a terrestrial origin for the upper Malbork Formation.
    Źródło:
    Geological Quarterly; 2020, 64, 4; 1023---1047
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Climatic disaster at theTriassic–Jurassic bound ary – a clay minerals and major elements record from the Polish Basin
    Autorzy:
    Brański, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059743.pdf
    Data publikacji:
    2014
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Triassic–Jurassic boundary
    clay minerals
    major elements
    weathering regime
    palaeoclimatic shifts
    Polish Basin
    Opis:
    The Triassic-Jurassic boundary interval (ca. 201 Ma) was a time of sudden global environmental changes triggered by Pangea breakup and Central Atlantic Magmatic Province development. The bulk-rock mineralogy, clay mineralogy and major element geochemistry of 87 continental mudrock samples collected from four borehole cores yield information on Rhaetian-earliest Hettangian palaeoclimatic changes in the Polish Basin. During the Rhaetian, smectite preponderance was replaced by kaolinite and illite domination. This fundamental shift in clay mineral assemblages (supported by major element data) indicates very significant change in climate humidity. Moreover, some beds in the Zagaje Formation (Upper Rhaetian-Lower Hettangian) are particularly rich in kaolinite indicating extreme chemical weathering in humid-subtropical to tropical climate episodes in the aftermath of powerful warming and abundant rainfall. Importantly, the first distinct kaolinite enrichment appears already in the Lower Rhaetian Wielichowo Beds. In addition, abrupt and episodic shifts in the kaolinite-illite ratio and in values of weathering indices point to profound climate destabilisation and a sequence of frequent, catastrophic climatic reversals in the Late Rhaetian and at the Triassic-Jurassic boundary. These results are generally consistent with carbon isotope records in sections worldwide.
    Źródło:
    Geological Quarterly; 2014, 58, 2; 291--310
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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