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Wyszukujesz frazę "Aniline" wg kryterium: Temat

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    Tytuł:
    Assessment of Modified Rice Husks for Removal of Aniline in Batch Adsorption Process: Optimization and Isotherm Study
    Autorzy:
    Dakhil, Ihsan Habib
    Naser, Ghazi Faisal
    Ali, Ahmed Hassan
    Powiązania:
    https://bibliotekanauki.pl/articles/1955426.pdf
    Data publikacji:
    2021
    Wydawca:
    Polskie Towarzystwo Inżynierii Ekologicznej
    Tematy:
    adsorption
    aniline
    modified rice husk
    optimization
    Opis:
    The present work is aimed at investigating the capability of chemically modified rice husks (MRH) for the reduction of aniline ions from industrial wastewater. The experiments have been conducted to examine the influence of four operating parameters in the batch adsorption technique. The effect of initial concentrations of aniline (10–100) mg•L-1, MRH dose (0.1–1) g/100 ml, pH (3–9), and contact time (10–90) min has been studied. The selected range of operating factors was designed using the response surface method to establish a mathematical model that describes the adsorption process. The optimum parameters were 25 mg•L-1 initial concentration of aniline, 0.68 g MRH dose, 6.6 pH, and 70 min contact time. The point of zero charge was found equal to 6.8. The maximum removal efficiency of 84.97% was found under optimum conditions. The consistency of the mathematical model has been examined and the equilibrium results confirmed with the standard adsorption isotherm models, Langmuir and Freundlich, with a high correlation coefficient.
    Źródło:
    Journal of Ecological Engineering; 2021, 22, 7; 179-189
    2299-8993
    Pojawia się w:
    Journal of Ecological Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Theoretical ultrasonic velocities in binary liquid mixture containing aniline and anisole at different temperatures – a comparative study
    Autorzy:
    Sreedevi, Y.
    Srinivasu, Ch.
    Fakruddin, Sk.
    Narendra, K.
    Venkateswara Rao, B.R.
    Nirmal Rajeev, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/412398.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ultrasonic velocity
    aniline
    anisole
    binary liquid mixtures
    Opis:
    Ultrasonic velocity is measured experimentally at 3MHz frequency in the binary liquid mixture containing aniline and anisole at different temperatures over the entire composition range and theoretical values of ultrasonic velocity have been evaluated by using Nomoto’s relation, Impedance relation, Van Dael ideal mixture relation. These theoretical values are compared with the experimental values. A good agreement has been found between experimental and theoretical ultrasonic velocities.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 7, 2; 120-124
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Batch extractive distillation of mixture methanol-acetonitrile using aniline as a asolvent
    Autorzy:
    Li, G.
    Yu, Y.
    Bai, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/779141.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    batch extractive distillation
    methanol
    acetonitrile
    aniline
    simulation
    Opis:
    Methanol and acetonitrile form a minimum azeotrope at 336.74 K, which contains methanol 76.89 mas%. The simulation and the experiment to separate the mixture by batch extractive distillation using aniline as entrainer is performed. Based on the experimental and simulative VLE data, aniline is chosen to be the suitable solvent. The sensitivity analysis about the number of stages, the refl ux ratio, the solvent feed stage and the solvent fl ow rate is conducted to obtain the optimal parameters and confi guration of the extractive distillation column with minimal energy requirements. The most appropriate confi guration is 30 theoretical stages. The optimal entrainer feeding stage is 8 with a solvent fl ow rate of 20kg/h and the refl ux ratio of 2.0, respectively. The simulation results show the effect of the main variables on the extractive distillation process. The experiment is carried out to corroborate the feasibility of the separation of methanol-acetonitrile by batch extractive distillation.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 3; 48-53
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Biosorption of aniline blue from aqueous solution using a novel biosorbent Zizyphus oenoplia seeds: Modeling studies
    Autorzy:
    Kumar, M.
    Elangovan, G
    Tamilarasan, R
    Vijayakumar, G.
    Mukeshkumar, P. C.
    Sendhilnathan, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/778750.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    aniline blue
    removal
    biosorption
    Zizyphus oenoplia seed
    modeling
    Opis:
    This article presents the feasibility for the removal of Aniline Blue dye (AB dye) from aqueous solution using a low cost biosorbent material Zizyphus oenoplia seeds. In this study, a batch mode experiments of the adsorption process were carried out as a function of pH, contact time, concentration of dye, adsorbent dosage and temperature. The experimental data were fitted with Freundlich and Langmuir isotherm equations. The feasibility of the isotherm was evaluated with dimensionless separation factor (RL). The kinetic data of sorption process are evaluated by using pseudo-first order and pseudo-second order equations. The mode of diffusion process was evaluated with intra-particle diffusion model. The thermodynamic parameters like change in enthalpy (ΔHº); change in entropy (ΔSº) and Gibbs free energy change (ΔGº) were calculated using Van’t Hoff plot. The biosorbent material was characterized with Fourier Transform Infrared (FTIR) spectroscopy and the morphology was identified with Scanning Electron Microscope (SEM) in before and after adsorption of AB dye.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 3; 70-77
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of alkali metal promoters on catalytic performance of Co-based catalysts in selective hydrogenation of aniline to cyclohexylamine
    Autorzy:
    Valeš, Roman
    Zapletal, Martin
    Krupka, Jiří
    Powiązania:
    https://bibliotekanauki.pl/articles/2204145.pdf
    Data publikacji:
    2023
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Aniline
    Cyclohexylamine
    Hydrogenation
    Cobalt catalyst
    Alkali metal carbonate
    Opis:
    In this study, a series of Co-based catalysts with alkali metal carbonate promoters were prepared to investigate the interrelation between promotion effect of these carbonates and catalytic performance for aniline hydrogenation to cyclohexylamine in vapour phase. The chemical promoters Li2CO3 and Na2CO3 leading to decrease in catalytic activity of cobalt catalysts for aniline hydrogenation. Catalysts with K2CO3 and Cs2CO3 loadings have practically no catalytic activity for hydrogenation of aniline. Results of TPD of aniline proved that presence of alkali metals carbonates restricts the adsorption of aniline on the surface of cobalt catalysts. Further, it was found that the addition of Na2CO3 greatly enhances the catalytic selectivity towards the cyclohexylamine and inhibits the consecutive reactions of cyclohexylamine leading to formation of by-products such as dicyclohexylamine and N-phenylcyclohexylamine.
    Źródło:
    Polish Journal of Chemical Technology; 2023, 25, 1; 1--7
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Meso-tetraphenylporphyriniron(iii) chloride catalyzed oxidation of aniline and its substituents by magnesium monoperoxyphthalate in aqueous acetic acid medium
    Autorzy:
    Raja, M.
    Kulandaivelu, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/779003.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Aniline oxidation
    kinetics
    mechanism
    magnesium monoperoxyphthalate
    meso-tetraphenylporphyriniron(III) chloride
    catalyst
    Opis:
    The catalytic properties of the fi rst generation catalyst meso-tetraphenylporphyriniron(III) chloride and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in the oxidation of aniline and its substituents in acetic acid medium. The thermodynamic parameters for the oxidation have been determined and discussed. It confi rms the Exner relationship (only at the low range of temperatures) and also some of the activation parameters to the isokinetic relationships. The magnesium monoperoxyphthalate oxidation with 18 ortho- meta- and para-substituted anilines fulfi lls with isokinetic relationship but not to any of the linear free energy relationships. The reaction mechanism and the rate law were proposed.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 4; 35-41
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and characterization of Poly(n-ethyl aniline) / Talc composite materials
    Synteza i charakterystyka Poli(N-etylo aniliny) / Talk
    Autorzy:
    Anakli, D.
    Cetinkaya, S.
    Karakisla, M.
    Sacak, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/318872.pdf
    Data publikacji:
    2013
    Wydawca:
    Polskie Towarzystwo Przeróbki Kopalin
    Tematy:
    talc
    n-ethyl aniline
    conducting polymer
    composite
    talk
    n-etylo anilina
    polimer przewodzący
    kompozyt
    Opis:
    A new substituted polyaniline/layered talc conductive composite material were synthesized chemically using ammonium persulfate as oxidizing agent in aqueous HCl medium. The oxidant type, N-ethyl aniline to oxidant mole ratio and N-ethyl aniline concentration on the PNEAn content and conductivity of the composite were investigated as the effect of the polymerization conditions. Optimum reaction conditions were outlined as NEAn/oxidant ratio 1 and 0.2 M NEAn monomer concentration with (NH4)2S2O8 on the poly(N-ethyl aniline) yield and conductivity. The conductive composites were characterized by two probe technique for surface resistance and thermo gravimetric analysis (TGA) techniques. The increased thermal stability of the composite compared to that of pure polymer was obtained by the thermogravimetric analysis method.
    Nowy przewodzący materiał kompozytowy podstawiony polianiliną/warstwowany talkiem zsyntetyzowano chemicznie przy użyciu nadtlenodisiarczanu amonu jako czynnika utleniającego w wodnym kwasie chlorowodorowym. Badano rodzaj utleniacza, anilinę N-etylową do stosunku molowego utleniacza oraz stężenie aniliny N-etylowej w PNEAn [Poly( N-ethyl aniline)] oraz przewodność kompozytu co jednocześnie było skutkiem warunków polimeryzacji. Optymalnymi warunkami jakie określono dla reakcji to NEAn/utleniacz w stosunku 1 oraz 0,2M stężenie monomeru NEAn wraz z (NH4)2S2O8 na polianilinie N-etylowej. Kompozyty przewodzące zostały scharakteryzowane przez badanie oporu powierzchni oraz analizę termograwimetryczną (TGA). Zwiększona stabilność termiczna kompozytu została porównana do tej z czystego polimeru została określona przez metodę termograwimetryczną.
    Źródło:
    Inżynieria Mineralna; 2013, R. 14, nr 2, 2; 115-118
    1640-4920
    Pojawia się w:
    Inżynieria Mineralna
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, characterization, biological activity of Schiff bases derived from 2-bromo-4-methyl aniline and its potentiometric studies with Cu(II), Co(II) and Ni(II) ions
    Autorzy:
    Upadhyay, Surbhi V.
    Zala, Raksha V.
    Bhatt, Keyur D.
    Powiązania:
    https://bibliotekanauki.pl/articles/1030767.pdf
    Data publikacji:
    2020
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    2-bromo-4-methyl aniline
    Antimicrobial activity
    Irving-Rossotti
    Potentiometric studies
    Schiff base
    Stability constant
    Opis:
    Schiff bases namely, 2-bromo-4-methyl-N-(2-nitrobenzylidene)aniline; 2-bromo-4-methyl-N-(2,4,5-trimethoxybenzylidene)aniline; 2-bromo-N-(4-methoxybenzylidene)-4-methylaniline and N-((1H-indol-3-yl)methylene-2-bromo-4-methylaniline have been synthesized and characterized by elemental analysis, FT-IR, Mass and 1H-NMR spectroscopy. Schiff bases have been screened for Antimicrobial activity against bacteria and fungi by using MIC determination. Binary complexes of Co(II), Ni(II) and Cu(II) with Schiff bases in solution have been studied potentiometrically in 60:40 % (V/V) 1,4-dioxane-water system at constant temperature 27 ±0.5 ºC and at an ionic strength of 0.1 M KNO3. The order of stability constant of formed binary complexes in solution was examined.
    Źródło:
    World Scientific News; 2020, 145; 1-15
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Spectral studies and antimicrobial activities of some (E)-N-(substituted benzylidene)-2,6-diisopropylanilines
    Autorzy:
    Thirunarayanan, G.
    Manikandan, V.
    Aarulkumaran, R.
    Rarajan, R.
    Usha, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182740.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    2
    6-di(propan-2-yl)aniline
    Schiff base
    Spectral correlation and Antimicrobial studies
    Synthesis
    Opis:
    A series of Schiff’s base compounds were synthesized from 2,6-di(propan-2-yl) aniline with substituted aromatic aldehydes. The structures of all the synthesized compounds were characterized by physical constants, IR and NMR spectroscopic techniques. All the observed IR frequencies νC=N (cm-1), NMR δ(ppm) of C-H & C=N chemical shifts have been correlated with Hammett substituent constants and F and R parameters using single and multi-linear regression analyses in order to study the effect of substituents on these spectral data has been studied. All the synthesized Schiff’s base compounds were screened for their antimicrobial activity by disc diffusion method.
    Źródło:
    World Scientific News; 2017, 66; 20-42
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of IR and NMR spectral correlations and biological evaluation of 4-(6-ethyl-2-(substituted phenyl)-6H-pyrido[3,2-b]carbazol-4-yl) aniline derivatives
    Autorzy:
    Thirunarayanan, Ganesamoorthy
    Powiązania:
    https://bibliotekanauki.pl/articles/1189992.pdf
    Data publikacji:
    2016
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    IR and NMR spectra
    Substituent effects
    Hammett equation
    Antibacterial activity
    Antifungal activity
    pyrido[3
    2-b]carbazol-4-yl) aniline
    Opis:
    A series of seven titled compounds have been prepared and their purities were examined by literature method. The characteristic infrared stretching frequencies (, cm-1) and the NMR chemical shifts (, ppm) of these anilines were assigned. These assigned spectral data were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analysis. From the statistical results the effect of substituents on the spectral data have been discussed. The antimicrobial activities of these aniline derivatives have been evaluated by Bauer-Kirby disc-diffusion method.
    Źródło:
    World Scientific News; 2016, 52; 228-246
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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