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    Wyświetlanie 1-4 z 4
    Tytuł:
    Correlation Induced Optimization of Wave Functions: the Hubbard Chain
    Autorzy:
    Spałek, J.
    Podsiadły, R.
    Wójcik, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/2013007.pdf
    Data publikacji:
    2000-03
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    71.10.Fd
    71.15.Fv
    31.25.Nj
    Opis:
    We determine the explicit form of the single-particle Wannier functions {w$\text{}_{i}(r)}$ appearing in the parameters of quantum models. The method is illustrated on the example of the Hubbard chain, for which we derive the renormalized wave equation starting from a variational principle and by treating the system ground state energy as a functional of {w$\text{}_{i}(r)}$ and their derivatives. In this manner, the optimized basis is obtained only after the electronic correlations have been included in the rigorous Lieb-Wu solution. The results for the ground state energy and the size of the renormalized s-type orbitals, both as a function of interatomic distance, are calculated explicitly.
    Źródło:
    Acta Physica Polonica A; 2000, 97, 3; 381-384
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Studies of Fractal Aspects of Cement
    Autorzy:
    Janik, J. A.
    Kurdowski, W.
    Podsiadły, R.
    Samseth, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/1952755.pdf
    Data publikacji:
    1996-12
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    61.12.Ex
    82.70.Gg
    Opis:
    Small angle neutron scattering can be used to reveal the fractal nature of matter. The problems of fractal aspects of the structure of cement are related to those of fractal aspects of silica aerogels. Natural cement, when mixed with water, transforms after a series of chemical reactions (in a large part) into an amorphous phase called C-S-H. It is believed that the cationic sublattice composed of CaO$\text{}_{6}$ octahedrons constitutes the C-S-H structural basis, to which the SiO$\text{}_{4}$ tetrahedral chains are attached. It is a layer structure in which the cation sublattice determines the way of SiO$\text{}_{4}$ condensation. It is natural to expect that in this way one may obtain a really amorphous substance, since some tetrahedrons may be lacking, which leads to defects. We present here the results of a small angle neutron scattering and X-ray diffraction study of several samples with the pure C-S-H phase for which during the process of chemical synthesis various ratios of molar contents of CaO and SiO$\text{}_{2}$ were used (various C/S ratios). We obtained a gradual change of fractal characteristics with the change of C/S ratio.
    Źródło:
    Acta Physica Polonica A; 1996, 90, 6; 1179-1184
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Fractal Structure of C-S-H and Tobermorite Phases
    Autorzy:
    Janik, J. A.
    Kurdowski, W.
    Podsiadły, R.
    Samseth, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2028897.pdf
    Data publikacji:
    2001-10
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    61.12.Ex
    82.70.Gg
    Opis:
    The C-S-H I phase is the main component of the cement paste, which is a near-amorphous, highly porous gel. Due to high porosity of the sample in this phase we can observe a fractal nature of the volume pores distribution, similar to that observed for silica aerogels. The C-S-H I phase is thermodynamically unstable and crystallize to a tobermorite phase, forming crystal aggregates on the surface of the amorphous paste. The mixture of these two phases, formed in this way, have irregular volume and surface structures, both of which may exhibit the fractal nature. To study the fractal nature of the matter the small angle neutron scattering method is frequently used. We present here the results of small angle neutron scattering studies supported by the X-ray diffraction and scanning electron microscope observations of several samples with the common molar C/S ratio equal to 1. Some of the samples were autoclaved during various time periods to accelerate transformation of the C-S-H I phase to tobermorite. We observed the fractal properties of the volume structure of all samples under study. Moreover, we observed also the fractal behaviors of the surfaces of the samples which were autoclaved.
    Źródło:
    Acta Physica Polonica A; 2001, 100, 4; 529-537
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Utilization of spent iron catalyst for ammonia synthesis
    Autorzy:
    Arabczyk, W.
    Narkiewicz, U.
    Lendzion-Bieluń, Z.
    Moszyński, D.
    Pełech, I.
    Ekiert, E.
    Podsiadły, M.
    Pelka, R.
    Jędrzejewski, R.
    Moszyñska, I.
    Sibera, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/778207.pdf
    Data publikacji:
    2007
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    katalizator żelazowy
    azotki żelaza
    nanorurka węglowa
    nanowłókna
    iron catalyst
    iron nitrides
    carbon nanotubes
    nanofibers
    Opis:
    Several methods of the utilization of spent iron catalyst for ammonia synthesis have been presented. The formation of iron nitrides of different stoichiometry by direct nitriding in ammonia in the range of temperatures between 350°C and 450°C has been shown. The preparation methods of carbon nanotubes and nanofibers where iron catalyst catalyse the decomposition of hydrocarbons have been described. The formation of magnetite embedded in a carbon material by direct oxidation of carburized iron catalyst has been also presented.
    Źródło:
    Polish Journal of Chemical Technology; 2007, 9, 3; 108-113
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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