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Wyświetlanie 1-3 z 3
Tytuł:
Synthesis and Characterization of ZnO/MnFe2O4 Nanocomposites for Degrading Cationic Dyes
Autorzy:
Yuniar
Agustina, Tuty Emilia
Faizal, Muhammad
Hariani, Poedji Loekitowati
Powiązania:
https://bibliotekanauki.pl/articles/24201760.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
nanocomposite
ZnO/Fe2O4
cationic dyestuff
photocatalysis
Opis:
By breaking down harmful dye waste into harmless components under the right irradiation sources, photocatalysis is an unorthodox but promising technique that can reduce industrial wastewater pollution, particularly in the textile industry. Synthetic textile dyes called cationic dyes must be handled carefully because they are poisonous and challenging to breakdown. Photocatalytic oxidation is a useful technique for eliminating hazardous organic pigments. This investigation aims to synthesize and characterize ZnO/MnFe2O4 nanocomposites as well as investigate the effects of varying ZnO:MnFe2O4 ratios, pH levels, doses, and irradiation times on band gap reduction and photocatalytic applications tested with cationic dyes, specifically methylene blue, under the illumination of sunlight. the co-precipitation approach for the manufacture of nanocomposites with different mole ratios of ZnO:MnFe2O4 (1:0.1; 2:0.1; 3:0.1). The component comprising the nanocomposite is ZnO/MnFe2O4, according to the results of the characterisation using XRD, SEM-EDX, FTIR, and BET. UV-DRS measurements of the band gap revealed that as ZnO was reduced, the band gap of the nanocomposite likewise decreased, from 3.35 eV to 2.78 eV. The greatest degradation of 93.2% was achieved for the degradation of 50 mg/L methylene blue (MB) dye with a catalyst dosage of 20 mg at a ratio of 1:0.2 for 50 minutes of irradiation. Since the point of zero charges (pzc) was reached at a pH of 7.8, a photodegradation adsorption-friendly solution pH of 8 was created.
Źródło:
Journal of Ecological Engineering; 2023, 24, 4; 252--263
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of Calcium Oxide from Green Mussel Shell with Iron Oxide as a Potential Adsorbent for the Removal of Iron and Manganese Ions from Acid Mine Drainage
Autorzy:
Purwaningrum, Widia
Hasanudin, Hasanudin
Rachmat, Addy
Riyanti, Fahma
Hariani, Poedji Loekitowati
Powiązania:
https://bibliotekanauki.pl/articles/2202252.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
CaO/Fe3O4
green mussel shell
adsorption
iron
manganese
acid mine drainage
Opis:
Acid mine drainage (AMD) has the characteristics of high heavy metal ion content and low pH. This study aimed to synthesize the CaO/Fe3O4 composite for the adsorption of iron and manganese ions from acid mine drainage. CaO was synthesized from the shells of green mussels (Perna viridis). The CaO/ Fe3O4 composites were characterized using XRD, BET surface area, SEM-EDS, and VSM. The functional groups of the composite before and after adsorption were analyzed using FTIR. The adsorption of Fe(II), Fe(III), and Mn(II) ions was carried out with the batch method to determine the effect of pH, contact time, and initial concentration of metal ions. The CaO/ Fe3O4 composite has magnetic properties, as indicated by the saturation magnetization value of 65.49 emu/g. The Langmuir and Freundlich isotherm models were used to describe the adsorption isotherm of the composite for Fe(II), Fe(III), and Mn(II) ions. Investigations were also conducted on adsorption kinetics, including pseudo-first-order and pseudo-second-order, as well as adsorption thermodynamics comprising free energy, enthalpy, and entropy. Pseudo-first-order and Langmuir isotherms are suitable to describe the adsorption of Fe(II), Fe(III), and Mn(II) ions with adsorption capacities of Fe(III) > Fe(II) > Mn(II). Moreover, the adsorption of all ions using the composite occurred spontaneously. The removal effectiveness for Fe and Mn ions from AMD using CaO/ Fe3O4 composite, reached 90.41 and 97.59%, respectively, in volume 100 mL AMD, composite mass 0.4 g, and a contact time of 60 minutes.
Źródło:
Journal of Ecological Engineering; 2022, 23, 11; 188--201
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High Efficient Photocatalytic Degradation of Methyl Orange Dye in an Aqueous Solution by $CoFe_2O_4-SiO_2-TiO_2$ Magnetic Catalyst
Autorzy:
Hariani, Poedji Loekitowati
Said, Muhammad
Salni, -
Aprianti, Nabila
Naibaho, Yohanna Asina Lasma Rohana
Powiązania:
https://bibliotekanauki.pl/articles/2025485.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
magnetic
degradation
photocatalytic
methyl orange
Opis:
This study successfully synthesized a core-shell-shell in the form of $CoFe_2O_4-SiO_2-TiO_2$ catalyst magnetic and recyclable. The catalyst was employed for the photocatalytic degradation of methyl orange (MO) dye. Subsequently, the catalyst was subjected to XRD, FTIR, SEM-EDS, VSM, as well as UV-DRS characterizations. The photocatalytic degradation was studied as a function of the solution pH, MO concentration, and irradiation time, while the kinetics of photocatalytic degradation and the catalyst reusability were also evaluated. On the basis of the XRD, FTIR, and SEM-EDS characterizations, the $CoFe_2O_4$ coating was successfully carried out using $SiO_2$ and $TiO_2$. $CoFe_2O_4-SiO_2-TiO_2$ was discovered to possess magnetic properties with a saturation magnetization of 17.59 emu/g and a bandgap value of 2.4 eV. The photocatalytic degradation of MO followed the Langmuir-Hishelwood model. The optimum degradation was obtained at the MO concentration of 25 mg/L, solution pH of 4, catalyst dose of 0.05 g/L, irradiation time of 160 minutes, MO removal efficiency achieved 93.46%. The regeneration study showed $CoFe_2O_4-SiO_2-TiO_2$ after 5 cycles were able to catalyze the photocatalytic degradation with an MO removal efficiency of 89.96%.
Źródło:
Journal of Ecological Engineering; 2022, 23, 1; 118-128
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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