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    Wyświetlanie 1-11 z 11
    Tytuł:
    Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411747.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange reactions
    nuclear grade resins
    cation exchange resins
    enthalpy
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 127-135
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. K. L.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411848.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange equilibrium
    nuclear grade resins
    cation exchange
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 231-239
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412153.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    cation exchange
    nuclear grade resins
    ion exchangers
    change in enthalpy
    equilibrium constant in standard state
    Indion-223
    Opis:
    In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 199-207
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Assessment of physico-chemical properties of sediments collected along the Mahul Creek near Mumbai, India
    Autorzy:
    Singare, P.U.
    Ansari, M.V.A.
    Dixit, N.N.
    Powiązania:
    https://bibliotekanauki.pl/articles/11066.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    assessment
    physicochemical property
    sediment
    industrial effluent
    toxic pollutant
    Mahul Creek
    Mumbai city
    India
    Opis:
    The present study was performed for the period of one year from January 2013 to December 2013 in order to understand the physico-chemical properties of sediments samples collected along the Mahul Creek of Mumbai. The annual average pH value of the creek sediments was recorded as 5.38. It is feared that such low pH value of sediment might increase the acidity of creek water thereby triggering the heavy metal toxicity which will further reduced survivorship in fish through chronic stress and affect the reproductive partner. The annual average salinity content of the sediment was recorded as 4601.17 ppm. It is important here to note that the high salinity of the sediment may increase the salinity level of creek water which is considered as a major stress factor for most freshwater organisms including crustaceans. The average annual concentration of phosphate in the creek sediment was found to 480.39 ppm. Such high concentration of phosphate in the creek sediments might accelerate the process of eutrophication. From the results it appears that as India moves towards stricter regulation of industrial effluents to control water pollution, greater efforts are required to reduce the risk due to the toxic pollutants which are released into the ecosystems.
    Źródło:
    International Letters of Natural Sciences; 2014, 11, 1
    2300-9675
    Pojawia się w:
    International Letters of Natural Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Toxic heavy metals in sediments of Mahul Creek near Mumbai, India
    Autorzy:
    Singare, P.U.
    Ansari, M.V.A.
    Dixit, N.N.
    Powiązania:
    https://bibliotekanauki.pl/articles/11831.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    toxic metal
    heavy metal
    sediment
    creek sediment
    industrial effluent
    Mahul Creek
    India
    Opis:
    The present study was performed for the period of one year from January 2013 to December 2013 in order to understand the level of toxic heavy metals in the sediments of Mahul Creek near Mumbai. The annual average concentration of heavy metals like Cr, Zn, Cu, Ni, Pb, Cd, As and Hg was found to be 277.5, 121.7, 100.3, 63.8, 21.5, 14.6, 10.4 and 4.9 ppm respectively. It is feared that this heavy metals accumulated in the creek sediments may enter the water thereby creating threat to the biological life of an aquatic ecosystem. The results of present study indicates that the existing situation if mishandled can cause irreparable ecological harm in the long term well masked by short term economic prosperity due to extensive industrial growth.
    Źródło:
    International Letters of Natural Sciences; 2014, 10
    2300-9675
    Pojawia się w:
    International Letters of Natural Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Toxic heavy metals in the Mahul Creek water of Mumbai, India
    Autorzy:
    Singare, P.U.
    Ansari, M.V.A.
    Dixit, N.N.
    Powiązania:
    https://bibliotekanauki.pl/articles/11858.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    toxic metal
    heavy metal
    Mahul Creek
    creek water
    industrial effluent
    India
    Opis:
    The present study was performed for the period of one year from January 2013 to December 2013 in order to understand the level of toxic heavy metals in the water of Mahul Creek near Mumbai. It was observed that the annual average concentration of heavy metals like Cd, As, Hg, Cr, Pb, Cu, Ni and Zn, was found to be 0.003, 0.004, 0.0009, 0.012, 0.015, 0.019, 0.04 and 0.23 ppm respectively. The results suggest that there is a need to have such scientific monitoring for longer time period in order to understand the trend in level of these toxic heavy metals discharged in to the creek water. It is feared that the existing problem if ignored may increase the level of this heavy metals in creek water thereby creating threat to the biological life of an aquatic ecosystem. From the results of the present investigation it seems that the time has come to move towards ecosystem specific discharge standards to maintain the health and productivity of natural resources on which the majority of Indians are dependent.
    Źródło:
    International Letters of Natural Sciences; 2014, 10
    2300-9675
    Pojawia się w:
    International Letters of Natural Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Water pollution along the Mahul Creek of Mumbai, India – Study of physico-chemical properties
    Autorzy:
    Singare, P.U.
    Ansari, M.V.A.
    Dixit, N.N.
    Powiązania:
    https://bibliotekanauki.pl/articles/10886.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    water pollution
    Mahul Creek
    creek water
    Mumbai city
    India
    physicochemical property
    industrial effluent
    Opis:
    The present study was performed for the period of one year from January 2013 to December 2013 in order to understand the physico-chemical properties of Mahul Creek water. From the results of our study it was observed that the annual average COD level was 362.09 ppm which was far higher than the maximum tolerable level of 250 ppm set for inland surface water as well as for marine coastal water. The annual average conductivity was found to be 6122.81 μS cm-1 which was very much above the conductivity limit for inland surface water of 1000 μS cm-1 set by Central Pollution Control Board (CPCB) for propagation of fisheries. The annual average total alkalinity level was recorded as 166.25 ppm, which according to the UN Department of Technical Cooperation for Development (1985) was found to be strongly alkaline. The annual average hardness level of the creek water was found to be 2488.65 ppm which was above the limit of 300 ppm set by ISI. From the results of the present investigation it seems that the time has come to implement proper effluent water treatment techniques and enforcement of pollution control by the regulatory authority on the indiscriminate discharge of industrial wastewater into water bodies.
    Źródło:
    International Letters of Natural Sciences; 2014, 11, 1
    2300-9675
    Pojawia się w:
    International Letters of Natural Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on preferential selectivity of nuclear grade resin Indion-223 towards some bivalent ions
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412085.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    bivalent exchange reactions
    nuclear grade resins
    cation exchange
    reaction thermodynamics
    enthalpy change
    ionic selectivity
    equilibrium constant
    Indion-223
    Opis:
    In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 15; 11-21
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412388.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange
    nuclear grade resins
    cation exchangers
    enthalpy change
    standard equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 190-198
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412486.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    uni-univalent ion exchange reactions
    ionic selectivity
    nuclear grade resins
    cation exchangers
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 15; 22-29
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analysis of scopoletin and mangiferin in botanicals and formulations of Shankhpushpi by HPLC
    Autorzy:
    Nahata, A.
    Sethiya, N.K.
    Jain, N.
    Dixit, V.K.
    Powiązania:
    https://bibliotekanauki.pl/articles/71638.pdf
    Data publikacji:
    2018
    Wydawca:
    Instytut Włókien Naturalnych i Roślin Zielarskich
    Opis:
    Introduction: Shankhpushpi has been widely used in traditional Indian systems of medicine as a brain and memory boosting tonic. There are a variety of botanicals reported to be used as sources of Shankhpushpi in various parts of India. For instance, Canscora decussata Schult, Clitorea ternatea Linn., Convolvulus pluricaulis Choisy. and Evolvulus alsinoides Linn. are most commonly used as sources of Shankhpushpi by practitioners of Ayurveda in different parts of the country. Objective: When it comes to using Shankhpushpi in herbal formulations, qualitative and quantitative analysis of the correct botanicals in the formulation decides its pharmacological effectiveness. Scopoletin and mangiferin are proven bioactive markers identified in Shankhpushpi botanicals in our previous studies. Hence the study is aimed at providing a simple analytical method for the identification of the correct variety of Shankhpushpi using proven markers. Methods: In this study, a High Performance Liquid Chromatographic (HPLC) method has been developed for the estimation of scopoletin and mangiferin levels in four botanicals of Shankhpushpi and their marketed formulations. Result: A simple analytical method was developed which proved to be very crucial in estimating concentrations of mangiferin and scopoletin in various test samples. This method can be used to identify the correct botanicals of Shankhpushpi present in any Ayurvedic formulation or raw material or processed powder by evaluating the content of scopoletin or mangiferin as markers. Conclusion: The developed HPLC method is a quick and reliable method for the quantitative monitoring of mangiferin and scopoletin in herbal extracts and marketed formulations of Shankhpushpi.
    Źródło:
    Herba Polonica; 2018, 64, 4
    0018-0599
    Pojawia się w:
    Herba Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-11 z 11

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