Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "TNT" wg kryterium: Wszystkie pola

  Lista filtrów
Wyrównaj
Wyświetlanie 1-15 z 23
Tytuł:
Fortifcation of W/O Emulsions by Demilitarized Explosives. Part I. Use of TNT
Autorzy:
Němec, O.
Jungová, M.
Mareček, R.
Novotný, M.
Zeman, S.
Šelešovský, J.
Powiązania:
https://bibliotekanauki.pl/articles/358504.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
demilitarized explosives
detonation
emulsion
TNT
Opis:
This paper presents a study of the relationship between detonation velocities, D, and relative explosive strength (RS) of fortifed W/O emulsion explosives, on the one hand, and the grain size and quality of the demilitarized TNT used for this fortifcation, on the other. It has been found that demilitarized TNT having a grain size below 400 μm could give acceptable results both in terms of initiation and detonation velocity and the RS values. Demilitarized TNT, however, is not a reliable sensitizer even in a micronized state, and therefore using TNT necessitates simultaneous sensitizing of the fnal W/O explosive with microballoons and it has no signifcantly better infuence on the performance of the resulting explosives. The small-scale cook-off test of such a W/O mixture fortifed by 50% by wt. of TNT has shown that such a mixture is a relatively safe explosive.
Źródło:
Central European Journal of Energetic Materials; 2011, 8, 3; 193-207
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Reinforcement of the TNT System by a Newly-designed GAP-based Polyurethane-Urea: a Molecular Simulation Investigation
Autorzy:
Qian, W.
Shu, Y.
Ma, Q.
Li, H.
Wang, S.
Chen, X.
Powiązania:
https://bibliotekanauki.pl/articles/358512.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
TNT
GAP
polyurethane-urea
inter-molecular interaction
mechanical properties
Opis:
A glycidyl azide (GAP)-based polyurethane-urea (PUU) modifier used in the 1,3,5-trinitrotoluene (TNT)-based composite explosive was investigated by molecular simulation. Inter-molecular interactions were investigated using quantum chemistry calculation on the dimer of TNT and GAP-PUU, and attractive forces were found between the two molecules. The cohesive energy densities and the solubility parameters were obtained through molecular dynamics simulations combined with thermodynamic calculations on the TNT and GAP-PUU amorphous cell models, and the miscibility of the modifier in molten TNT was predicted to be good. The interaction energies and the mechanical properties were then obtained by molecular simulations and mechanical calculations on the solid-phase models of the GAP-PUU with TNT along three crystalline directions, and an improvement in the mechanical properties was predicted.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 2; 411-426
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on NTO-, FOX-7- and DNAN-based Melt Cast Formulations
Autorzy:
Mishra, V. S.
Vadali, S. R.
Bhagat, A. L.
Garg, R. K.
Kugaonkar, V. M.
Raman, S.
Sinha, R. K.
Asthana, S.
Powiązania:
https://bibliotekanauki.pl/articles/358500.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
melt cast
DNAN
TNT
FOX-7
NTO
RDX/TNT
VOD
sensitivity
Opis:
In the present paper, 2,4-dinitroanisole (DNAN) has been evaluated as a melt cast explosive in comparison to the widely used 2,4,6-trinitrotoluene (TNT). The detonation failure diameter of a bare DNAN charge is greater than 100 mm and about 44 mm with 1.5 mm steel confinement. Comparative studies of two sets of formulations were carried out. The first set comprised formulations containing 60% of NTO, FOX-7, HMX or RDX and 40% of DNAN or TNT. The second set comprised formulations containing 30% of NTO, FOX-7, TATB or RDX and 70% of DNAN or TNT. The studies were mainly concentrated on characterization of the formulations, which included determination of the sensitivity parameters and the velocity of detonation (VOD). The study confirmed that DNAN and DNAN-based formulations are relatively insensitive compared to TNT and the analogous TNT-based formulations respectively. The rate of the detonation reaction of DNAN is enhanced in the presence of the high energy ingredients RDX, HMX, FOX-7 and NTO to varying degrees. The VODs of the FOX-7/TNT and RDX/TNT formulations match closely with the proportions of FOX-7 and RDX under study. The VOD and shock sensitivity of the FOX-7/DNAN formulations decrease rapidly compared to the RDX/DNAN formulations, with increases in the proportion of FOX-7 or RDX. The combinations of NTO with TNT, and NTO with DNAN, are more shock insensitive than TNT or DNAN alone. NTO-based compositions are more insensitive than FOX-7-based compositions.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 2; 403-417
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on Stripping-down TNT from Waste Munitions by Supercritical CO2 Fluid Extraction under Low Temperature Conditions
Autorzy:
Yang, T.-M.
Li, J.-S.
Su, C.-S.
Lu, K.-T.
Yeh, T.-F.
Powiązania:
https://bibliotekanauki.pl/articles/358681.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
treatment of waste munitions
supercritical fluid extraction technique
TNT
stripping-down
low temperature conditions
Opis:
The traditional methods of waste munitions treatment are expensive and also have potential risks during the treatment process. The supercritical fluid extraction technique has been a rapidly developing technique in the chemical industry in recent years. CO2 is used as the solvent, which has some advantages, such as low pollution, low cost, good chemical stability and can be operated under low temperature conditions. This research explored the feasibility of reclaiming TNT from waste munitions by supercritical CO2 fluid extraction. It was found interestingly that the melting point of TNT can be lowered in supercritical CO2 fluid. Therefore, the melting process of TNT was observed under different temperature and pressure conditions to determine the best operating conditions for stripping-down TNT from waste munitions. Afterwards, simulated warheads with weight loadings of 60 g, 500 g and 1 kg of TNT were prepared and stripping-down tests from the simulated warheads were carried out using supercritical CO2 fluid at temperatures lower than the normal melting point of TNT. The results showed that TNT could be completely removed from the simulated warheads and the optimum operating conditions were determined as 55 °C and 25 MPa. This study will contribute to the feasibility evaluation of stripping-down TNT-based high explosives.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 191-205
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Risk assessment screening study for fire, explosion and toxicity effects of hydrocarbons stored in a sphere and bullet
Autorzy:
Behari, N.
Noga, M.
Powiązania:
https://bibliotekanauki.pl/articles/243809.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
liquefied petroleum gas
fire
boiling liquid expanding vapour cloud explosion
BLEVE
vapour cloud explosion
screening assessment
TNO technique
TNT method
pożar
eksplozja
chmura pary
ocena przesiewowa
technika TNO
metoda TNT
Opis:
A fast and economical approach was used to assess impact of fires, explosions and toxicity for a LPG gas storage facility using Fire Explosion and Chemical (FEC) Indices, the TNT and TNO multi energy methods, which are part of a process hazard analysis study. The assessment identified high consequence events for radiation, toxicity and overpressure due to catastrophic rupture of spheres and bullets holding LPG. The FEC Indices indicated that further investigation was needed to determine the extent of blast overpressure whereas toxicity was not identified as a high consequence. The TNO method was used to assess overpressure for congested volumes and unconfined vapour cloud explosions for a bullet, whereas the TNT method was used to predict overpressure occurring on a sphere with no congestion. The FEC indices can be used to screen for high consequence events in order to save time and identify the level of risk complexity needed for process equipment, whereas the TNO method can be easily applied when determining safety distances from LPG facilities for various building constructions provided that the degree of congestion is known.
Źródło:
Journal of KONES; 2017, 24, 1; 47-57
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infuence of Different Parameters on the TNT-Equivalent of an Explosion
Autorzy:
Simoens, B.
Lefebvre, M. H.
Minami, F.
Powiązania:
https://bibliotekanauki.pl/articles/357938.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
emulsion explosive
cylindrical charge
blast overpressure
blast impulse
Opis:
Emulsion explosives are used in a wide range of applications, amongst which some in closed vessels, where the properties at short range need to be known. A series of tests with spherical charges has been carried out to determine the TNT-equivalent at short range of an explosive emulsion based on both peak overpressure and impulse. Generally, the value is found to be constant over the considered range, with a value of 1 for overpressure and of 0.7 for impulse. In most common applications, explosive charges are not spherical. Experiments with cylindrical charges have been performed to study the infuence of (1) the shape of the charge (length-to-diameter ratio) and (2) the location of initiation (central or at one end). At the considered range, increasing L/D increases the peak overpressure and the impulse perpendicular to the axis, but decreases these effects on the axis. The central initiation causes the largest effects on the centreline. The initiation at one end causes a shift in the location of the peak overpressure, but the highest impulse remains on the centreline.
Źródło:
Central European Journal of Energetic Materials; 2011, 8, 1; 53-67
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simulation of the impact resistance of Kilo type submarine loaded with non-contact mine explosion
Symulacja wytrzymałości kadłuba okrętu podwodnego typu Kilo obciążonego falą ciśnienia od niekontaktowego wybuchu miny
Autorzy:
Szturomski, B.
Kiciński, R.
Powiązania:
https://bibliotekanauki.pl/articles/223246.pdf
Data publikacji:
2017
Wydawca:
Akademia Marynarki Wojennej. Wydział Dowodzenia i Operacji Morskich
Tematy:
impact resistance of the structure
model of the pressure wave
underwater explosion of TNT
acoustic medium
odporność udarowa konstrukcji
model fali ciśnienia
wybuch TNT w wodzie
ośrodek akustyczny
Opis:
The paper presents simulations of the state of stress and deformation of the Kilo class submarine hull loaded from pressure wave of non-contact mine explosion. To accomplish the task the finite element method was used. Pressure wave was described by T. L. Geers and K. S. Hunter model. The way of modeling the pressure wave using the acoustic medium implemented to CAE programs was shown. To describe the material an elastic-plastic model of Jonson-Cook which takes into account the speed of deformation was used. The paper presents pressure distribution on the Kilo type submarine hull exposed on 100 kg of TNT explosion load in front of the bow of the ship.
W artykule przedstawiono symulacje stanu naprężenia i deformacji kadłuba okrętu podwodnego klasy Kilo obciążonego falą ciśnienia od niekontaktowego wybuchu ładunku TNT. Do rozwiązania zadania wykorzystano metodę elementów skończonych. Fala ciśnienia została opisana wzorami T. L. Geersa i K. S. Huntera. Pokazano sposób modelowania fali ciśnienia przy użyciu ośrodka akustycznego realizowanego w programach CAE. Do opisu materiału użyto modelu elastyczno-plastycznego Jonsona-Cooka, który uwzględniał prędkość odkształcenia. Scharakteryzowano rozkład ciśnienia na kadłubie okrętu podwodnego typu Kilo od wybuchu 100 kg TNT przed dziobem.
Źródło:
Zeszyty Naukowe Akademii Marynarki Wojennej; 2017, R. 58 nr 1 (208), 1 (208); 99-110
0860-889X
Pojawia się w:
Zeszyty Naukowe Akademii Marynarki Wojennej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the Shape of an Explosive Charge: Quantification of the Modification of the Pressure Field
Autorzy:
Simoens, B.
Lefebvre, M.
Powiązania:
https://bibliotekanauki.pl/articles/358774.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
shape effect
emulsion explosive
C4
TNT
Opis:
Many scientific articles dealing with the detonation of explosive charges and their effects suppose that the charge is spherical and centrally initiated. Yet, when discussing the blast wave effect, the charge shape and the location of initiation could be as important as the composition or the mass of the considered explosive. Specifically, close to the charge, the shape may cause significant modifications of the pressure field compared to the predictions developed for spherical charges. Experiments have been carried out, using an emulsion explosive, TNT and C4, in order to quantify the shape effect. Unconfined, centrally initiated spherical and cylindrical charges with different length-to-diameter (L/D) ratios have been fired. The pressure in the median plane was recorded for different reduced distances. Results for spherical charges showed excellent agreement with well-known references. The expected change of the pressure field in the median plane of a cylindrical charge was observed, directly linked to the L/D ratio. Peak overpressure magnifications of up to almost 3 have been measured. The dimensions of the zone within which an increase of the blast wave effect is observed, have also been determined. A similar behaviour for TNT and C4 has been demonstrated; but a different behaviour has been observed for the emulsion explosive.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 195-213
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of Melt Cast Compositions Based on cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5 d] imidazole (BCHMX)/TNT
Autorzy:
Elbeih, A.
Zeman, S.
Powiązania:
https://bibliotekanauki.pl/articles/358268.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nitramines
BCHMX
sensitivity
detonation
brisance
Opis:
cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5 d]imidazole (BCHMX) is a new bicyclic nitramine which has been prepared using a two-stage synthetic method. In this work, a new melt cast composition based on BCHMX/TNT (60/40 by wt.) was prepared. For comparison purposes, Composition B based on RDX (1,3,5-trinitro1,3,5-triazacyclohexane)/TNT (60/40 by wt.), and HMX (1,3,5,7-tetranitro-1,3,5,7tetraazacyclooctane)/TNT (60/40 by wt.) were also studied. Impact and friction sensitivities of these compositions and of the individual explosives were determined. The detonation velocities were measured experimentally. The performance of the compositions prepared was studied by measuring the brisance using the Kast method. The detonation parameters of the compositions and the individual explosives were calculated using the EXPLO5 thermodynamic code. The results show that mixing these nitramines with TNT decreases their sensitivities. BCHMX/TNT is more sensitive to impact and friction than Composition B while it has higher detonation parameters, at the same level as HMX/TNT. In comparison, BCHMX/TNT has the highest relative brisance of the compositions studied. It is postulated that the higher performance characteristics of BCHMX and compositions based on it, in comparison with those of HMX, are due to a higher positive heat of formation for this nitramine.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 501-513
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New energetic materials derived from common explosives. Review
2,4,6-Trinitrotoluen jako źródło nowoczesnych materiałów wybuchowych. Przegląd
Autorzy:
Szala, Mateusz
Sałaciński, Tomasz
Powiązania:
https://bibliotekanauki.pl/articles/1068442.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
2,4,6-trinitrotoluene (TNT)
synthesis
cyanotrinitrobenzene
trinitro-nitromethyl-benzene
nitromethyl-diphenylamine
ATNT
BTNHT
DATNT
DNTN
HNDFM
HNS
TNAT
TNB
TNBHT
TNX
2,4,6-trinitrotoluen (TNT)
synteza
cyjano-2,4,6-trinitrobenzen
1,3,5-trinitro-2-(nitrometylo) benzen
nitro-metylo-difenyloamina
Opis:
Omówiono wybrane, mające właściwości wybuchowe lub będące potencjalnie związkami energetycznymi, produkty reakcji w których 2,4,6-trinitrotoluen jest substratem. Opisano między innymi: trinitrobenzen, cyjanotrinitrobenzen, trinitroksylen, amino-trinitrotolueny, trinitro-nitrometylo-benzen, metylenobis(2,4,6-trinitrobenzen), heksanitrostilben, nitro-metylo-difenyloaminy, 4,4’,6,6’-tetranitro- 2,2’-azoksytoluen oraz pochodne 2,4,6-trinitrobenzylidenoaminy. Dla każdego opisanego związku przedstawiono ścieżkę syntezy oraz dla wybranych materiałów podano parametry detonacyjne.
Źródło:
Materiały Wysokoenergetyczne; 2020, 12, 1; 90-110
2083-0165
Pojawia się w:
Materiały Wysokoenergetyczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Water Vapor to Explosives and Their Use for Improvised Explosive Devices
Autorzy:
Hutov, I.
Ganev, R.
Godinyachki, G.
Grozev, V.
Powiązania:
https://bibliotekanauki.pl/articles/403677.pdf
Data publikacji:
2013
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
explosives
TNT
DNN
munitions
water vapor
Opis:
This report examines the stability of TNT and dinitronaphthalene and their mixtures after their thermal extraction from the shells of artillery munitions by means of water vapor and their use for improvised explosives with high power. The comparison of the baseline explosive mixture with the samples acquired after the water vapor extraction showed no significant differences in their characteristics. Similarly, each of the explosive mixture components (TNT and DNN) after the water vapor extraction, examined separately, did not show significant differences from the original TNT and DNN characteristics.
Źródło:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa; 2013, 4, 4 (14); 77-83
2081-5891
Pojawia się w:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental Study of the Explosion of Aluminized Explosives in Air
Autorzy:
Chen, Y.
Xu, S.
Wu, D. J.
Liu, D. B.
Powiązania:
https://bibliotekanauki.pl/articles/358676.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
explosion in air
aluminized explosives
boron powders
TNT equivalence
fireballs
Opis:
Piezoelectric gauges were used to measure the shock wave overpressure of aluminized explosives and of a TNT charge. An infrared thermal-imaging spectrometer was used to collect the infrared signatures produced by the explosion fireball when the examined explosives were detonated. The measurement of the infrared signatures was used to estimate the surface temperatures and the dimensions of the fireball. Two aluminized explosive compositions (RDX/Al/AP and RDX/Al/B/AP) have been analyzed. 500 g charges of the aluminized explosives were prepared and studied, and their TNT equivalences were calculated according to the experimental data and the explosion law. The highest surface temperatures of the fireballs of these aluminized explosives were up to 1600 °C, which was higher than that of the TNT charge. In the region of the highest surface temperature above 700 °C, the duration for the composition RDX/Al/AP was about 232 ms (2.73 times more than TNT), whilst RDX/Al/B/AP was about 360 ms. The fireballs obtained from the explosion of these aluminized explosives had larger dimensions than that of TNT, especially when the surface temperature was above 1000 °C. The test results indicate that the addition of boron powders to aluminized explosives is a good way to enhance their blast effect, to improve the temperature of the explosion field and to prolong the duration of the higher temperature.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 117-134
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Content and changes in dissolved organic matter in meadow and arable soils over time
Autorzy:
Rosa, E.
Debska, B.
Pakula, J.
Tobiasova, E.
Powiązania:
https://bibliotekanauki.pl/articles/971316.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
meadow and arable soils
toc
tnt
dissolved organic matter
Opis:
Considering the discrepancies in the reports on seasonal changes in the content of dissolved organic carbon, this paper concerns the research which aimed at defining the content and seasonal changes in dissolved organic matter (DOM) in arable and meadow soils in moderate climate conditions. The research has involved the soils sampled in the kujawsko-pomorskie province (Poland). Gleic Phaeozems (meadow soils), Brunic Arenosols and Eutric Cambisols were sampled from the depth of 0-30 cm, 30-60 cm and 60-100 cm, November 2011 through September 2013. The soil samples were analyzed for dry weight content, pH, content of total organic carbon and total nitrogen. DOM was extracted with 0.004 mol·dm⁻³ CaCl₂, in the extracts the content of dissolved organic carbon (DOC) and dissolved nitrogen (DNt) were assayed. The share of DOC was determined by the soil management. The analysis of variance did not show significant differences in the content of TOC and Nt across the soil sampling dates. Were recorded changes in DOC and DNt between successive sampling dates; for topsoil for DOC – from -12.06% to 13.34% (meadow soils) and for DNt -40.84% to 47.44% (arable soils).
Źródło:
Polish Journal of Soil Science; 2019, 52, 2; 183-194
0079-2985
Pojawia się w:
Polish Journal of Soil Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Comparison of the Sensitivity and Performance Characteristics of Melt-pour Explosives with TNT and DNAN Binder
Autorzy:
Trzciński, W.
Cudziło, S.
Dyjak, S.
Nita, M.
Powiązania:
https://bibliotekanauki.pl/articles/358284.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
insensitive explosives
thermal analysis and performance
Opis:
Some sensitivity and performance characteristics for pure 2,4-dinitroanisole (DNAN) and 2,4,6-trinitrotoluene (TNT), as well as for meltpour composites containing 40% of DNAN or TNT, 20% of RDX, and 40% of NTO were determined (under the same conditions) and compared.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 3; 443-455
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Degradation Behaviour and Kinetics of aged TNT-based Melt Cast Composition B
Autorzy:
Singh, Arjun
Sharma, Tirupati Chander
Singh, Vasundhara
Mukherjee, Niladri
Powiązania:
https://bibliotekanauki.pl/articles/358256.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
composition B
thermal degradation
thermogravimetry
Differential Scanning Calorimetry
kinetics
thermodynamic parameters
Opis:
In the present paper, three kinds of aged and freshly prepared 2,4,6-trinitrotoluene (TNT) based Composition B stockpiled, for a period of 20 and 32 years, were investigated for the effect of natural ageing on their thermal degradation behaviour and kinetic parameters. The properties investigated indicated that there was no significant change in the thermal stability of the samples aged under natural environmental conditions. The kinetic parameters were studied by means of the Kissinger method using the peak temperature at maximum reaction rate from DSC data, and the isoconversional Kissinger-Akahira-Sunnose (KAS) and ASTM E689 methods from TGA data. The apparent activation energies calculated by the Kissinger method were 173.8 kJ·mol–1 for fresh, 170.4 kJ·mol–1 for 20 y old and 187.1 kJ·mol–1 for 32 y old Composition B, respectively. The values calculated by the KAS method were found to be in the range 77.2-235.8 kJ·mol–1 for fresh Composition B, 75.7-224.0 kJ·mol–1 for 20 y old and 70.4-196.0 kJ·mol–1 for 30 y old Composition B, respectively. The activation energies obtained from the KAS methods are in good agreement and consistent with the isoconversional ASTM E689 kinetic method. The thermodynamic parameters, such the Gibbs free energy of activation (ΔG#), activation enthalpy (ΔH#) and activation entropy (ΔS#) for the formation of activated complexes were also studied and are discussed.
Źródło:
Central European Journal of Energetic Materials; 2019, 16, 3; 360-379
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 23

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies