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Wyświetlanie 1-4 z 4
Tytuł:
Use of PASP and ZnSO4 mixture as depressant in the flotation separation of chalcopyrite from Cu-activated marmatite
Autorzy:
Wei, Qian
Jiao, Fen
Qin, Wenqing
Dong, Liuyang
Feng, Liqin
Powiązania:
https://bibliotekanauki.pl/articles/109451.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chalcopyrite
marmatite
polyaspartic acid
mixed depressant
adsorption
Opis:
In this study, the synergistic depressive effect of polyaspartic acid (PASP) and zinc sulfate (ZnSO4) in the flotation separation of chalcopyrite from Cu-activated marmatite was investigated by micro-flotation experiments and ore sample flotation tests, and the possible depressive mechanism was proposed from contact angle measurements, fourier transform infrared (FT-IR) analysis, inductively coupled plasma (ICP) measurements and X-ray photoelectron spectroscopy (XPS) analysis. Microflotation tests indicated that the mixed depressant PASP/ZnSO4 (PZ) exerted strong depressive effect on Cu-activated marmatite in the pH range of 9~12, but it had little effect on chalcopyrite flotation. The ore sample flotation experiments indicated the PZ system decreased the grade of Zn in Cu concentrate by 4.18%, and the depressant consumption was reduced by more than a half. The results from contact angle measurement demonstrated that the hydrophobicity of Cu activated-marmatite surface was higher than that of chalcopyrite surface in presence of PZ. FT-IR analysis demonstrated the more intensive chemisorption of PZ on Cu-activated marmatite surface. ICP measurements showed that PASP had an excellent complexing ability with Cu2+ and Zn2+, which not only reduced the activation of Cu species, but also generated Zn-PASP complex on marmatite surface. XPS analysis indicated a stronger interaction between PZ and Cu-activated marmatite surface, and the depressant PZ may mainly react with Cu-activated marmatite surface through the copper atoms.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1192-1208
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of sodium salt of N,N-dimethyldi-thiocarbamate on the flotation separation of marmatite from galena
Autorzy:
Jiao, Fen
Cui, Yanfang
Wang, Daowei
Qin, Wenqing
Powiązania:
https://bibliotekanauki.pl/articles/110431.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
DMDC
galena
marmatite
UV–vis spectroscopy
adsorption
ICP
Opis:
An organic reagent, sodium salt of N,N-dimethyldi-thiocarbamate (DMDC) was investigated as a depressant for the separation of lead activated marmatite from galena in the presence of diethyldithiocarbamate (DDTC). The flotation tests of single mineral showed that lead-activated marmatite could be depressed efficiently using DMDC as the depressant. UV–vis spectroscopy and ICP study confirmed that DMDC had a stronger capacity of complexing with lead ions or hydroxy complexes of lead. FTIR and adsorption measurement showed that the adsorption of DMDC on galena and marmatite was chemisorption. In addition, after pre-treated with DMDC, DDTC could co-adsorb on the galena surface, however, less DDTC species adsorbed on the marmatite surfaces.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 389-399
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of compound phosphate collector on flotation separation of jamesonite from marmatite and insights into adsorption mechanism
Autorzy:
Huang, Weiqin
Gu, Guohua
Chen, Xiong
Wang, Yanhong
Powiązania:
https://bibliotekanauki.pl/articles/1448921.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
compound phosphate
jamesonite
marmatite
flotation separation
adsorption mechanism
Opis:
Separating jamesonite and marmatite is difficult due to their similar response to traditional collectors. To improve the selectivity of the collector and simplify the reagent system, compound phosphate (MP) as a collector for the separation of jamesonite from marmatite was studied in this study. The flotation tests revealed that, compared with the most used butyl xanthate (BX), MP had the advantages of lower dosage and stronger selectivity under weak acid pulp. Under the optimum flotation conditions, a concentrate with the grade of 31.54% Pb, 6.93% Zn and the recovery of 89.87% Pb, 12.31% Zn could be obtained from mixed binary minerals flotation (mass ratio of 1:1). Adsorption, zeta potential, FT-IR and XPS analysis demonstrated that MP performed strong chemisorption on jamesonite surface while underwent weak physisorption on marmatite, this difference was responsible for the excellent selectivity of MP toward jamesonite flotation and weak collecting capacity to marmatite.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 294-304
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of grinding media on the flotation of copper-activated marmatite
Autorzy:
Long, Tao
Chen, Yao
Shi, Juanjuan
Chen, Wei
Zhu, Yangge
Zhang, Chonghui
Bu, Xianzhong
Powiązania:
https://bibliotekanauki.pl/articles/109857.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
grinding media
copper-activated marmatite
flotation separation
surface property
Opis:
How to avoid the shortage of floatability and non-purpose flotation in marmatite flotation is a big problem. This paper innovatively studies how to reduce these two negative phenomena from the perspective of grinding media. The effects of steel and stainless-steel balls on the flotation performance of copper-activated marmatite were investigated mainly through flotation tests, redox potential measurements, ion concentration tests, and XPS and FT-IR spectrum studies. The flotation results showed that the floatability of copper-activated marmatite remarkably decreased by using the steel ball in the grinding process, but it had a mere influence when stainless-steel medium was used. Redox potential measurements showed that the grinding environment of stainless-steel medium could exhibit a higher oxidizing potential than the steel grinding environment. Results from FTIR, XPS, and ion concentration measurements demonstrated that more ferric ions existed on the copper activated marmatite surface in the steel grinding environment than that in the stainless-steel environment. Ferric ions could further hinder the activation effect of copper ions on marmatite and result in decreased marmatite flotation. This research could potentially explain the mechanism of ferric ions in the grinding process, and it can be utilized to improve the flotation performance of marmatite ore through selecting suitable grinding media in ball mill operations.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 2; 229-237
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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