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Wyszukujesz frazę "E41" wg kryterium: Temat


Tytuł:
A Novel Method for Manufacturing Polymer/Metal Hybrid Structures
Autorzy:
Altan, M.
Yavuz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1187217.pdf
Data publikacji:
2016-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
68.47.De
Opis:
In this study, a method for manufacturing polymer/metal hybrid structure is presented in which traditional plastic injection machine was converted to plastic injection forming (PIF). In this method, deforming of the metal and adhering the metal to the polymer is done in one step. In the experimental study, a special mold within rectangular cavity was used during PIF process. Aluminum plates of different thicknesses were used as the metal parts of the structure. The injected polymers were pure polystyrene and elastomer-added polystyrene. The deformability of the Al plates was examined under different injection pressures. In order to provide adhesion between metal and polymer, an adhesive of elastomeric nature was applied on the metal plate prior to injection molding. Bending test was applied to determine the flexural strength and maximum deflection of the polymer/metal hybrid structures. The obtained results were satisfactorily acceptable in improving the method for designing and manufacturing polymer/metal hybrid structures in one step.
Źródło:
Acta Physica Polonica A; 2016, 129, 4; 639-641
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Temperature and Pressure Dependence of the Free Volume in Fluoroelastomers from PALS and PVT Experiments
Autorzy:
Dlubek, G.
Sen Gupta, A.
Wawryszczuk, J.
Kilburn, D.
Pionteck, J.
Krause-Rehberg, R.
Goworek, T.
Alam, M. A.
Kaspar, H.
Lochhaas, K. H.
Powiązania:
https://bibliotekanauki.pl/articles/2042202.pdf
Data publikacji:
2005-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
78.70.-g
Opis:
Positron lifetime and pressure-volume-temperature experiments were performed as function of T (100-485 K) and P (10$\text{}^{-5}$ Pa-500 MPa) on a fluoroelastomer. From positron annihilation lifetime spectroscopy, analyzed with LT9.0 assuming a dispersion in the e$\text{}^{+}$ (τ$\text{}_{2}$) and o-Ps (τ$\text{}_{3}$) lifetime, the mean, 〈v$\text{}_{h}$〉, and the width (standard deviation), σ$\text{}_{h}$, of the hole size distribution were calculated. The pressure-volume-temperature data were analyzed using the Simha-Somcynsky hole-lattice theory to estimate the specific hole free volume V$\text{}_{f}$. From a comparison of V$\text{}_{f}$ with 〈v$\text{}_{h}$〉 the specific hole number, N'$\text{}_{h}$, is estimated. The data from thermal expansion and pressure experiments show complete agreement when taking into account the compressibility of the occupied volume.
Źródło:
Acta Physica Polonica A; 2005, 107, 4; 685-689
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Homonuclear Separated Local-Field Spectroscopy by Magnetization-Exchange NMR
Autorzy:
Demco, D.
Filip, X.
Filip, C.
Chira, D.
Cozar, O.
Powiązania:
https://bibliotekanauki.pl/articles/1968466.pdf
Data publikacji:
1997-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.25.+k
61.41.+e
Opis:
The possibility to perform homonuclear separated-local field NMR spectroscopy by magnetization-exchange is presented. Solid-state one-dimensional proton magnetization-exchange NMR is used to investigate intergroup residual dipolar couplings in cis-1,4-polybutadiene elastomer. A three-spin model is employed, in which the CH- and CH$\text{}_{2}$-protons are considered to be coupled by residual dipolar interactions. The magnetization-exchange process between the CH- and the CH$\text{}_{2}$-group in the regime of short mixing time provides valuable insight regarding molecular order. The spin-system response reflects well-localized dipolar interactions. The residual intergroup dipolar couplings are measured along the average polymer-chain direction for different temperatures. The dynamic order parameter along the chains is also evaluated.
Źródło:
Acta Physica Polonica A; 1997, 92, 6; 1135-1149
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Simplified Method for the Estimation of Hole Free Volume Fraction from the Specific Volume
Autorzy:
Dlubek, G.
Pionteck, J.
Powiązania:
https://bibliotekanauki.pl/articles/1812487.pdf
Data publikacji:
2008-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
78.70.-g
Opis:
A brief introduction in the equation of state of the Simha-Somcynsky hole theory is presented. This theory allows to calculate the volume fraction h of free volume holes from pressure-volume-temperature experiments. These holes are detected by ortho-positronium and from the value of h and the mean ortho-positronium hole size the hole density may be calculated. We discuss a simplified method to estimate h which makes use of the relation V* = 1.52 $V_W$ between the scaling volume V* of the Simha-Somcynsky hole theory equation of state and the van der Waals volume $V_W$. Moreover, we present a new simplified method for the estimation of h which starts with the Schottky (Arrhenius) equation for the concentration of thermal vacancies and makes use of a linear relation between the scaling temperature T* and the hole formation enthalpy $H_h$, $H_h$(kJ/mol)=6.54×$10^{-4}$T*(K).
Źródło:
Acta Physica Polonica A; 2008, 113, 5; 1331-1338
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free-Volume and Tensile Properties of Glass Fibre Reinforced Polyamide 6 Composites
Autorzy:
Dryzek, E.
Wróbel, M.
Juszyńska-Gałązka, E.
Powiązania:
https://bibliotekanauki.pl/articles/1033894.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.41.+e
Opis:
The tensile properties and free volume of commercially available modified polyamid 6 and polyamid 6 composites with 15 and 30 wt% of glass fibre were the subject of the studies. The tensile test allowed us to obtain the stress-strain curves and determine the tensile properties of the polyamid 6 samples. The positron lifetime measurements were performed for the samples before the test and for the samples in the vicinity of the break after they failed. The composites exhibited slightly lower values of the ortho-positronium lifetime and therefore smaller size of the local free volumes in comparison to polyamid 6 without reinforcement. The analysis of the positron lifetime spectra indicated size distribution of the free volume. The initially narrower distributions for the composite samples became broader as a result of the deformation. The deformation caused also increase of the ortho-positronium intensity in the obtained positron lifetime spectra.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1501-1505
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Positron Annihilation Lifetime Spectroscopy of ABS Objects Manufactured by Fused Deposition Modelling
Autorzy:
Dryzek, M.
Dryzek, E.
Powiązania:
https://bibliotekanauki.pl/articles/1033901.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.41.+e
Opis:
Positron annihilation lifetime spectroscopy was used to study acrylonitrile butadiene styrene (ABS) specimens manufactured using fused deposition modelling to explore possibilities of identifying differences in molecular structure. The set of specimens was prepared including square tiles and long rectangular tiles (100 mm and 200 mm long) with all filament roads parallel to the longer edge. All types of tiles were produced with various infill line distance parameter resulting in different overlapping of the roads in horizontal and vertical directions. The slight increase of the ortho-positronium lifetime indicating increase of the mean free volume radius was observed for the longest tiles for which influence of weld interface is expected to be most pronounced. No differences were observed for different infill line distance parameters.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1506-1508
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Role of Ferric(III) Oxide in Poly-(1,4-Phenylene Sulphide) Curing. EPR and X-ray Studies
Autorzy:
Wejchan-Judek, M.
Hoffmann, S. K.
Goslar, J.
Garbarczyk, J.
Powiązania:
https://bibliotekanauki.pl/articles/2043404.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
61.41.+e
Opis:
Commercially available poly-(1,4-phenylene sulfide) = PPS with trade names TEDUR and RYTON contain a great amount of Fe(III) (order of 10$\text{}^{20}$ Fe/gram) as shown by electron spin resonance spectra. The curing of the pure and Fe-doped (0.2% Fe$\text{}_{2}$O$\text{}_{3}$) PPS polymers proves that Fe(III) can be used for improvement of the PPS strength by increasing the polymer cross-linking and a decrease in the polymer crystallinity degree as shown by X-ray diffraction.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 107-112
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optical Order Parameter of Dichroic Azo-Dyes in Liquid Crystalline Side-Chain Polysiloxanes
Autorzy:
Chrzumnicka, E.
Bauman, D.
Jadżyn, J.
Powiązania:
https://bibliotekanauki.pl/articles/2035645.pdf
Data publikacji:
2002-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
61.30.Gd
64.70.Md
Opis:
Polarized light absorption spectra of seven dichroic azo-dyes dissolved in mesogenic side-chain polysiloxanes were recorded as a function of temperature. On the basis of the spectra the optical order parameter of the dyes was determined. The influence of the dye on the phase transition temperatures of polysiloxanes was examined. The results obtained for polysiloxanes were compared with the data for low molecular weight liquid crystal.
Źródło:
Acta Physica Polonica A; 2002, 102, 6; 767-780
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Spin-Lattice Relaxation in Polymers and Crystals Related to Disorder and Structure Defects
Autorzy:
Hoffmann, S. K.
Hilczer, W.
Radczyk, T.
Polus, I.
Powiązania:
https://bibliotekanauki.pl/articles/2035737.pdf
Data publikacji:
2003-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
61.80.-x
76.30.-v
Opis:
Temperature dependences (4-300 K) of the electron spin-lattice relaxation have been determined by electron spin echo technique for free radicals in two polymeric systems: phenol-formaldehyde resin and polyhydrazodisulphide. The dependences are described in terms of dynamics specific for amorphous systems involving two-level tunnelling states at low temperatures, exchange-coupled clusters of paramagnetic centres and local oscillators. Some universal temperature behaviour of the spin-lattice relaxation of amorphous systems is suggested, with a strong increase in relaxation rate with temperature at low temperatures and much weaker increase above 50 K with characteristic linear temperature dependence in a broad temperature range and cosech(Δ/kT) -type behaviour. It is also shown that the amorphous-type behaviour appears in low temperatures relaxation studies of single crystals but it is due to a non-uniform distribution of doped paramagnetic ions. Such behaviour we have found in Tutton salt crystals doped with Cu$\text{}^{2+}$, as well as for free radical centres produced by ionising irradiation in (NH$\text{}_{4}$)$\text{}_{3}$H(SeO$\text{}_{4}$)$\text{}_{2}$ and Li(N$\text{}_{2}$H$\text{}_{5}$)SO$\text{}_{4}$ single crystals, where extended phonons are suppressed around radiation damage centres suggesting a local amorphisation of the crystal structure.zapisz i p
Źródło:
Acta Physica Polonica A; 2003, 103, 4; 373-385
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Relations Between Hole Volume and Macroscopic Volume in Various Polymers
Autorzy:
Dlubek, G.
Alam, M. A.
Saarinen, K.
Stejny, J.
Fretwell, H. M.
Powiązania:
https://bibliotekanauki.pl/articles/2007964.pdf
Data publikacji:
1999-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
65.70.+y
78.70.-g
Opis:
Different definitions of the free volumes are discussed and related to the total specific volume and to the local free (hole) volume. Positron lifetime measurements are reported for polyethylene, polytetrafluoroethylene, and CR39-copolymers. Two long-lived components appear in polyethylene and polytetrafluoroethylene, which were attributed to o-Ps annihilations in crystalline regions and in holes of the amorphous phase. From a relation between the coefficients of the thermal expansion of macroscopic and hole volume, the fractional hole volume h and from this the number of holes, N, is estimated. Values of T$\text{}_{g}$=195 K, h$\text{}_{g}$=4.5% (polyethylene) and 5.7% (polytetrafluoroethylene) and N$\text{}_{g}$=0.73 nm$\text{}^{-3}$ (polyethylene) and 0.36 nm$\text{}^{-3}$ (polytetrafluoroethylene) were obtained. In semicrystalline polymers these values agree with estimates obtained from the densities of the crystalline and amorphous phases. The effect of cross-linking on the free-volume properties of CR39-copolymer networks was studied. The comparison of the hole volume with the specific volume allowed us to estimate the number density of holes to ≈1 nm$\text{}^{-3}$.
Źródło:
Acta Physica Polonica A; 1999, 95, 4; 521-526
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Terpolymer Addition on the Thermal and Termomechanical Properties of Poly(Phenylene Sulfide)
Autorzy:
Cetin, B.
Sahin, A.
Yilmaz, T.
Sinmazcelik, T.
Curgul, I.
Powiązania:
https://bibliotekanauki.pl/articles/1033681.pdf
Data publikacji:
2017-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.70.Pg
83.85.Vb
61.41.+e
Opis:
Poly(phenylene sulfide) (PPS) is one of the high-performance engineering polymers and it exhibits superior behavior, such as electrical insulation, dimensional and thermal stability, chemical resistance for various industrial applications. In addition to this, PPS has a high degree of crystallinity and it maintains these properties at high temperatures. These advantageous properties of PPS can be dependent on its chemical structure, composed of phenyl groups linked by a sulfur atom, which gives rigidity to the polymer chains. Owing to these properties, PPS is widely used in electrical and electronic components, automobile industry and mechanical applications. On the other hand, brittleness of PPS restricts its further applications. For this reason, ethylene-acrylic ester-glycidyl methacrylate terpolymer (Lotader®-AX8900) was used to overcome the brittleness of PPS. The effects of terpolymer addition on the thermal and thermomechanical properties of blends were investigated in this study. PPS/Lotader (0, 2, 5, 10 wt.% Lotader®) blends of various compositions were prepared. The blends were prepared by using laboratory scale micro compounder and injection molding machine. Thermomechanical and thermal properties of blends were investigated by means of dynamic mechanic analysis and differential scanning calorimeter test methods. As a result of this study, it was found that increasing loading level of Lotader® significantly decreased the crystallinity and increased glass transition temperature of PPS. On the other hand, Lotader® addition did not affect the melting temperature of PPS considerably. Results of dynamic mechanic analysis test revealed that while damping factor peak and loss modulus values of blends increased with the addition of Lotader®, storage modulus of blends decreased with the increasing loading level of Lotader®. When all test results are considered, it can be concluded that Lotader addition changes the brittle nature of PPS to ductile nature. In addition to this, 2 wt.% Lotader addition to PPS enables the optimum ductility for PPS without deteriorating its other properties.
Źródło:
Acta Physica Polonica A; 2017, 131, 3; 598-600
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of the Crash Boxes Light Weighting with Syntactic Foams by the Finite Element Analysis
Autorzy:
Özer, H.
Can, Y.
Yazıcı, M.
Powiązania:
https://bibliotekanauki.pl/articles/1031574.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.70.Dh
62.20.-x
61.41.+e
Opis:
Light-weighting is a new scope in the automotive industry to accommodate new emission regulations. The parts produced with conventional metallic materials are replaced with parts produced by using light weight or high strength materials, to obtain light weighted equivalents of the same strength. Foam core sandwich structures, high strength steels, composite materials are the most used alternative materials. Syntactic foams that show outstanding performance in case of high-speed collisions have an excellent utility as energy absorbers in vehicle crash boxes. Syntactic foams are modeled in crash boxes at various filling rates and filling patterns in the context of this study. As results of the FEM analyses, it is observed that syntactic foams have excellent crash performance, as well as weight-reducing effect in vehicle crash boxes.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 734-737
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
How Random Is a Random Polymer Coil?
Autorzy:
Zając, W.
Powiązania:
https://bibliotekanauki.pl/articles/1490102.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
61.43.-j
61.05.fg
Opis:
Short range order within amorphous, random polymer structures is a well known and widely studied property of disordered systems. An aggregate of five random atactic chains, each comprising 400 building units was computer-generated and then used to calculate neutron coherent scattering intensity for 0.01 < Q < 30 $nm^{-1}$ (0.001 < Q < 3 $Å^{-1}$). The latter was compared with experimental data within the diffuse scattering range. On the grounds of quantum chemical calculations for an atactic polystyrene tetramer and the above information it is concluded that interactions among phenyl rings are responsible for the onset of the local order in this polymer.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 464-467
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Dynamics Simulations of Poly(dimethylsiloxane) Properties
Autorzy:
Fojtíková, J.
Kalvoda, L.
Sedlák, P.
Powiązania:
https://bibliotekanauki.pl/articles/1402106.pdf
Data publikacji:
2015-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
31.15.xv
61.41.+e
81.05.Lg
Opis:
Models of poly(dimethylsiloxane) (PDMS) oligomers differing in topology are defined and structure and mechanical properties of these analysed by three different theoretical approaches: the Bicerano graph method, atomistic molecular dynamics simulations and mesoscale dissipative particle dynamics. The calculations are performed within the simulation software environment Materials Studio (Accelrys Software Inc.). The obtained values of the Young and bulk modulus are juxtaposed to experimental data available for real PDMS materials and quality of the agreement discussed in relation to the theory level and simulation method applied.
Źródło:
Acta Physica Polonica A; 2015, 128, 4; 637-639
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Outdoor Ageing of an Ethylene-Propylene Copolymer: A Positron Annihilation Study
Autorzy:
Consolati, G.
Quasso, F.
Gallo, R.
Severini, F.
Powiązania:
https://bibliotekanauki.pl/articles/2043322.pdf
Data publikacji:
2005-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
78.70.Bj
81.05.Lg
Opis:
An investigation on the environmental degradation of an ethylene-propylene copolymer was carried out through positron annihilation lifetime spectroscopy, density and differential scanning calorimetry measurements. Polymer sheets were exposed to sunlight up to 11000 hours. Density and melting enthalpy increase with ageing, while ortho-positronium intensity decreases; ortho-positronium lifetime does not show significant variations up to 4400 hours. At higher exposures it starts to decrease. Outdoor ageing produces an increased crystallinity of the copolymer; also a degradation occurs with formation of carbonyl groups. The corresponding Ps inhibition is the main reason for the decrease in ortho-positronium intensity, the other one being the reduced amount of the amorphous phase available. The lifetime decrease observed at the highest exposures can be interpreted in terms of a shrinking of the nanoholes trapping positronium.
Źródło:
Acta Physica Polonica A; 2005, 107, 5; 805-810
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł

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