- Tytuł:
-
Metody badań niejednorodności energetycznej powierzchni katalizatorów i adsorbentów
Methods of investigation energetical heterogeneity on the surface of catalysts and adsorbents - Autorzy:
- Woszczyński, P.
- Powiązania:
- https://bibliotekanauki.pl/articles/172199.pdf
- Data publikacji:
- 2013
- Wydawca:
- Polskie Towarzystwo Chemiczne
- Tematy:
-
heterogeniczność
niejednorodność energetyczna
równanie Fredholma
adsorpcja
kalorymetria
chromatografia
odwrócona chromatografia gazowa
chromatografia z odwróconym przepływem
programowana termiczna desorpcja
heterogeneity
adsorbent
catalyst
Fredholm equation
adsorption
calorimetry
chromatography
inverse gas chromatography (IGC)
IGC
reverse-flow IGC (RF-IGC )
programmed thermal desorption (TPD)
TPD - Opis:
- The knowledge of the properties and a surface structure of catalysts and adsorbents is of great importance in the selection of these materials to the relevant objectives. Interesting structural information can be obtained in many ways, for example: with the use of spectroscopic or microscopic techniques or in direct examination of the adsorption isotherms. This article focuses on these last-mentioned methods, which can be a source of information on energy heterogeneity of the catalyst or adsorbent surface. Heterogeneity is usually determined by measuring adsorption isotherms of a selected adsorbate on the examined adsorbent, which is dependent of adsorbate coverage on the adsorbent relative to the equilibrium pressure under isothermal conditions. Among the many mathematical models describing this relationship particularly interesting is the adsorption isotherm model described by generalized integral Fredholm equation. The solution of this equation is density function with the assumed local isotherm model. There are different ways to solve the Fredholm equation, depending on measurement methods of obtained adsorption isotherms. For example, an application of static techniques (gravimetric or volumetric) needs to use advanced, sophisticated numerical methods for directly solving integral equations, other techniques (e.g. such as calorimetric or chromatographic) provide specific values that simplify these calculations. The resulting energy density function allows to observe active centers as peaks or inflections of the curve on the energy spectrum graph.
- Źródło:
-
Wiadomości Chemiczne; 2013, 67, 7-8; 635-664
0043-5104
2300-0295 - Pojawia się w:
- Wiadomości Chemiczne
- Dostawca treści:
- Biblioteka Nauki
Artykuł