- Tytuł:
-
Molekularne materiały magnetyczne
Molecular magnetic materials - Autorzy:
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Löffler, M.
Gałkowska, A.
Korabik, M.
Utko, J.
Lis, T. - Powiązania:
- https://bibliotekanauki.pl/articles/172078.pdf
- Data publikacji:
- 2018
- Wydawca:
- Polskie Towarzystwo Chemiczne
- Tematy:
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magnetyzm
struktura krystaliczna
magnesy molekularne
SMMs
SIM
frustracja spinowa
magnetism
crystal structure
molecular magnets
spin frustration - Opis:
- The „molecular” term appears more and more often in the materials chemistry. The Nobel Prize in 2016 was awarded to Jean-Pierre Sauvage, Sir J. Fraser Stoddart and Bernard R. Feringa „for the design and synthesis of molecular machines”. Magnetism in molecular scale, also known as molecular nanomagnetism, has been developing intensively since the second half of the last century. This branch of science involves the magnetic properties of coordination compounds of d- and f-electron metals. The paper presents results of the magnetic studies of molecular magnets of copper(II) and dysprosium(III), which have been pursuing in two doctoral thesis. The compounds form trinuclear and triangular molecules. The spin frustration phenomenon observed in the triangular relationship of copper(II) has been described. Since dysprosium(III) ion is characterized by a large magnetic anisotropy, the triangular, trinuclear coordination compound of dysprosium(III) of the formula [Dy3L5HLCl4]∙HL (where HL = 2-methoxyethanol) presents the characteristic properties of molecular magnets (SMMs) behavior. Two values of the energy barier were determined as Ueff/kB = 84,6 K and 31,2 K with the corresponding relaxation times τ0 = 1,82·10-6 s and 5,19·10-5 s. The data are probably attributed to different geometry of the coupled dysprosium ions.
- Źródło:
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Wiadomości Chemiczne; 2018, 72, 7-8; 523-541
0043-5104
2300-0295 - Pojawia się w:
- Wiadomości Chemiczne
- Dostawca treści:
- Biblioteka Nauki
Artykuł