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Wyszukujesz frazę "Baláž, M." wg kryterium: Autor


Wyświetlanie 1-5 z 5
Tytuł:
Kinetics of Solid-State Synthesis of Quaternary Cu₂FeSnS₄ (Stannite) Nanocrystals for Solar Energy Applications
Autorzy:
Baláž, P.
Baláž, M.
Zorkovská, A.
Škorvánek, I.
Bujňáková, Z.
Trajić, J.
Powiązania:
https://bibliotekanauki.pl/articles/1032135.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Pp
81.05.Hd
61.46.Hk
Opis:
In this study we demonstrate the use of elemental precursors (Cu, Fe, Sn, S) to obtain stannite forms by a solid-state one-pot mechanochemical synthesis. In the processing route, we report the kinetics of the synthesis. For the characterization of the unique nanostructures, X-ray diffraction, specific surface area measurements and SQUID magnetometry methods were applied. CFTS polymorphs with the tetragonal body-centered structure with the average crystallite size 18-19 nm were obtained. The weak ferromagnetic properties of the quaternary nanocrystals after maximum milling time were also documented.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1153-1155
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemical Dechlorination of PVC by Utilizing Eggshell Waste
Autorzy:
Baláž, M.
Baláž, P.
Bujňáková, Z.
Pap, Z.
Kupka, D.
Zorkovská, A.
Powiązania:
https://bibliotekanauki.pl/articles/1375093.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Lg
81.20.Wk
88.20.dr
Opis:
Within this work, the dechlorination of polyvinylchloride (PVC) chemical as a model by co-milling with eggshell was performed in a planetary ball mill in order to show that mechanochemistry can be utilized for the simultaneous treatment of two wastes, while the products of the treatment can be used in further applications. The products of the reaction are water-soluble calcium chloride ($CaCl_2$), which can be used e.g. for de-icing of roads in winter and organic residue on the basis of ethylene, which can be recovered as energy source. The highest dechlorination yield (almost 97%) was achieved under following milling conditions: molar ratio between Ca and Cl: 2.34, ball-to-powder ratio: 65, rotation speed of the planet carrier: 550 rpm, milling time: 4 h and material of milling media: tungsten carbide. The optimum conditions were then applied for the removal of chlorine from industrial waste - the abandoned PVC window parapet. In this case, 95% dechlorination was evidenced.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 884-887
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemical Reduction of Chalcopyrite CuFeS₂: Changes in Composition and Magnetic Properties
Autorzy:
Baláž, P.
Zorkovská, A.
Baláž, M.
Kováč, J.
Tešinský, M.
Osserov, T.
Guseynova, G.
Ketegenov, T.
Powiązania:
https://bibliotekanauki.pl/articles/1032642.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Pp
81.05.Hd
Opis:
High-energy milling of sulphides with a reactive metal in so-called mechanochemical reduction mode can lead to products in nanorange and to composition which simplifies the following metallurgical processing. Chalcopyrite CuFeS₂, a ternary semiconductor with antiferromagnetic properties represents promising candidate as an advanced material for use in inexpensive nanoelectronics (solar cells, magnetic area), as well as copper ore source in metallurgical operations. In this work, the process of mechanochemical reduction of chalcopyrite with elemental iron is studied. The composition and properties of nanopowder prepared by high-energy milling were analyzed by X-ray diffraction and magnetic measurements. Most of the reaction takes place during 30 min with chalcocite Cu₂S and troilite FeS as the only reaction products. The magnetic investigations reveal significant increase of saturation magnetization as a result of milling. Unlike the conventional high-temperature reduction of chalcopyrite, the mechanochemical reduction is fast and ambient temperature and atmospheric pressure are sufficient for its propagation.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1165-1167
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemically Synthesized CuFeSe₂ Nanoparticles and Their Properties
Autorzy:
Dutková, E.
Škorvánek, I.
Sayagués, M.
Zorkovská, A.
Kováč, J.
Baláž, P.
Powiązania:
https://bibliotekanauki.pl/articles/1032137.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Hd
81.07.Wx
81.20.Wk
Opis:
The mechanochemical synthesis of nanocrystalline CuFeSe₂ particles prepared by high-energy milling in a planetary mill in an argon atmosphere from copper, iron, and selenium for 60 min is reported for the first time. The CuFeSe₂ nanoparticles crystallize in tetragonal structure with mean crystallite size of about 32±1 nm. High resolution transmission electron microscopy measurements confirmed the presence of agglomerates which are formed by small nanocrystalline domains (5-40 nm). The magnetic data revealed that paramagnetic CuFeSe₂ nanoparticles coexist with a small amount of ferromagnetic impurities at room temperature. The magnetic transition towards a weak ferromagnetic or ferrimagnetic behavior occurs in CuFeSe₂ at approximately 79 K. The band gap of the CuFeSe₂ particles is 0.95 eV which is wider than the band gap in bulk materials (0.16 eV), which could be in many aspects of application more beneficial.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1156-1158
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemically Synthesized Nanocrystalline $Sb_2S_3$ Particles
Autorzy:
Dutková, E.
Sayagués, M.
Real, C.
Zorkovská, A.
Baláž, P.
Šatka, A.
Kováč, J.
Ficeriová, J.
Powiązania:
https://bibliotekanauki.pl/articles/1375343.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Hd
81.07.Bc
81.20.Wk
Opis:
Nanocrystalline $Sb_2S_3$ particles have been synthesized from Sb and S powders by high-energy milling in a planetary mill using argon protective atmosphere. X-ray diffraction, particle size analysis, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, electron diffraction, high resolution transmission electron microscopy, UV-VIS, and differential scanning calorimetry methods for characterization of the prepared particles were applied. The powder X-ray diffraction pattern shows that $Sb_2S_3$ nanocrystals belong to the orthorhombic phase with calculated crystallite size of about 36 nm. The nanocrystalline $Sb_2S_3$ particles are constituted by randomly distributed crystalline nanodomains (20 nm) and then these particles are forming aggregates. The monomodal distribution of $Sb_2S_3$ particles with the average hydrodynamic parameter 210 nm was obtained. The quantification of energy dispersive X-ray spectroscopy analysis peaks give an atomic ratio of 2:3 for Sb:S. The optical band gap determined from the absorption spectrum is 4.9 eV, indicating a considerable blue shift relative to the bulk $Sb_2S_3$. Differential scanning calorimetry curves exhibit a broad exothermic peak between 200 and 300°C, suggesting recovery processes. This interpretation is supported by X-ray diffraction measurements that indicate a 23-fold increase of the crystallite size to about 827 nm as a consequence of application of high temperature process. The controlled mechanochemical synthesis of $Sb_2S_3$ nanoparticles at ambient temperature and atmospheric pressure remains a great challenge.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 943-946
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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