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Wyświetlanie 1-9 z 9
Tytuł:
Radiation processing of polymers and semiconductors at the Institute of Nuclear Chemistry and Technology
Autorzy:
Zimek, Z.
Przybytniak, G.
Kałuska, I.
Powiązania:
https://bibliotekanauki.pl/articles/146107.pdf
Data publikacji:
2006
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
electron beam accelerators
radiation processing
Opis:
R&D studies in the field of radiation technology in Poland are mostly concentrated at the Institute of Nuclear Chemistry and Technology (INCT). The results of the INCT works on polymer and semiconductor modification have been implemented in various branches of national economy, particularly in industry and medicine. Radiation technology for polymer modification was implemented in the middle of the 1970-ties. Among others, the processes of irradiation and heat shrinkable products expansion have been developed. The transfer of this technology to Polish industry was performed in the middle of the 1980-ties. The present study aims at the formulation of new PE composites better suited to new generation of heat shrinkable products, for example, a new generation of hot-melt adhesives has been developed to meet specific requirements of customers. Modified polypropylene was used for the production of medical devices sterilized by radiation, especially disposable syringes, to overcome the low radiation resistance of the basic material. Modified polypropylene (PP-M) has been formulated at the INCT to provide material suitable for medical application and radiation sterilization process. Modification of semiconductor devices by EB was applied on an industrial scale since 1978 when the INCT and the LAMINA semiconductor factory successfully adopted that technology to improve specific semiconductor devices. This activity is continued on commercial basis where the INCT facilities served to contract irradiation of certain semiconductor devices according to the manufacturing program of the Polish factory and customers from abroad.
Źródło:
Nukleonika; 2006, 51,suppl.1; 129-132
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical study of dose and dose rate effect on trichloroethylene (HClC=CCl2) decomposition in dry and humid air under electron beam irradiation
Autorzy:
Nichipor, H.
Yacko, S.
Sun, Y.
Chmielewski, A. G.
Zimek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/146819.pdf
Data publikacji:
2008
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
trichloroethylene
electron beam decomposition
computer simulation
Opis:
Experimental data related to C2HCl3 (TCE) removal in dry and humid (200-1000 ppm of H2O) air, respectively, in ambient conditions under electron beam irradiation in the dose range of 1-40 kGy has been published in the literature. Based on the experimental results a theoretical model of C2HCl3 decomposition was proposed for the kinetic mechanism of such process. The active radicals of Cl, O and OH play an important role in the decomposition of TCE. According to the calculations performed, the Cl- dissociative electron attachment predominates in the initial stage of C2HCl3 decomposition. Cl radical accelerates this degradation by chain process in both humid and dry air, respectively. The OH radical produced in humid air also enhances the decomposition process of TCE.
Źródło:
Nukleonika; 2008, 53, 1; 11-16
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Decomposition of toluene in air mixtures under electron beam irradiation
Autorzy:
Sun, Y.
Chmielewski, A. G.
Bułka, S.
Zimek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/148028.pdf
Data publikacji:
2009
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
toluene
4-chlorotoluene
decomposition
electron beam
Opis:
The model gases of toluene-air mixtures were prepared by blowing technical air into liquid toluene and then irradiated with an ILU-6 accelerator located at the Institute of Nuclear Chemistry and Technology (INCT), Poland. It was found that the decomposition efficiency of toluene increases with absorbed dose and decreases with initial concentration of toluene. At 14.5 kGy dose, the decomposition efficiencies of toluene were 50, 37 and 34.5% for the initial concentrations of toluene 32.0, 63.4 and 78.0 ppm, respectively. At 58.0 kGy dose, the decomposition efficiencies of toluene were 93.8 and 78.1%, the initial concentrations of toluene being 32.0 and 63.4 ppm, respectively. Benzaldehyde was identified as one of the by-products of toluene decomposition in an air mixture. The decomposition efficiency and by-product formation under EB irradiation were compared between toluene and 4-chlorotoluene.
Źródło:
Nukleonika; 2009, 54, 2; 65-70
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of hindered amine light stabilizers on the resistance of polypropylene towards ionizing radiation
Autorzy:
Przybytniak, G.
Mirkowski, K.
Rafalski, A.
Nowicki, A.
Legocka, I.
Zimek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/148686.pdf
Data publikacji:
2005
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
polypropylene
stabilizers
HALS
electron beam
apparent viscosity
nucleation agent
Opis:
The influence of hindered amine light stabilizers (HALSs) on physical and mechanical properties of irradiated and non-irradiated isotactic polypropylene (PP) was studied. The stabilizers under investigation were: Tinuvin 765 (T765) and Tinuvin 622 (T622) - derivatives of 1,2,2,6,6-pentamethyl piperidine and Chimassorb 944 (C944) - a derivative of 2,2,6,6-tetramethyl piperidine. It was found that the stabilizers reduce the amount of peroxyl radicals in the amorphous phase of PP. The irradiation with electron beam causes a drop of apparent viscosity both in the original and in the modified PP however the effect is smaller in the presence of HALSs. Admixture of T622 and T765 stabilizers increases the crystallization temperature of non-irradiated PP by about 8 10°C (measured by DSC) what results from the facilitated formation of a large number small microcrystals. It was concluded that HALSs initiate two opposite tendencies - chemical protection against damage initiated by free radicals and, simultaneously, physical enhancement of sensitivity towards irradiation by the increase of nucleation density. In the studied systems, the presence of maleic anhydride does not improve compatibility between the polymeric matrix and HALSs.
Źródło:
Nukleonika; 2005, 50, 4; 153-159
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of boundary effects on electron beam dose distribution formation in multilayer targets
Autorzy:
Kałuska, I.
Lazurik, V. T.
Lazurik, V. M.
Popov, G. F.
Rogov, Y. V.
Zimek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/148556.pdf
Data publikacji:
2010
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
absorbed dose
electron beam
simulation
Monte Carlo
software ModeStEB
dosimetry
Opis:
Computational dosimetry play a significant role in an industrial radiation processing at dose measurements in the product irradiated with electron beams (EB), X-ray and gamma ray from radionuclide sources. Accurate and validated programs for absorbed dose calculations are required for computational dosimetry. The program ModeStEB (modelling of EB processing in a three-dimensional (3D) multilayer flat targets) was designed specially for simulation and optimization of industrial radiation processing, calculation of the 3D absorbed dose distribution within multilayer packages. The package is irradiated with scanned EB on an industrial radiation facility that is based on the pulsed or continuous type of electron accelerators in the electron energy range from 0.1 to 25 MeV. Simulation of EB dose distributions in the multilayer targets was accomplished using the Monte Carlo (MC) method. Experimental verification of MC simulation prediction for EB dose distribution formation in a stack of plates interleaved with polyvinylchloride (PVC) dosimetric films (DF), within a packing box, and irradiated with a scanned 10 MeV EB on a moving conveyer is discussed.
Źródło:
Nukleonika; 2010, 55, 3; 363-368
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simulation of decomposition of dichloroethylenes (trans-DCE, cis-DCE, 1,1-DCE)/air under electron beam irradiation
Autorzy:
Sun, Y.
Chmielewski, G.
Bułka, S.
Zimek, Z.
Nichipor, H.
Powiązania:
https://bibliotekanauki.pl/articles/146568.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
trans-dichloroethylene
cis-dichloroethylene
1,1-dichloroethylene
electron beam
decomposition
mechanism
Opis:
On the basis of the experimental results, computer simulations of decomposition of dichloroethylenes for three isomers (trans-DCE, cis-DCE, 1,1-DCE) in air under electron beam were carried out. Computer code “Kinetic” and “Gear” method were used. Calculation results well agree with the experimental results. Decomposition efficiency of DCE is mainly determined by Cl- dissociated secondary electron attachment, followed by Cl radical addition reaction with DCE.
Źródło:
Nukleonika; 2007, 52, 2; 59-67
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The kinetics of 1,1-dichloroethene (CCl2=CH2) and trichloroethene (HClC=CCl2) decomposition in dry and humid air under the influence of electron beam
Autorzy:
Nichipor, H.
Dashouk, E.
Yacko, S.
Chmielewski, A.
Zimek, Z.
Sun, Y.
Vitale, S.
Powiązania:
https://bibliotekanauki.pl/articles/148600.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
1,1-dichloroethene
trichloroethene
electron beam decomposition
theoretical model
kinetics calculation
Opis:
New experimental data related to the removal of C2H2Cl2 and C2HCl3 in dry and humid (300 ppm of H2O) air at atmospheric pressure and a temperature of 25°C under the influence of electron beam in the dose range 1 < D < 100 kGy are published. Taking into account these experimental data, theoretical models of the decomposition of both compounds and computer simulations were performed by the present authors to find the kinetics of such processes. The influence of active atoms Cl, O and OH radicals on the VOC degradation process has been established. The theoretical model of C2H2Cl2 degradation under the influence of electron beam in dry and humid air describes the C2H2Cl2 decay and formation of the main products like Cl2, COCl2, CO, CO2, HCl, HCOCl and C2H2Cl2O. The results of calculation of the kinetics of C2H2Cl2 decomposition were compared with data obtained experimentally for the C2H2Cl2 concentration range 321-2213 ppm. It was established that the relation between the rate constants of intermediate product decomposition: C2H2Cl3O Ţ C2H2Cl2O + Cl; (k1) C2H2Cl3O Ţ COCl2 + CH2C2; (k2) should be k1/k2 = 40. The theoretical model of C2HCl3 degradation under the influence of electron beam in dry and humid air describes the C2HCl3 decay and formation of the main products like Cl2, COCl2, CO, CO2, HCl, HCOCl and C2HCl3O. A detailed comparison of experimental and theoretical data for the C2HCl3 concentration 108-3206 ppm shows that the relation between the rate constants of intermediate product decomposition: C2HCl4O Ţ C2HCl3O + Cl; (k3) C2HCl4O Ţ COCl2 + CHCl2; (k4) should be k3/k4 =10. It was also found that O2+ ions have been formed in a gas mixture as a result of charge transfer process from N2+ ions, partly in excited form, which may lead to charge transfer to C2HCl3 and degradation of those particles. According to performed calculation, it can be stated that in humid air (300 ppm of H2O) VOC degradation is occurring mainly due to a chain reaction stimulated by Cl atoms, but also OH radicals are playing an important role. In the described gas mixture, the OH radicals are formed in the following reactions: O2+) + H2O + M Ţ (O2+)H2O + M O2+ (H2O) + H2O Ţ O2 + (H3O+)OH (H3O+)OH + H2O Ţ H3O+ + OH + H2O VOC degradation process under the influence of electron beam is more effective in humid air than in dry air for the same initial VOC concentration level. This conclusion is also supported by experimental data. --------------------------------------------------------------------------------
Źródło:
Nukleonika; 2003, 48, 1; 45-50
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron beam treatment of simulated marine diesel exhaust gases
Autorzy:
Licki, J.
Pawelec, A.
Zimek, Z.
Witman-Zając, S.
Powiązania:
https://bibliotekanauki.pl/articles/148426.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
electron accelerator
electron beam treatment
free radicals
marine diesel exhaust gases
NOx removal
seawater scrubber
Opis:
The exhaust gases from marine diesel engines contain high SO2 and NOx concentration. The applicability of the electron beam flue gas treatment technology for purification of marine diesel exhaust gases containing high SO2 and NOx concentration gases was the main goal of this paper. The study was performed in the laboratory plant with NOx concentration up to 1700 ppmv and SO2 concentration up to 1000 ppmv. Such high NOx and SO2 concentrations were observed in the exhaust gases from marine high-power diesel engines fuelled with different heavy fuel oils. In the first part of study the simulated exhaust gases were irradiated by the electron beam from accelerator. The simultaneous removal of SO2 and NOx were obtained and their removal efficiencies strongly depend on irradiation dose and inlet NOx concentration. For NOx concentrations above 800 ppmv low removal efficiencies were obtained even if applied high doses. In the second part of study the irradiated gases were directed to the seawater scrubber for further purification. The scrubbing process enhances removal efficiencies of both pollutants. The SO2 removal efficiencies above 98.5% were obtained with irradiation dose greater than 5.3 kGy. For inlet NOx concentrations of 1700 ppmv the NOx removal efficiency about 51% was obtained with dose greater than 8.8 kGy. Methods for further increase of NOx removal efficiency are presented in the paper.
Źródło:
Nukleonika; 2015, 60, No. 3, part 2; 689-695
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A review on electron beam flue gas treatment (EBFGT) as a multicomponent air pollution control technology
Autorzy:
Basfar, A. A.
Fageeha, O. I.
Kunnummal, N.
Chmielewski, A. G.
Licki, J.
Pawelec, A.
Zimek, Z.
Warych, J.
Powiązania:
https://bibliotekanauki.pl/articles/148616.pdf
Data publikacji:
2010
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
fossil fuel combustion
heavy fuel oil
electron beam irradiation
plasma processes
flue gas treatment
SO2 removal
NOx removal
Źródło:
Nukleonika; 2010, 55, 3; 271-277
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-9 z 9

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