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Wyświetlanie 1-4 z 4
Tytuł:
Characteristics of Silver Nanoparticles in Different pH Values
Autorzy:
Mražíková, A.
Velgosová, O.
Kavuličová, J.
Matvija, M.
Čižmárová, E.
Willner, J.
Powiązania:
https://bibliotekanauki.pl/articles/355669.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Ag nanoparticles
particle size
stability
pH
Opis:
Stability of silver nanoparticles strongly influences the potential of their application. The literature shows wide possibilities of nanoparticles preparation, which has significantly impact on their properties. Therefore, the improvement of AgNPs preparation plays a key role in the case of their practical use. The pH values of the environment are one of the important factors, which directly influences stability of AgNPs. We present a comparing study of the silver nanoparticles prepared by „bottom-up“ methods over by chemical synthesis and biosynthesis using AgNO3 (0.29 mM) solution. For the biosynthesis of the silver nanoparticles, the green freshwater algae Parachlorella kessleri and Citrus limon extracts were used as reducing and stabilizing agents. Chemically synthesized AgNPs were performed using sodium citrate (0.5%) as a capping agent and 0.01% gelatine as a reducing agent. The formation and long term stability of those silver nanoparticles synthesized either biologically and chemically were clearly observed by solution colour changes and confirmed by UV-vis spectroscopy. The pH values of formed nanoparticle solutions were 3 and 5.8 for biosynthesized AgNPs using extract of Citrus limon and Parachlorella kessleri, respectively and 7.2 for chemically prepared AgNPs solution using citrate. The SEM as a surface imaging method was used for the characterization of nanoparticle shapes, size distribution and also for resolving different particle sizes. These micrographs confirmed the presence of dispersed and aggregated AgNPs with various shapes and sizes.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 993-998
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Possibilities of Metals Extracton From Spent Metallic Automotive Catalytic Converters by Using Biometallurgical Method
Możliwości wykorzystania metod biometalurgicznych do ekstrakcji metali ze zużytych metalowych katalizatorów samochodowych
Autorzy:
Willner, J.
Kaduková, J.
Fornalczyk, A.
Mrážiková, A.
Marcinčáková, R.
Velgosová, O.
Powiązania:
https://bibliotekanauki.pl/articles/354688.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spent catalytic converters
metallic carrier
biometallurgy
Acidithiobacillus bacteria
zużyte katalizatory
metalowe nośniki
biometalurgia
bakterie Acidithiobacillus
Opis:
he main task of automotive catalytic converters is reducing the amount of harmful components of exhaust gases. Metallic catalytic converters are an alternative to standard ceramic catalytic converters. Metallic carriers are usually made from FeCrAl steel, which is covered by a layer of Precious Group Metals (PGMs) acting as a catalyst. There are many methods used for recovery of platinum from ceramic carriers in the world, but the issue of platinum and other metals recovery from metallic carriers is poorly described. The article presents results of preliminary experiments of metals biooxidation (Fe, Cr and Al) from spent catalytic converters with metallic carrier, using bacteria of the Acidithiobacillus genus.
Głównym zadaniem katalizatorów samochodowych jest zmniejszenie ilości szkodliwych składników spalin. Katalizatory na nośniku metalowym są alternatywą dla standardowych katalizatorów na nośniku ceramicznym. Nośniki metalowe najczęściej wykonuje się ze stali FeCrAl, na którą nieniesiona jest warstwa platynowców, pełniących funkcje katalityczne. W pracy przedstawiono wyniki wstępnych prób bioutleniania metali ze zużytych katalizatorów na nośniku metalowym (Fe, Cr, Al.), z udziałem bakterii z rodzaju Acidithiobacillus.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 3A; 1877-1880
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Specific Conditions on Cu, Ni, Zn and Al Recovery from PCBS Waste Using Acidophilic Bacterial Strains
Autorzy:
Mrážiková, A.
Kaduková, J.
Marcinčáková, R.
Velgosová, O.
Willner, J.
Fornalczyk, A.
Saternus, M.
Powiązania:
https://bibliotekanauki.pl/articles/353402.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bioleaching
metals
electronic waste
PCBs
Opis:
The objective of this work was to evaluate the influence of static, stirring and shaking conditions on copper, zinc, nickel and aluminium dissolution from printed circuit boards (PCBs) using the mixed acidophilic bacterial culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans. The results revealed that static conditions were the most effective in zinc and aluminium dissolution. Zinc was removed almost completely under static conditions, whereas maximum of nickel dissolution was reached under the stirring conditions. The highest copper recovery (36%) was reached under stirring conditions. The shaking conditions appeared to be the least suitable. The relative importance of these systems for the bioleaching of copper and nickel decreased in the order: stirring, static conditions, shaking.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 261-264
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dissolution of Metal Supported Spent Auto Catalysts in Acids
Autorzy:
Fornalczyk, A.
Kraszewski, M.
Willner, J.
Kaduková, J.
Mrážiková, A.
Marcinčáková, R.
Velgosová, O.
Powiązania:
https://bibliotekanauki.pl/articles/353228.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
dissolution
metal supported auto catalysts
metal substrate
Opis:
Metal supported auto catalysts, have been used in sports and racing cars initially, but nowadays their application systematically increases. In Metal Substrate (supported) Converters (MSC), catalytic functions are performed by the Platinum Group Metals (PGM): Pt, Pd, Rh, similarly to the catalysts on ceramic carriers. The contents of these metals make that spent catalytic converters are valuable source of precious metals. All over the world there are many methods for the metals recovery from the ceramic carriers, however, the issue of platinum recovery from metal supported catalysts has not been studied sufficiently yet. The paper presents preliminary results of dissolution of spent automotive catalyst on a metal carrier by means of acids: H2SO4, HCl, HNO3, H3PO4. The main assumption of the research was the dissolution of base metals (Fe, Cr, Al) from metallic carrier of catalyst, avoiding dissolution of PGMs. Dissolution was the most effective when concentrated hydrochloric acid, and 2M sulfuric acid (VI) was used. It was observed that the dust, remaining after leaching, contained platinum in the level of 0.8% and 0.7%, respectively.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 233-236
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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