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    Wyświetlanie 1-10 z 10
    Tytuł:
    Hammett spectral LFER of some antioxidant substituted benzylidene hydrazines
    Autorzy:
    Thirunarayanan, G.
    Manikandan, V.
    Arulkumaran, R.
    Rajarajan, M.
    Sathiyendiran, V.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182556.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-(2
    5-dinitrophenyl)-2-(substituted benzylidene)hydrazines
    Hammett correlations
    IR spectra
    NMR spectra
    antioxidant activity
    hydroxy apatite
    Opis:
    About nine (E)-(2,5-dinitrophenyl)-2-(substituted benzylidene)hydrazines have been synthesized by hydroxy apatite catalyzed condensation of 2,4-dinitrophenyl hydrazine and substituted benzaldehydes under microwave irradiation conditions. The obtained yields of these hydrazines are more than 85%. The purities of synthesized hydrazines are examined by the analytical and spectroscopic data reported earlier. The infrared spectral C=N, NH frequencies (v, cm-1) and the NMR spectral chemical shifts of CH, NH protons and carbons are assigned and are correlated with Hammett substituent constants, F and R parameter using single and multi-regression analysis. From the results of statistical analysis the effects of substituent on the group frequencies have been discussed. The antioxidant activities of these synthesized hydrazines were measured using DPPH radical scavenging method. The hydroxy- and methoxy- substituted hydrazines shows significant antioxidant activity.
    Źródło:
    World Scientific News; 2017, 69; 201-219
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    FT-IR, 1H and 13C NMR QSAR and molecular docking study on some (E)-2-(2-((aryl)(phenyl)methylene) hydrazinyl)benzo[d]thiazoles
    Autorzy:
    Muthuvel, I.
    Thirunarayanan, G.
    Manikandan, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/1066169.pdf
    Data publikacji:
    2019
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d]thiazoles
    Docking analysis
    Hammett equation
    IR spectra
    NMR spectra
    QSAR study
    Schiff’s bases
    Opis:
    About six (E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d]thiazoles have been synthesized and characterized by literature data. The infra-red stretching frequencies (ν, cm-1) of NH, CN, C=C and the NMR chemical shifts (δ, ppm) of NH, C=N and ipso carbons were assigned. These spectroscopic data were correlated for studying the QSAR employing Hammett equation with various Hammett substituent constants, Swain-Lupton’s F and R parameters using single and multi-regression analysis. From the results of regression analysis, the QSAR will be predicted by means of effects of substituents on the spectroscopic data of the functional group frequencies. The molecular docking character was evaluated by Schrodinger program, probing analogue docking in Topoisomerase enzymes. The crystallographic enzyme ligand complex (PDB entry 3TTZ) was obtained from the RCSB Protein Data Bank.
    Źródło:
    World Scientific News; 2019, 131; 54-74
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, spectral correlation analysis and evaluation of antimicrobial activities of some (E)-1-(2,4-dimethylthiazol-5-yl)-3-phenylprop-2-en-1-ones
    Autorzy:
    Sathiyendiran, V.
    Balaji, S.
    Senbagam, R.
    Vijayakumar, R.
    Manikandan, V.
    Rajarajan, M.
    Muthuvel, I.
    Markandan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1031849.pdf
    Data publikacji:
    2020
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    4-dimethylthiazol enones
    Antimicrobial activities
    Crossed-Aldol condensation
    E-2
    IR and NMR spectra
    Spectral correlation analysis
    Substituent effects
    UV
    Opis:
    In this work, an attempt was made to synthesized (E)-1-(2,4-dimethylthiazol-5-yl)-3-phenylprop-2-en-1-one by cross-aldol condensation reaction of 5′-acetyl-2,4-dimethylthiazole with various substituted Benz aldehyde in the presence base (sodium hydroxide). The synthesized (E)-1-(2,4-dimethylthiazol-5-yl)-3-phenylprop-2-en-1-one derivative was characterized by physical constants, UV, FT-IR, 1H-NMR & 13C-NMR spectral data. All the observed spectral data of substituted (E)-1-(2,4-dimethylthiazol-5-yl)-3-phenylprop-2-en-1-one compounds have been correlated with Hammett substituent constants(σ, σ+, σI & σR) and F and R parameters using single and multi-linear regression analyses and studied for their anti-microbial activities and compared with the standard drugs (Ciprofloxacin). Some compound of the series exhibited promising anti-microbial activity compared to standard drugs (Ciprofloxacin).
    Źródło:
    World Scientific News; 2020, 141; 66-90
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines
    Autorzy:
    Arulkumaran, R.
    Manikandan, V.
    Christuraj, P.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182844.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (e)-1-benzylidene-2-(diphenylmethylene) hydrazine
    ir and nmr spectra
    hammett correlations
    Opis:
    About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.
    Źródło:
    World Scientific News; 2017, 62; 93-110
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, and spectral Hammett correlation analysis of some (E)-1-(5-chloro-2-hydroxyphenyl)-3-phenylprop-2-en-1-one compounds
    Autorzy:
    Balaji, S.
    Vijayakumar, R.
    Manikandan, V.
    Senbagam, R.
    Rajarajan, M.
    Vanangamudi, G.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1182925.pdf
    Data publikacji:
    2016
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (e)-5-chloro-2-hydroxyphenyl chalcones
    synthesis
    uv
    ir and nmr spectra
    hammett correlation analysis
    substituent effect
    Opis:
    A series of substituted of (E)-1-(5-chloro-2-hydroxyphenyl)-3-phenylprop-2-en-1-one compounds by cross-aldol condensation reaction of 5-chloro-2-hydroxy acetophenone with various substituted benzaldehyde in the presence sodium hydroxide (base). The synthesized substituted (E)-1-(5-chloro-2-hydroxyphenyl)-3-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. All the spectral data of substituted (E)-1-(5-chloro-2-hydroxyphenyl)-3-phenylprop-2-en-1-one compounds has been Hammett correlation with linear regression analyses.
    Źródło:
    World Scientific News; 2016, 49, 2; 144-161
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and spectral Hammett correlation analysis of some (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds
    Autorzy:
    Christuraj, P.
    Rajakumar, P. R.
    Geetha, C.
    Vanangamudi, G.
    Arulkumran, R.
    Manikandan, V.
    Sundararajan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1179576.pdf
    Data publikacji:
    2017
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-ones
    FT-IR and NMR spectra
    Hammett correlation analysis
    Substituent constants
    Substituent effects
    UV
    Opis:
    A series of substituted of (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds by cross-aldol condensation reaction of 5-bromothiophene-2-carbaldehyde with various substituted acetaldehyde in the presence sodium hydroxide (base). The synthesized substituted (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The group frequencies of infrared ʋ(cm-1) of CO s-cis and s-trans, CH in-plane and out of plane, CH=CH out of plane, >C=C< out of plane modes, NMR chemical shifts δ (ppm) of Hα, Hβ, CO, Cα and Cβ of these chalcones were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analyses.
    Źródło:
    World Scientific News; 2017, 74; 15-35
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Hammett spectral QSAR analysis of some (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
    Autorzy:
    Vijayakumar, S.
    Manikandan, V.
    Arulkumaran, R.
    Christuraj, P.
    Sundararajan, R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1076503.pdf
    Data publikacji:
    2019
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones
    IR
    NMR spectra
    QSAR study
    UV
    regression analysis
    Opis:
    About nine substituted (E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-ones have been synthesized by solvent-free method. These enones were analyzed by spectral techniques. The characteristic spectral frequencies were correlated through Hammett equation with Hammett substituent constants, F and R parameters using single and multi-regression analysis method. From the statistical analysis results, the quantitative structure activity relationships have been discussed by means of effects of substituents on the spectral frequencies.
    Źródło:
    World Scientific News; 2019, 115; 52-67
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and effects of substituent on (E)-styryl-3-methyl-2-thienyl chalcones
    Autorzy:
    Christuraj, P.
    Geetha, C.
    Vanangamudi, G.
    Arulkumaran, R.
    Manikandan, V.
    Rajakumar, P. R.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1161056.pdf
    Data publikacji:
    2018
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones
    FT-IR & NMR spectra
    Fly-ash:H3PO4 nanocatalyst
    Hammett correlation analysis
    Substituent effects
    UV
    solvent-free synthesis
    Opis:
    Series of eleven substituted of (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones compounds by cross-aldol condensation reaction of 3-methylthiophene-2-carbaldehyde with various substituted acetaldehyde in the occurrence of Fly-Ash: H3PO4 catalyst. The effect of catalytic activity of this fly-ash:H3PO4 nanocatalyst was studied with the obtained yield of products under solvent-free conditions. The synthesized substituted (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The infrared group frequencies of ʋ(cm-1) of COs-cis & s-trans, CHip and CHop, CH=CHop, >C=C
    Źródło:
    World Scientific News; 2018, 112; 55-73
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and spectral studies of some N-[(E)-phenylmethylidene]benzenesulfonamides
    Autorzy:
    Sekar, K. G.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/412358.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    N-[(E)-phenylmethylidene]benzenesulfonamides
    SiO2-H3PO4
    Greener synthesis
    Hammett correlations
    Opis:
    A series of some N-[(E)-phenylmethylidene]benzenesulfonamide derivatives have been synthesised using solid SiO2-H3PO4 catalyst under solvent free conditions in microwave irradiation. The synthesised E-N-benzene sulfonilimines purities have been verified by their physical constants and spectroscopic data. The spectral frequencies are correlated with Hammett substituent constants, F and R parameters using linear regression analysis. From the results of statistical analysis the effect of substituents on the group frequencies will be discussed.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 8, 3; 249-258
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, effect of substituents and antimicrobial activities of some 4-bromophenyl chalcones
    Autorzy:
    Vijayakumar, S.
    Vanangamudi, G.
    Thirunarayanan, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/1191238.pdf
    Data publikacji:
    2016
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    (E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones
    UV spectra
    IR spectra
    NMR spectra
    Substituent effects
    Antimicrobial activities
    Opis:
    Elven (E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones are formed using sodium hydroxide catalyzed Aldol condensation between 4-bromoacetophenone and substituted benzaldehyde. The production of these chalcone compounds are above 90%. These α, β unsaturated ketones were specified by their physical constants and spectral data (UV, IR, 1H and 13C-NMR). Hammett substituted constants (σ, σ+, σI & σR and F and R parameters have been used for correlating the spectral values of these α, β unsaturated ketones by using single and multi-linear regression analysis. The impacts of substituents on the spectral data have been known on statistical analysis. By using Bauer-Kirby method the anti-microbial activities of these (E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones compounds are estimated.
    Źródło:
    World Scientific News; 2016, 54; 132-152
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-10 z 10

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