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    Wyświetlanie 1-4 z 4
    Tytuł:
    Application of cross-linked chitosan for nitrate nitrogen (v) removal from aqueous solutions
    Autorzy:
    Jóźwiak, Tomasz
    Filipkowska, Urszula
    Szymczyk, Paula
    Mielcarek, Artur
    Powiązania:
    https://bibliotekanauki.pl/articles/1035179.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
    Tematy:
    adsorption
    chitosan beads
    cross-linked chitosan beads
    dyes
    glutaraldehyde
    Opis:
    This study was aimed at determining the possibility of applying non-cross-linked chitosan (CHs) as well as chitosan cross-linked with glutaraldehyde (CHs-GLA) and epichlorohydrin (CHSECH) for the removal of nitrates (V) from aqueous solutions. The scope of the study included determinations of: optimal pH value of nitrates sorption (from pH range of 2-11), equilibrium time of sorption process, and maximum N-NO3 sorption capacity of the analysed chitosan sorbents. Kinetics of nitrates sorption was described with pseudo-first and pseudo-second order equations, and with the intraparticle diffusion model. Sorption capacity analysis was conducted with the heterogeneous Langmuir model, the double Langmuir model and the Freundlich model. The optimal pH value of N-NO3 sorption onto CHs-GLA and CHs-ECH was pH 3, whereas onto CHs this was pH 4. The equilibrium time of sorption reaction was the same for all chitosan sorbents and reached 120 min. The maximum sorption capacity of CHs, CHs-GLA and CHs- ECH accounted for 12.71 mg N-NO3/g, 34.99 mg N-NO3/g and 38.47 mg N-NO3/g.
    Źródło:
    Progress on Chemistry and Application of Chitin and its Derivatives; 2014, 19; 41-52
    1896-5644
    Pojawia się w:
    Progress on Chemistry and Application of Chitin and its Derivatives
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of chitosan ionically crosslinked with sodium edetate for reactive dyes removal from aqueous solutions
    Autorzy:
    Jóźwiak, Tomasz
    Filipkowska, Urszula
    Szymczyk, Paula
    Kuczajowska-Zadrożna, Małgorzata
    Mielcarek, Artur
    Powiązania:
    https://bibliotekanauki.pl/articles/1034883.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
    Tematy:
    chitosan beads
    crosslinking
    dyes sorption
    sodium edetate
    Opis:
    In this study, we investigated the effect of chitosan crosslinking with sodium edetate (SE) on its sorption capacity of Reactive Black 5 and Reactive Yellow 84 dyes. The first stage of the study allowed establishing conditions of chitosan crosslinking. The process of ionic crosslinking was effective only at pH 4 and at the optimal dose of sodium edetate ranging from 0.046 to 0.462 g/g CHs. Process temperature in the range of 20-60oC had no significant effect on the stability of crosslinked chitosan. Contrary to the non-crosslinked chitosan (CHs), chitosan crosslinked with sodium edetate (CHs-SE) was capable of dyes sorption at pH 3. Sorption of reactive onto both CHs and CHs-SE was the most effective at pH 4. Chitosan crosslinking with SE had a positive effect on the effectiveness of RB5 and RY84 sorption. This effect was especially tangible within the first ten or so hours of sorption. After 24 h of the process, the sorption capacity of CHs-SE against RB5 and RY84 reached 1296.69 mg/g and 1883.62 mg/g, respectively. In the case of CHs, sorption capacity achieved after the same time was lower and accounted for 1025.55 mg RB5/g and 1539.67 mg RY84/g.
    Źródło:
    Progress on Chemistry and Application of Chitin and its Derivatives; 2015, 20; 82-96
    1896-5644
    Pojawia się w:
    Progress on Chemistry and Application of Chitin and its Derivatives
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of dyes from aqueous solutions by glauconite immobilised on chitosan hydrogel beads
    Autorzy:
    Jóźwiak, Tomasz
    Filipkowska, Urszula
    Szymczyk, Paula
    Kuczajowska-Zadrożna, Małgorzata
    Mielcarek, Artur
    Powiązania:
    https://bibliotekanauki.pl/articles/1034580.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
    Tematy:
    Basic Violet 10
    Reactive Black 5
    chitosan
    glauconite
    hydrogel beads
    immobilisation
    sorption
    Opis:
    The sorption capacity of glauconite, glauconite immobilised on chitosan hydrogel beads and unmodified chitosan hydrogel beads against Reactive Black 5 and Basic Violet 10 was compared in this article. The effect of pH on the sorption effectiveness of dyes on the tested sorbents was investigated and the sorption capacity of sorbents after 24 and 72 h was determined. Langmuir sorption, double Langmuir and Freundlich isotherms were used to describe the experimental data. The adsorption efficiency of the dyes on sorbents containing chitosan was highest at pH 4. In the case of glauconite, Reactive Black 5 removal efficiency was the highest at pH 3, and Basic Violet 10 removal efficiency was highest at pH 2. The sorption capacity of glauconite immobilised on chitosan hydrogel spheres obtained after 72 h was -656.73 mg/g and -32.77 mg/g for Reactive Black 5 and Basic Violet 10, respectively.
    Źródło:
    Progress on Chemistry and Application of Chitin and its Derivatives; 2017, 22; 54-65
    1896-5644
    Pojawia się w:
    Progress on Chemistry and Application of Chitin and its Derivatives
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The influence of chitosan deacetylation degree on reactive black 5 sorption efficiency from aqueous solutions
    Autorzy:
    Jóźwiak, Tomasz
    Filipkowska, Urszula
    Szymczyk, Paula
    Kuczajowska-Zadrożna, Małgorzata
    Mielcarek, Artur
    Zyśk, Michał
    Powiązania:
    https://bibliotekanauki.pl/articles/1034679.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
    Tematy:
    Reactive Black 5
    chitosan
    deacetylation degree
    sorption
    Opis:
    In the paper sorption capacity of chitosan having a deacetylation degree DD=75%, DD=85% and DD=90% relatively to the Reactive Black 5 were compared. Studies on the effectiveness of the dye sorption were carried out in a wide pH range – from 3 to 11. For each of the tested chitosan sorbents, sorption capacity has been determined. The results were described by isotherms Freundlich and Lagmuir isotherms, and a double Langmuir isotherm. Sorption of Reactive Black 5 most efficiently occurred at pH 4. At pH <4 chitosan sorbents underwent dissolution, regardless of the degree of deacetylation. The efficiency of dye sorption increased with the degree of deacetylation. The sorption capacity calculated after 12 h of the chitosan sorption with DD=75%, DD=85% and DD =90% was, relatively to the Reactive Black 5, respectively 433.03 mg/g and 464.52 mg/g and 532.14 mg/g. The impact of the deacetylation degree on pHZPC (zero point of charge) of the sorbent was also examined. Along with the increase in the deacetylation degree the value of chitosan pHZPC increased as well and at DD=75% DD=85% and DD=90%, pHZPC amounted respectively 7.6, 7.7 and 7.8.
    Źródło:
    Progress on Chemistry and Application of Chitin and its Derivatives; 2016, 21; 83-92
    1896-5644
    Pojawia się w:
    Progress on Chemistry and Application of Chitin and its Derivatives
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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