- Tytuł:
- Synthesis and spectral Hammett correlation analysis of some (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds
- Autorzy:
-
Christuraj, P.
Rajakumar, P. R.
Geetha, C.
Vanangamudi, G.
Arulkumran, R.
Manikandan, V.
Sundararajan, R.
Thirunarayanan, G. - Powiązania:
- https://bibliotekanauki.pl/articles/1179576.pdf
- Data publikacji:
- 2017
- Wydawca:
- Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
- Tematy:
-
(E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-ones
FT-IR and NMR spectra
Hammett correlation analysis
Substituent constants
Substituent effects
UV - Opis:
- A series of substituted of (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds by cross-aldol condensation reaction of 5-bromothiophene-2-carbaldehyde with various substituted acetaldehyde in the presence sodium hydroxide (base). The synthesized substituted (E)-3-(5-bromothiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The group frequencies of infrared ʋ(cm-1) of CO s-cis and s-trans, CH in-plane and out of plane, CH=CH out of plane, >C=C< out of plane modes, NMR chemical shifts δ (ppm) of Hα, Hβ, CO, Cα and Cβ of these chalcones were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analyses.
- Źródło:
-
World Scientific News; 2017, 74; 15-35
2392-2192 - Pojawia się w:
- World Scientific News
- Dostawca treści:
- Biblioteka Nauki
Artykuł