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    Wyświetlanie 1-11 z 11
    Tytuł:
    Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411747.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange reactions
    nuclear grade resins
    cation exchange resins
    enthalpy
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 127-135
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. K. L.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411848.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange equilibrium
    nuclear grade resins
    cation exchange
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 231-239
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412388.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange
    nuclear grade resins
    cation exchangers
    enthalpy change
    standard equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 190-198
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on Halide Ions Selectivity of Industrial Grade Anion Exchange Resin Auchlite A-378
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412220.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    selectivity
    ion exchange reactions
    halide ions
    industrial grade resins
    anion exchange resins
    enthalpy
    equilibrium constant
    Auchlite A-378
    Opis:
    The thermodynamic approach was applied to predict the trend selectivity of industrial grade anion exchange resin Auchlite A-378 in chloride form towards iodide and bromide ions in the solution. The study was conducted by performing the Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions under gradually increasing temperature conditions. The thermodynamic equilibrium constants K values were used to calculate the enthalpies of the two uni-univalent ion exchange reactions. It was observed that the K values for Clˉ/Iˉ ion exchange reaction were higher than Clˉ/Brˉ exchange reaction under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -39.51 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction is responsible for higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 44-50
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412305.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    selectivity
    ion exchange reactions
    halide ions
    nuclear grade resins
    anion exchange resins
    enthalpy
    equilibrium constant
    Auchlite ARA-9366
    Opis:
    The selectivity behaviour of nuclear grade anion exchange resin Auchlite ARA-9366 in chloride form towards iodide and bromide ions in the solution was studied. The trend in selectivity of the resin was predicted on the basis of thermodynamics of Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions. It was observed that the equilibrium constants K values for Clˉ/Iˉ ion exchange reaction were higher than that calculated for Clˉ/Brˉ exchange under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -47.87 and -36.14 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction as compared to that obtained during Clˉ/Brˉ exchange supports higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 67-73
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ion-exchange reaction thermodynamics to study the selectivity behaviour of nuclear and non-nuclear grade anion exchange resins
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412083.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ionic selectivity
    uni-univalent exchange
    thermodynamic equilibrium constant
    enthalpy
    nuclear grade ion exchange resin
    Auchlite ARA-9366
    Auchlite A-378
    Opis:
    In the present investigation, attempts were made to understand the difference in bromide ion selectivity of the two closely related anion exchange resins Auchlite ARA-9366 and Auchlite A-378 in chloride form. The selectivity difference was predicted based on the thermodynamic equilibrium constants and enthalpy values of Clˉ/Brˉ ion exchange reactions performed by using the two resins. During Clˉ/Brˉ exchange reactions, with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 8.15x10-2 to 6.06x10-2 for Auchlite ARA-9366 resins and from 2.16x10-2 to 1.10x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -36.14 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the bromide ions in the solution as compared to Auchlite A-378 resins.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 6; 8-15
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamics of Ion-exchange reaction in predicting the ionic selectivity of Auchlite ARA-9366 and Auchlite A-378 anion exchange resins
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412499.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ionic selectivity
    uni-univalent exchange
    thermodynamic equilibrium constant
    enthalpy
    nuclear grade ion exchange resin
    Auchlite ARA-9366
    Auchlite A-378
    Opis:
    The paper deals with predicting the iodide ion selectivity of nuclear and non-nuclear grade anion exchange resins. The ionic selectivity prediction was made on the basis of thermodynamic data of Clˉ/I ˉ ion exchange reaction. It was observed that with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 59.77x10-2 to 23.77x10-2 for Auchlite ARA-9366 resins and from 9.01x10-2 to 4.05x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -47.87 and -39.51 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the iodide ions in the solution as compared to Auchlite A-378 resins, when both the resins are present in chloride form.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 6; 1-7
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412486.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    uni-univalent ion exchange reactions
    ionic selectivity
    nuclear grade resins
    cation exchangers
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 15; 22-29
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Radiotracer Technique in Study of Strongly Basic Anion Exchange Resins Dowex-SBR LC and Indion-454
    Autorzy:
    Singare, P. U.
    Powiązania:
    https://bibliotekanauki.pl/articles/411866.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    anion exchange resins
    Indion-454
    Dowex-SBR LC
    radioisotopes
    131I
    82Br
    ion-isotopic exchange reaction
    reaction kinetics
    characterization
    Opis:
    The present paper demonstrates application of isotopic tracer technique in characterization of anion exchange resins Dowex-SBR LC and Indion-454 for which 131I and 82Br radio isotopes were used. The characterization was made based on iodide and bromide ion-isotopic exchange reaction kinetic data obtained for the two resins. It was observed that during iodide ion-isotopic exchange reaction performed at 35.0 °C, 1.000 g of ion exchange resins and 0.002 mol/L labeled iodide ion solution, the values of specific reaction rate (min-1), amount of ion exchanged (mmol), initial rate of ion exchange (mmol/min) and log Kd were 0.379, 0.426, 0.161 and 16.2 respectively for Dowex-SBR LC resin, which was higher than the respective values of 0.156, 0.243, 0.038 and 13.4 as that obtained by using Indion-454 resins. The identical trend was observed for the two resins during bromide ion-isotopic exchange reaction. The results of present investigation also indicate that during the two ion-isotopic exchange reactions, for both the resins, there exists a strong positive linear correlation between amount of ions exchanged and concentration of ionic solution; and strong negative correlation between amount of ions exchanged and temperature of exchanging medium. Based on overall results it appears that under identical experimental conditions, as compared to Indion-454 resins, Dowex-SBR LC resins show superior performance. It is expected here that the present technique can be extended further for characterization of different ion exchange resins which will further help in the selection of those reins for the specific industrial application.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 13; 37-49
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of Nondestructive Radio Tracer Technique in Performance Evaluation of Anion Exchange Resins Duolite ARA-9366 and Duolite A-171
    Autorzy:
    Singare, P. U.
    Powiązania:
    https://bibliotekanauki.pl/articles/412526.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    non-destructive tracer technique
    radio analytical technique
    radioactive tracer isotopes
    131I
    82Br
    reaction kinetics
    ion-isotopic exchange reactions
    nuclear grade resin
    Duolite ARA-9366
    Duolite A-171
    Opis:
    Radio analytical technique as a non-destructive technique was used in the present investigation to trace the kinetics of ion-isotopic exchange reaction taking place in Duolite ARA-9366 (nuclear grade) and Duolite A-171 (non-nuclear grade) anion exchange resins. The kinetics data suggest that during iodide ion-isotopic exchange reactions under identical experimental conditions of 40.00C, 1.000 g of ion exchange resins and 0.003 M labeled iodide ion solution, the values of specific reaction rate (min-1), amount of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol/min) and log Kd were 0.176, 0.383, 0.067 and 7.8 respectively for Duolite ARA-9366 resin, which was higher than 0.142, 0.353, 0.050 and 7.0 respectively as that obtained for Duolite A-171 resins. Also it is observed that at a constant temperature of 40.0 °C, as the concentration of labeled iodide ion solution increases 0.001 M to 0.004 M, the percentage of iodide ions exchanged increases from 49.20 % to 51.80 % for Duolite ARA-9366 resins; and from 45.20 % to 47.80 % for Duolite A-171 resins. The similar trend was observed for the two resins during bromide ion-isotopic exchange reactions. The overall results indicate superior performance of Duolite ARA-9366 resins over Duolite A-171 resins under identical operational parameters.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 13; 63-76
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412153.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    cation exchange
    nuclear grade resins
    ion exchangers
    change in enthalpy
    equilibrium constant in standard state
    Indion-223
    Opis:
    In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 199-207
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-11 z 11

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