- Tytuł:
- Meta-stable solidification created by the detonation method of coating formation
- Autorzy:
-
Wołczyński, W.
Garzeł, G.
Morgiel, J.
Senderowski, C.
Pawłowski, A. - Powiązania:
- https://bibliotekanauki.pl/articles/382812.pdf
- Data publikacji:
- 2012
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
krystalizacja
krzepnięcie szybkie
powłoka Fe-Al
faza amorficzna
theory of crystallization
rapid solidification process
Fe-Al coating
meta-stable phase diagram
amorphous phase - Opis:
- Particles of the Fe-Al type (less than 50 m in diameter) were sprayed onto the 045 steel substrate by means of the detonation method. The TEM, SAED and EDX analyses revealed that the Fe-Al particles have been partially melted in the experiment of coating formation. Particle undergone melting even within about 80% of its volume. Therefore, solidification of the melted part of particles was expected. Solidification differed significantly due to a large range of chemical composition of applied particles (from 15 at.% Al up to 63 at.% Al). A single particle containing 63 at.% Al was subjected to the detailed analysis, only. The TEM / SAED techniques revealed in the solidified part of particle three sub-layers: an amorphous phase, [...] , periodically situated FeAl + Fe2Al5 phases, and a non-equilibrium phase, [...]. A hypothesis dealing with the inter-metallic phases formation in such a single particle of the nominal composition No = 0.63 is presented. At first, the solid / liquid system is treated as an interconnection: substrate / liquid / nonmelted particle part . Therefore, it is suggested that the solidification occurs simultaneously in two directions: towards a substrate and towards a non-melted part of particle. The solidification mechanism is referred to the Fe-Al meta-stable phase diagram. It is shown that the melted part of particle solidifies rapidly according to the phase diagram of meta-stable equilibrium and at a significant deviation from the thermodynamic equilibrium.
- Źródło:
-
Archives of Foundry Engineering; 2012, 12, 2; 93-96
1897-3310
2299-2944 - Pojawia się w:
- Archives of Foundry Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł