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Wyszukujesz frazę "Podsiadła, D." wg kryterium: Autor


Wyświetlanie 1-2 z 2
Tytuł:
Optical and Dilatometric Properties of (CH$\text{}_{3}$)$\text{}_{2}$NH$\text{}_{2}$Al(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O Crystals in Paraelectric and Ferroelectric Phases
Autorzy:
Podsiadła, D.
Czapla, Z.
Andriyevsky, B.
Myshchyshyn, O.
Powiązania:
https://bibliotekanauki.pl/articles/2011078.pdf
Data publikacji:
1999-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.Kb
78.20.Fm
Opis:
Experimental investigation of the thermal linear expansion l(T) and temperature dependencies of the interference optical path difference D(T) were carried out for (CH$\text{}_{3}$)$\text{}_{2}$ NH$\text{}_{2}$Al(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O crystal, in the range of 120-310 K for three crystal physical directions. Decrease in electrostriction coefficients g of crystal was observed on approaching the phase transition point T$\text{}_{c}$ ≈ 150 K in ferroelectric phase. Relative temperature changes of the lengthening δl/l and refractive index δn/(n-1) are of the same order of magnitude. Peculiarities of temperature dependence of dilatometric and optical parameters of (CH$\text{}_{3}$)$\text{}_{2}$NH$\text{}_{2}$Al(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O testify for qualitative reconstruction of chemical bonds in the crystal when temperature changes in the same phase.
Źródło:
Acta Physica Polonica A; 1999, 96, 3-4; 409-416
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Vibrational Spectroscopic Properties of a $[C(NH_2)_3]_4Cl_2SO_4$ Ferroelectric Crystal - An Experimental and Theoretical Study
Autorzy:
Podsiadła, D.
Czupiński, O.
Dudzic, D.
Czapla, Z.
Powiązania:
https://bibliotekanauki.pl/articles/1207043.pdf
Data publikacji:
2014-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.30.-j
78.20.Bh
77.80.B-
Opis:
Tetraguanidinium dichloride-sulphate crystal, $[C(NH_2)_3]_4Cl_2SO_4$, abbreviated as $G_4Cl_2SO_4$ was investigated. The vibrational infrared spectra of powdered $G_4Cl_2SO_4$ crystal in Nujol mull were studied in the wide range of temperature, from 298 K to 377 K. This temperature range contains all the phases in the crystal (named III, II, I on heating, respectively). The temperature changes of wavenumbers, centre of gravity, and intensity of the bands were analyzed to clarify the molecular mechanism of the phase transitions. It was shown that in cooling from 377 K to 313 K the phase II is the same as the room temperature phase. Information about hydrogen bonds was obtained. The time dependence of internal vibrations at 356 K was observed and it was connected with slow transition III → II. For more detailed band assignment Raman spectrum at room temperature, at ferroelectric phase was carried out. Theoretical calculations were made based on density functional theory, with the B3LYP method using 6-311 + G(d,p) basic set. Calculated normal vibrational modes of the molecule, their frequencies and intensities were compared with these recorded in experiment. Theoretical description of the molecule including hydrogen bonds were optimized and the bond parameters were obtained. The Mulliken charges population analysis was performed.
Źródło:
Acta Physica Polonica A; 2014, 125, 1; 115-127
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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