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Wyświetlanie 1-3 z 3
Tytuł:
Magnetic Properties and Electronic Structure of CeTIn (T = Ni, Cu, Pd, Au) Compounds
Autorzy:
Szytuła, A.
Penc, B.
Gondek, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/2047306.pdf
Data publikacji:
2007-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Eh
71.27.+a
75.20.Hr
79.60.-i
Opis:
The electronic structure of the ternary CeTIn (T = Ni, Cu, Pd, Au) compounds was investigated by means of X-ray photoelectron spectroscopy. Our interest was aimed mainly to the valence bands and the Ce3d core levels of investigated compounds. Analysis of the valence bands indicates that they are mainly determined by the Tnd band, whereas a share of the R4f states can be estimated to be about a few percent only. The analysis of the differential valence bands spectra between CeTIn and LaTIn analogues suggests that the Ce4f$\text{}^{1}$ ground states shift deeper below the Fermi level with an increase in the 4f level occupation factor. The analysis of the Ce3d spectra made on the basis of the Gunnarsson-Schönhammer model indicates the hybridization parameter equal to 148 meV for CeNiIn, 45 meV for CeCuIn, 177 meV for CePdIn, and 123 meV for CeAuIn.
Źródło:
Acta Physica Polonica A; 2007, 111, 4; 475-486
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electronic Structure of CePtIn and LaPtIn Compounds
Autorzy:
Jezierski, A.
Penc, B.
Szytuła, A.
Winiarski, A.
Powiązania:
https://bibliotekanauki.pl/articles/1419892.pdf
Data publikacji:
2012-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.-b
71.20.Lp
71.27.+a
79.60.-i
Opis:
The electronic structure of the ternary RPtIn (R = La, Ce) compounds, which crystallize in the hexagonal ZrNiAl-type structure, was studied by X-ray photoelectron spectroscopy measurements and calculation using the ab initio methods (linear muffin-tin orbital in the atomic sphere approximation, full potential linear muffin-tin orbital, full potential linear orbital). The results showed that the valence band in these compounds is formed by the Pt 5d and In 5s and 5p states. The band calculations with spin-orbit coupling have shown that the Ce 4f peaks consist of two peaks above the Fermi level that correspond to the $Ce 4 f_{7/2}$ and $4 f_{5/2}$ doublet and wide peaks corresponding to the La 4f states. The analysis of Ce 3d spectra on the basis of the Gunnarsson-Schönhammer model gives hybridization of 4f orbitals with the conduction electron band equal to 170 meV.
Źródło:
Acta Physica Polonica A; 2012, 122, 1; 212-215
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Valence Band of $Ce_2Co_{0.8}Si_{3.2}$ and $Ce_2RhSi_3$ Studied by Resonant Photoemission Spectroscopy and FPLO Calculations
Autorzy:
Starowicz, P.
Kurleto, R.
Goraus, J.
Walczak, Ł.
Penc, B.
Adell, J.
Szlawska, M.
Kaczorowski, D.
Szytuła, A.
Powiązania:
https://bibliotekanauki.pl/articles/1374249.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.27.+a
75.30.Mb
71.20.Eh
74.25.Jb
Opis:
This work presents studies of the valence band of two Kondo lattice systems: $Ce_2Co_{0.8}Si_{3.2}$, which is paramagnetic with the Kondo temperature $T_{K}$ ≈50 K and $Ce_2RhSi_3$, which is antiferromagnetic below $T_{N}$=4.5 K and exhibits $T_{K}$ ≈9 K. The photoemission spectra, which are obtained with photon energy tuned to Ce 4d-4f resonance, reveal a Kondo peak at the Fermi energy $(E_{F})$, its spin-orbit splitting partner at 0.24 eV and a broad maximum related to Ce $f^0$ final state. The spectra indicate that Kondo peak has a higher intensity for $Ce_2Co_{0.8}Si_{3.2}$. The off-resonance photoemission data reveal that a maximum in the 3d electron density of states is shifted towards $E_{F}$ for $Ce_2Co_{0.8}Si_{3.2}$ as compared to $Ce_2RhSi_3$. Full-potential local-orbital calculations were realized with local spin density approach +U approach for 213 stoichiometry. They show that a higher density of states near $E_{F}$ is observed for $Ce_2CoSi_3$. The calculations also reveal the existing tendencies for antiferromagnetic and ferromagnetic ground states in a case of $Ce_2RhSi_3$ and $Ce_2CoSi_3$, respectively.
Źródło:
Acta Physica Polonica A; 2014, 126, 4a; A-144-A-147
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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