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Wyszukujesz frazę "lignin oxidation" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Limitation of lignin derivatives as biomarkers of land derived organic matter in the coastal marine sediments
Autorzy:
Pempkowiak, J.
Powiązania:
https://bibliotekanauki.pl/articles/2079190.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
lignin oxidation
biomarker
stable carbon isotope
nonlinear analysis
Gdansk Bay
Southern Baltic Sea
coastal sediment
Opis:
Lignin oxidation products (vanillyl, syringil and cummaryl phenols), and δ13C were measured in a variety of land and marine samples collected in Inner Puck Bay – dominated by marine vascular plants, small river run-off, and shallow bottom, and in Gdańsk Bay – characterized by large river run-off, small marine vascular plants population, and the average depth exceeding euphotic zone. Both study areas are parts of the Gdańsk Basin, Southern Baltic. Typical δ13C values (δ13C = -28‰) and both composition and concentrations of lignin phenols were measured in samples originating from land. Small, yet easily measurable amounts of lignin phenols were found in marine vascular plants biomass (Σ8 = 90 µg/100 mg organic matter). The biomass was characterized by exceptionally high δ13C values (-12‰). No lignin phenols and typical δ13C values (-22‰) were measured in marine phytoplankton biomass. δ13C and both composition and content of lignin phenols in organic matter of surface sediments collected in the study area fall in the range marked by the end members. The proportion of land derived organic matter calculated using lignin phenols, or δ13C in Gdańsk Bay were comparable, while in Puck Bay they differed substantially. It was concluded that a) in areas with substantial bottom coverage with vascular plants the two end members approach, usually employed to establish the contribution of organic matter sources, is insufficient, b) organic matter originating from three sources: riverine, phytoplankton, and vascular plants contribute to sedimentary organic matter in Puck Bay with the respective proportion 30:40:30.
Źródło:
Oceanologia; 2020, 62, 3; 374-386
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Horizontal and vertical distribution of lignin in surface sediments of the Gdańsk Basin
Autorzy:
Staniszewski, A.
Lejman, A.
Pempkowiak, J.
Powiązania:
https://bibliotekanauki.pl/articles/47928.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
oxidation provenience
organic matter
surface sediment
vertical distribution
accumulation area
Baltic Sea
Vistula River
Gdansk Basin
horizontal distribution
lignin
Opis:
The aim of this study was to identify and quantify lignin transported from the River Vistula to the accumulation area in the Gdańsk Basin. Sediment samples collected along the Vistula mouth –Gdańsk Deep transect were analysed for lignin. Lignin was characterised by oxidative degradation, cupric oxide being chosen as the most suitable oxidising agent. The polar functional groups of the oxidation products were silylated and the derivatives analysed by capillary gas chromatography on fused capillary silica columns with flame ionisation detection. Lignin-derived oxidation products were quantified in the range from 3 to 20 μg g−1 dry wt. for phenolic acids and from 6 to 12 μg g−1 dry wt. for phenolic aldehydes. Differences in oxidation products contents are assigned to different lignin sources in the marine environment. The horizontal and vertical gradients of these compounds in the sediments of the Gdańsk Basin are documented. The results are discussed in terms of the origin and fate of organic matter in the Gdańsk Basin. The measured differences in quality and quantity of the identified oxidation products provide insight into diagenetic processes in the surface marine sediments.
Źródło:
Oceanologia; 2001, 43, 4
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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