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Wyszukujesz frazę "crosslinking" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Structural and swelling properties of hydrogel membranes based on chitosan crosslinked with glutaraldehyde and sodium tripolyphosphate
Autorzy:
Gierszewska-Drużyńska, Magdalena
Ostrowska-Czubenko, Jadwiga
Powiązania:
https://bibliotekanauki.pl/articles/1035178.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
crosslinking
membranes
swelling kinetics
Opis:
Chemically and physically crosslinked chitosan hydrogel membranes were obtained by treatment of chitosan (Ch) with glutaraldehyde (GA) and with GA and subsequently with sodium tripolyphosphate (TPP). The formation of covalent and ionic crosslinks between Ch, GA and ionic TPP was confirmed by FTIR spectroscopy. The studies of dynamic swelling behaviour of synthesized membranes in buffer solutions of different pH (1.0, 7.4, 9.0) indicated that the swelling process obeyed a second-order kinetics. Values of an apparent swelling rate constant for Ch/GA and Ch/GA/TPP membranes were of the same order for acidic and neutral swelling media but they increased for alkaline solutions.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2015, 20; 43-53
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Equilibrium swelling study of crosslinked chitosan membranes in water, buffer and salt solutions
Autorzy:
Gierszewska, Magdalena
Ostrowska-Czubenko, Jadwiga
Powiązania:
https://bibliotekanauki.pl/articles/1034640.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
crosslinking
equilibrium swelling
membranes
Opis:
Physically crosslinked membranes were prepared by treating chitosan (Ch) with pentasodium tripolyphosphate (TPP) at different reaction conditions. The equilibrium swelling ratio, Seq, of Ch/TPP membranes in water, buffer and salt solutions at 37 C were determined. The experimental data indicated, that Seq depended on pH of buffer solution and type and concentration of salt solution. Swelling capacity in water depended on the content of TPP ions in the membrane and crosslinking density
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2016, 21; 55-62
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of crosslinking process conditions on molecular and supermolecular structure of chitosan hydrogel membrane
Autorzy:
Gierszewska-Drużyńska, Magdalena
Ostrowska-Czubenko, Jadwiga
Powiązania:
https://bibliotekanauki.pl/articles/1035415.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
crosslinking
membrane
morphology
supermolecular stucture
Opis:
Unmodified (Ch) and ionically crosslinked with sodium tripolyphosphate (Ch/TPP) chitosan membranes were prepared. Various crosslinking conditions (pH, crosslinking time) were applied. Differences in membrane molecular structure was examined using FTIR spectroscopy. Scanning electron microscopy (SEM) coupled with Energy Dispersive X-Ray (EDX) Spectrometer as well as atomic force microscopy (AFM) were used for estimation of an effect of crosslinking conditions on supermolecular structure of chitosan membrane. Strong effect of pH of crosslinking TPP solution on crosslinking agent distribution inside the membranes and roughness of membrane surface was found. Differences in membrane morphology prior and after crosslinking results from differences in crosslinking density.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2011, 16; 15-22
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of ionic crosslinking on thermal properties of hydrogel chitosan membranes
Autorzy:
Gierszewska-Drużyńska, Magdalena
Ostrowska-Czubenko, Jadwiga
Powiązania:
https://bibliotekanauki.pl/articles/1035522.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
DSC
TG/DTG
chitosan
crosslinking
hydrogel
thermal stability
Opis:
Ionically crosslinked one‑component chitosan (Ch), two‑component chitosan/sodium alginate (Ch/NaAlg) and chitosan/pentasodium tripolyphosphate (Ch/TPP) membranes as well as three‑component chitosan/sodium alginate/pentasodium tripolyphosphate (Ch/NaAlg/TPP) membranes were prepared. Formation of ionic interactions between Ch and NaAlg and/or TPP was confirmed by FTIR analysis. An effect of a crosslinking process on thermal properties of hydrogel membranes was examined using TG/DTG/DTA and DSC methods. Changes in the number of thermal degradation steps of the studied hydrogel membranes were observed. Considering the temperature at which thermal degradation starts as a criterion of the thermal stability, it was concluded that the thermal stability increases according to the series: Ch/NaAlg ≈ Ch/NaAlg/TPP ≈ Ch/TPP
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2010, 15; 25-32
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
State of water in noncrosslinked and crosslinked hydrogel chitosan membranes – dsc studies
Autorzy:
Ostrowska-Czubenko, Jadwiga
Pieróg, Milena
Gierszewska-Drużyńska, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/1035477.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
DSC
chitosan membranes
crosslinking
glutaraldehyde
states of water
trisodium citrate.
Opis:
Modified chitosan hydrogel membranes were prepared using glutaraldehyde (GA) and sodium citrate (NaCIT) as crosslinking agents. Molecular and supermolecular structure analyses of unmodified and modified chitosan membranes have been conducted by FTIR and X-ray spectroscopy. FTIR results showed covalent and ionic crosslinks formation between chitosan (Ch) and GA or simultaneously Ch, GA and NaCIT. The state of water in noncrosslinked and crosslinked chitosan membranes were analysed by differential scanning spectroscopy (DSC). Three types of water in hydrogel membranes were found: non-freezing bound water, freezing bound water and freezing free water, while there were variations in the amount of non-freezing bound water in these polymers. The effect of ionic crosslinking on water state, mainly on the nonfreezing water content, was discussed.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2011, 16; 147-156
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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