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Wyszukujesz frazę "inhibitor" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl
Autorzy:
Ezeugo, J. N. O.
Onukwuli, O. D.
Omotioma, M.
Powiązania:
https://bibliotekanauki.pl/articles/1113582.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Picralima nitida
Zinc
corrosion
inhibitor
optimization
Opis:
Herein, the optimization of inhibitive action of the ethanol extract of oil from Picralima nitida leaves, towards acid corrosion of zinc, was tested using weight loss and thermometry methods. We found that the extract acts as a good corrosion inhibitor for zinc corrosion in 0.1 M HCl solutions. The inhibition action of the extract was discussed in view of Langmuir adsorption isotherm. This revealed that spontaneous processes govern the adsorption of the extract on zinc surface. Herein, the inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was also studied. This indicated that the presence of the extract increases the needed activation energy of the corrosion reaction. Furthermore, in our work, an optimal inhibition efficiency IE (%) of 86.78 was obtained at optimum inhibitor concentration of 1.2 gl-1, optimum temperature and time of 313 k and 8 hrs, respectively. From the calculated thermodynamic parameters, it can be said, then, that Picralima nitida extract provides good protection to zinc against pitting corrosion in chloride ion containing solutions.
Źródło:
World News of Natural Sciences; 2017, 15; 139-161
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Plant extract as biodegradable inhibitor for zinc in dilute solution of sulphuric acid
Autorzy:
Onukwuli, O. D.
Ezeugo, J. O.
Powiązania:
https://bibliotekanauki.pl/articles/1163555.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Picralima nitida leaf
Zinc
corrosion
inhibition
inhibitor
Opis:
The inhibitive action of the ethanol extract of oil from Picralima nitida leaf, towards acid corrosion of zinc, is tested using weight loss, and thermometry methods. It was found that the extract acted as a good corrosion inhibitor for zinc corrosion in 0.5 M H2SO4 solution. The inhibitive action of the extract was discussed in view of Langmuir adsorption isotherm. It was revealed that the adsorption of the extract on zinc surface is governed by spontaneous process. The inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was studied. Revelation from the studies indicates that the presence of extract increases the activation energy of the corrosion reaction. Furthermore, from the calculated thermodynamic parameters, it was observed that Picralima nitida extract provides a good protection to zinc against pitting corrosion in chloride ion containing solutions.
Źródło:
World Scientific News; 2018, 109; 195-210
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Deployment of Antepsin (Sucralfate) as Corrosion Inhibitor of Mild Steel in H2SO4 Medium: Chemical and Electrochemical Studies
Autorzy:
Udeh, B. C.
Onukwuli, O. D.
Omotioma, M.
Powiązania:
https://bibliotekanauki.pl/articles/1839460.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antepsin
Corrosion
H2SO4
Inhibitor
Mild Steel
Opis:
This study presents the deployment of antepsin (sucralfate) as corrosion inhibitor of mild steel in H2SO4 medium. Chemical (gravimetric) and electrochemical (potentiodynamic polarization and electrochemical impedance spectroscopy) techniques were used in the corrosion control investigation. The antepsin drug was characterized by gas chromatography mass spectrophotometer (GCMS) and Fourier transform infrared (FTIR) spectroscopy. Effects of inhibitor concentration, temperature and time on weight loss, corrosion rate, inhibition efficiency and degree of surface coverage were examined. Thermodynamic and adsorption properties of the corrosion inhibition process were determined. Inhibition efficiency was optimized using central composite design tool of Design Expert software version 12. Potentiodynamic polarization and electrochemical impedance spectroscopy were employed to determine the type and effectiveness of the inhibitor. As a confirmatory test, scanning electron microscopy (SEM) was employed to examine the surface morphology of the mild steel samples. Analysis of the results showed that major constituents of antepsin include tetradecanoate, metronidazole, hexadecanoic acid, methyl ester and 11-octadecenoic acid. The predominant functional groups include; C=O stretch, C-H bend and symmetric and asymmetric =C-O-C. Adsorption of the molecules of antepsin on the surface of the mild steel was spontaneous and occurred in agreement with physical adsorption. A quadratic model adequately described the relationship between inhibition efficiency and corrosion control variables of concentration of the inhibitor, temperature and time. Optimum inhibition efficiency of antepsin was obtained as 86.75%. Chemical and electrochemical results agreed that antepsin is suitable for corrosion control of mild steel in H2SO4 solution. Antepsin acted as mixed-type inhibitor (controlled both cathodic and anodic reactions).
Źródło:
World News of Natural Sciences; 2021, 37; 117-134
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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