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Wyszukujesz frazę "Ociepa-Kubicka, A." wg kryterium: Autor


Wyświetlanie 1-2 z 2
Tytuł:
Immobilizacja cynku i kadmu w glebach w wyniku stosowania substratów odpadowych
The Immobilization of Zinc and Cadmium in the Soil as a Result of the Use of Waste Substrates
Autorzy:
Ociepa, E.
Ociepa-Kubicka, A.
Okoniewska, E.
Lach, J.
Powiązania:
https://bibliotekanauki.pl/articles/1819005.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
substraty odpadowe
immobilizacja
sewage sludge
disintegration
pH
Opis:
The overall goal of the presented work was to evaluate the effects of a fertilizing mixture of sewage sludge, brown coal and brown coal (O+W+P) ash on mobility of Zn and Cd in soil environment and metal uptake by Miscanthus Giganteus. The pot experiment was done in semi-natural conditions from April 2007 to January 2008. The soil that was used in the experiment was taken from surroundings of Huta Częstochowa and village Dyrdy. Both soils were poorly contaminated with zinc and cadmium (II0) but there was a difference in their profiles, pH, granulometric compositions, sorption properties etc. The soil used in experiments was taken from 30 points lying on the diagonal of the study area with a depth of 0 to 20 cm. The pots used in the experiment had a capacity of 11 dm3,filled with soil of its natural moisture content after sieving through a sieve with a mesh diameter of 5 mm. For each soil there were used 6 combinations of fertilization and each of the combination was repeated in four pots. The effect of the prepared formulation was compared with the operation of the same residues (O), the mixture of sludge and mineral fertilizer (NPK+O), a mixture of lignite and mineral fertilizer (NPK+W) and the fertilization with mineral fertilizers (NPK). During periods of no precipitation or low precipitation values, the plants were watered to obtain soil moisture level of 60%. Results of this study indicate that all types of fertilizer improved sorption properties of soils, but in varying degrees. The reason is the increase in total exchangeable cations and a significant increase in the sorption capacity of the soil and the degree of saturation of the sorption complex bases. Depending on the soil type, the application of the investigated fertilizing mixture resulted in the increase in pH by 0,3–0,4, sorption capacity by 3,0 cmol(+)kg-1 and degree of sorption complex saturation with bases by 10–40%. The applied fertilizing mixture had a significant effect on limitation of bioavailable forms of Zn and Cd in soils and the content of metals in plant biomass. The introduction of O+W+P and W + NPK mixtures mostly affected to reduction of soluble forms of Zn and Cd in 1 M HCl and 0.01 M CaCl2 in studied soils. To estimate the degree of immobilization of metals in media immobilization If ratios were calculated. If values confirmed that the fertilizations O+W +P and W+NPK contributed to the immobilization of Zn and Cd in both soils. In soil enriched with O+W +P there was an observed reduction of zinc content in plants by approximately 15.0% compared to plants grown on control soil. The reduction of the cadmium content in plants grown on enriched soil 1 O+W+P was approximately 15.0% and approximately 17.0% in soil 2 in relation to the content of the crops grown on unfertilized soils. This was primarily the result of the enrichment of soil by organic matter and soil pH increase which resulted in limiting the mobility and bioavailability of heavy metals.
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 2; 1772-1786
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorpcja ołowiu na modyfikowanym węglu aktywnym ROW 08 Supra
Adsorption of Lead on ROW 08 Supra Modified Activated Carbon
Autorzy:
Lach, J.
Okoniewska, E.
Ociepa-Kubicka, A.
Szymonik, A.
Powiązania:
https://bibliotekanauki.pl/articles/1818532.pdf
Data publikacji:
2015
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
adsorpcja
ołów
izoterma Langmuira
adsorption
lead
Langmuir isotherm
Opis:
The presented work is aimed at comparing two types of gaseous modification: conventional with the use of external source of energy (heat) and originally developed method with Joule heat generated during the flow of electrical current through a carbon bed. Conventional modification of ROW 08 Supra activated carbon was conducted in a rotary furnace in the atmosphere of (1) steam and carbon dioxide at temperature of 400 and 800°C and (2) air at the temperature of 400°C. The modification of activated carbon in the electric heating experimental system (referred to as SEOW) occurred in the process of heating of activated carbon during the flow of electric current through the carbon bed up to 400°C, followed by cooling down with the air or carbon dioxide. Both methods for modification of activated carbons allowed for increasing adsorption capacity towards ions Pb(II). The advantage of heating the activated carbon with the electric heating experimental system (SEOW) required far less energy than in case of conventional method (up to many fold). In case of modified carbon ROW 08 Supra, the increased adsorption efficiency was obtained for coals modified at 800°C and the carbon modified at 400°C with the participation of water vapor. As a result of modification of the SEOW carbons for all analyzed activated carbons, the adsorption percentage increased. Among all the modified activated carbon, the highest adsorption capacity has been given to carbon modified to SEOW through heating it to 400°C and air cooling as well. The results are described by the means of Freundlich and Langmuir isotherm. In order to determine the coefficients of Langmuir isotherm, five different rectilinear forms were used. Among the analyzed issues the best fit to the experimental results obtained for the I Langmuir isotherms (the highest values of the coefficients R2). The impact of pH and temperature on the effectiveness within the adsorption solution of Pb (II) was also analyzed. The most effective adsorption of lead from solutions of pH 2, 4, and 6 occurred at the highest pH, but the differences between the adsorption solution at pH 6 and pH 8 has been low. Within the adsorption from solutions having a pH of 2 a very little adsorption of lead was observed. Furthermore the size of adsorption of solutions at 20, 30 and 40°C was analyzed as well. What has been found is that through increasing the temperature the efficiency of the adsorption process within Pb (II) is raised.
Źródło:
Rocznik Ochrona Środowiska; 2015, Tom 17, cz. 1; 692-709
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
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