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Wyświetlanie 1-10 z 10
Tytuł:
Activated carbons from molasses as CO₂ sorbents
Autorzy:
Młodzik, J.
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1070546.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
Aim of this research is to obtain effective, molasses based activated carbon, which would adsorb big amounts of CO₂. Molasses was mixed with KOH. Weight ratio of dry materials was 1:1 (AC1, AC3) and 1:2 (only AC2). Homogeneous mixture was obtained. Material was left for 3 h at 25°C. Drying lasted for 12 h at 200°C, and the material was grounded. The mixture was pyrolysed at 750°C, under constant flow (18 dm³/min) of nitrogen. The material was grounded again. Then, powder was washed with water, until filtrate was neutral, which took about 5 dm³ of water. AC3 was washed with 1 dm³ of water. After drying, materials were soaked in HCl (0.1 mol/dm³) for 19 h, and washed with water, until filtrate was neutral. CO₂ adsorption was performed under high pressure up to 40 atm, at 40°C. Specific surface area (according to the Brunauer-Emmett-Teller equation) was calculated for AC1, AC2 and AC3 and it is respectively 1985, 1967, and 2026 m²/g, micropore volume - 0.714, 0.707, and 0.728 cm³/g and it was between 75% and 89% of total pore volume. The excess uptake at 40 atm pressure was as follows: AC1 - 14.02 mmol/g, AC2 - 12.75 mmol/g, and AC3 - 15.79 mmol/g.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 402-404
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of commercial activated carbons for CO₂ adsorption
Autorzy:
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel,A. Gęsikiewicz-Puchalska, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1070602.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
The aim of the investigations was a modification of DTO, a commercial activated carbon (AC), to improve CO₂ adsorption capacity. The adsorption of CO₂ up to 40 bar at 40°C temperature was investigated. The volumetric method was applied for CO₂ adsorption isotherm measurements. The starting material - DTO - was modified using chemical activation (KOH, ZnCl₂, K₂CO₃). The textural parameters of all the ACs were determined by nitrogen adsorption at the liquid nitrogen temperature of -196°C on Quadrasorb SI. Results showed that the AC modified with KOH had the highest S_{BET}, V_{tot}, V_{mic} values of 2063 m²/g, 1.13 cm³/g, and 0.67 cm³/g, respectively. ACs with a wider pore size distribution (from micropores to mesopores) were obtained. The maximum CO₂ adsorption was equal to 14.44 mmol/g for DTO/KOH - modified carbon whereas 8.07 mmol/g of CO₂ was adsorbed at DTO. The CO₂ adsorption capacities of the ACs were found to be closely correlated with the BET surface areas of the materials tested. The experimental data was fitted to the Freundlich, Langmuir, Sips and Toth equations to determine the model isotherm. The Sips model was found to be the best for fitting the adsorption of CO₂.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 394-401
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of activated carbon from beet molasses and TiO₂ as the adsorption of CO₂
Autorzy:
Glonek, K.
Sreńscek-Nazzal, J.
Narkiewicz, U.
Morawski, A.
Wróbel, R.
Michalkiewicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/1075525.pdf
Data publikacji:
2016-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.U-
68.43.-h
Opis:
The objective of this work is to produce activated carbon from sugar beet molasses containing TiO₂ for CO₂ adsorption and reduction. Textural properties of activated carbons were obtained based on the adsorption-desorption isotherms of nitrogen at 77 K. The specific surface areas of activated carbons were calculated by the Brunauer-Emmett-Teller method. The volumes of micropores were obtained by density functional theory method. The adsorption isotherms of CO₂ were measured up to the pressure of 1 atm at a temperature of 40°C. The best activated carbon adsorbed 1.9 mmol/g of CO₂.
Źródło:
Acta Physica Polonica A; 2016, 129, 1; 158-161
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of Rhodamine B from aqueous solution by ZnFe2O4 nanocomposite with magnetic separation performance
Autorzy:
Konicki, W.
Siber, D.
Narkiewicz, U.
Powiązania:
https://bibliotekanauki.pl/articles/779010.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
Rhodamine B
ZnFe2O4
kinetics
thermodynamics
Opis:
Magnetic ZnFe2 O4  nanocomposite (ZnFe-NC) was used as an adsorbent for the removal of Rhodamine B (RB) from aqueous solution. The synthesized nanocomposite was characterized by XRD, SEM, HRTEM, BET and FTIR. The effects of various parameters such as initial RB concentration (5–25 mg L−1 ), pH (3.4–11.1) and temperature (20–60°C) were investigated. The adsorption capacity at equilibrium increased from 5.02 to 9.83 mg g−1 , with the increase in the initial concentration of RB from 5 to 25 mg L−1  at pH 7.0 and at 20°C. The experimental results indicated that the maximum RB removal could be attained at a solution pH of 4.4 and the adsorption capacity obtained was 6.02 mg g−1 . Kinetic adsorption data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order model and the intraparticle diffusion model. The adsorption kinetics well fitted using a pseudo-second-order kinetic model. The experimental isotherm data were analyzed using two isotherm models, namely, Langmuir and Freundlich. The results revealed that the adsorption behavior of the RB onto ZnFe-NC fitted well with the Langmuir isotherm model. In addition, various thermodynamic parameters, such as standard Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) have been calculated.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 4; 65-74
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Raman Scattering from ZnO(Fe) Nanoparticles
Autorzy:
Romčević, N.
Kostić, R.
Romčević, M.
Hadžić, B.
Kuryliszyn-Kudelska, I.
Dobrowolski, W.
Narkiewicz, U.
Sibera, D.
Powiązania:
https://bibliotekanauki.pl/articles/1811980.pdf
Data publikacji:
2008-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.20.-e
78.30.Fs
78.67.-n
Opis:
Nanocrystalline samples of ZnO(Fe) were synthesized by wet chemical method. Samples were characterized by X-ray diffraction to determine composition of the samples (ZnO, Fe₂O₃, ZnFe₂O₄) and the mean crystalline size (8-52 nm). In this paper we report the experimental spectra of the Raman scattering (from 200 to $1600 cm^{-1}$). Main characteristics of experimental Raman spectrum in 200 to $1600 cm^{-1}$ spectral region are: sharp peak at $436 cm^{-1}$ and broad two-phonon structure at ≈ $1150 cm^{-1}, typical of ZnO;broad structure below $700 cm^{-1}$ that has different position and shape in case of ZnFe₂O₄ or Fe₂O₃ nanoparticles.
Źródło:
Acta Physica Polonica A; 2008, 114, 5; 1323-1328
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Low-Frequency Raman Scattering from ZnO(Fe) Nanoparticles
Autorzy:
Kostić, R.
Romčević, N.
Romčević, M.
Hadžić, B.
Rudolf, R.
Kuryliszyn-Kudelska, I.
Dobrowolski, W.
Narkiewicz, U.
Sibera, D.
Powiązania:
https://bibliotekanauki.pl/articles/1807817.pdf
Data publikacji:
2009-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.30.Fs
78.67.-n
Opis:
Nanocrystalline samples of ZnO(Fe) were synthesized by wet chemical method. Samples were characterized by X-ray diffraction to determine the sample composition and the mean crystalline size. Low-frequency Raman modes were measured and assigned according to confined acoustic vibrations of spherical nanoparticles. Frequencies of these vibrational modes were analyzed in elastic continuum aproximation, which considers nanoparticle as homogeneous elastic sphere.
Źródło:
Acta Physica Polonica A; 2009, 116, 1; 65-67
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis by Wet Chemical Method and Characterization of Nanocrystalline ZnO Doped with $Fe_2O_3$
Autorzy:
Narkiewicz, U.
Sibera, D.
Kuryliszyn-Kudelska, I.
Kilański, L.
Dobrowolski, W.
Romčević, N.
Powiązania:
https://bibliotekanauki.pl/articles/1812407.pdf
Data publikacji:
2008-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.07.-b
75.75.+a
78.67.Bf
Opis:
Nanocrystalline samples of ZnO doped with $Fe_2O_3$ were synthetized by wet chemical method. The series of ZnO nanosized samples in the wide range of $Fe_2O_3$ concentration (from 5 wt.% to 95 wt.%) was prepared by precipitation from nitrate solutions using ammonia. The phase composition of the samples was determined using X-ray diffraction measurements. The phases of hexagonal ZnO, and/or rhombohedric $Fe_2O_3$, and/or $ZnFe_2O_4$ were identified. The mean crystalline size of nanocrystals, determined with the use of Scherrer's formula, varied from 8 to 52 nm. The preliminary micro-Raman spectroscopy measurements were performed. The observed features are typical of Fe doped ZnO nanoparticles. The magnetic measurements revealed the presence of different types of magnetic behavior. For samples with high $Fe_2O_3$ contents (above 70 wt.%) the ferromagnetic ordering was observed at room temperature. For samples with lower $Fe_2O_3$ contents we observed the phenomenon of superparamagnetism above the blocking temperature.
Źródło:
Acta Physica Polonica A; 2008, 113, 6; 1695-1700
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photoluminescence and Chromaticity Properties of ZnO Nanopowders Made by a Microwave Hydrothermal Method
Autorzy:
Wolska, E.
Sibera, D.
Witkowski, B.
Yatsunenko, S.
Pełech, I.
Narkiewicz, U.
Godlewski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1492917.pdf
Data publikacji:
2011-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.67.-n
61.43.Gt
81.07.Wx
78.55.Et
Opis:
Four series of ZnO nanopowders obtained by a microwave hydrothermal method are examined. Two different solvents (ethanol and distilled water) and different values of pressure during heating in the reactor were used. The obtained nanopowders show a bright emission covering visible light spectral region, including the band edge emission. Results of scanning electron microscopy, X-ray diffraction, photo- and cathodoluminescence investigations and also CIE1961 chromaticity diagram are presented.
Źródło:
Acta Physica Polonica A; 2011, 120, 5; 908-910
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of ZnO Doped with $Fe_{2}O_{3}$ - Hydrothermal Synthesis and Calcination Process
Autorzy:
Sibera, D.
Jędrzejewski, R.
Mizeracki, J.
Presz, A.
Narkiewicz, U.
Łojkowski, W.
Powiązania:
https://bibliotekanauki.pl/articles/1807546.pdf
Data publikacji:
2009-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.46.-w
68.37.Hk
81.07.-b
81.16.Be
Opis:
The aim of the present work is to compare two methods of synthesis of nanocrystallline zinc oxide doped with iron oxide. The synthesis was carried out using microwave asssisted hydrothermal synthesis and traditional wet chemistry method followed by calcination. The phase composition of the samples was determined using X-ray diffraction measurements. Depending on the chemical composition of the samples, hexagonal ZnO, and/or cubic $ZnFe_{2}O_{4}$ were identified. The morphology of the received materials was characterized using scanning electron microscopy. Two different structures of agglomerates were observed: a hexagonal structure (corresponding to zinc oxide) and spherical (corresponding to spinel phase). The effect of the iron oxide concentration on specific surface area and density of the samples was determined.
Źródło:
Acta Physica Polonica A; 2009, 116, S; S-133-S-135
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanocrystalline ZnO Doped with Fe$\text{}_{2}$O$\text{}_{3}$ - Magnetic and Structural Properties
Autorzy:
Kuryliszyn-Kudelska, I.
Hadžić, B.
Sibera, D.
Kilanski, L.
Romčević, N.
Romčević, M.
Narkiewicz, U.
Dobrowolski, W.
Powiązania:
https://bibliotekanauki.pl/articles/2048113.pdf
Data publikacji:
2011-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Tt
81.05.Dz
75.50.Lk
75.50.Vv
Opis:
We have studied the magnetic properties of ZnO nanocrystals doped with Fe$\text{}_{2}$O$\text{}_{3}$ in the magnetic dopant range from 5 to 70 wt%. The nanocrystals were synthesized by wet chemical method. The detailed structural characterization was performed by means of X-ray diffraction and micro-Raman spectroscopy measurements. The results of systematic measurements of magnetic AC susceptibility as a function of temperature and frequency are presented. We observed different types of magnetic behavior. For ZnO samples doped with low content of Fe$\text{}_{2}$O$\text{}_{3}$, the results of low-field AC susceptibility are satisfactorily explained by superparamagnetic model including inter-particle interactions. With the increase of magnetic Fe$\text{}_{2}$O$\text{}_{3}$ content, the spin-glass-like behavior is observed.
Źródło:
Acta Physica Polonica A; 2011, 119, 5; 689-691
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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