- Tytuł:
- Electrochemical properties of N'-ferrocenylmethyl-N'-phenylbenzohydrazide in aqueous and organic mediums
- Autorzy:
-
Nacer, S.N.
Lanez, T. - Powiązania:
- https://bibliotekanauki.pl/articles/411788.pdf
- Data publikacji:
- 2013
- Wydawca:
- Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
- Tematy:
-
cyclic voltammetry
diffusion coefficient
ferrocene derivative
half-wave potential
Randles-Sevcik equation - Opis:
- We carried out a detailed study of the kinetics of oxidation of N'-ferrocenylmethyl-N'-phenylbenzohydrazide (FcX) to ferrocenium ion (FcX+) in aqueous and organic mediums. This study using cyclic (CV) and rotating disk electrode (RDE) voltammetry showed that the FcX/FcX+ redox couple is reversible. The N'-ferrocenylmethyl-N'-phenylbenzohydrazide and ferrocenium ion diffusion coefficients (D) were calculated from these results. In addition, the electron transfer rate constant and the exchange current density for the oxidation of ferrocene were determined. A comparison of the kinetic data obtained from the two electrochemical techniques appears to show that the data from the RDE experiments are more reliable because they are collected under strict mass transport control.
- Źródło:
-
International Letters of Chemistry, Physics and Astronomy; 2013, 5; 76-85
2299-3843 - Pojawia się w:
- International Letters of Chemistry, Physics and Astronomy
- Dostawca treści:
- Biblioteka Nauki
Artykuł