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Wyszukujesz frazę "chemometrics" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Measurement data processing in spectrophotometric analysers of food. Review paper
Autorzy:
Morawski, R. Z.
Powiązania:
https://bibliotekanauki.pl/articles/221182.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spectrophotometry
chemometrics
spectral data processing
food analysis
wine analysis
Opis:
Spectrometry, especially spectrophotometry, is getting more and more often the method of choice not only in laboratory analysis of (bio)chemical substances, but also in the off-laboratory identification and testing of physical properties of various products, in particular - of various organic mixtures including food products and ingredients. Specialised spectrophotometers, called spectrophotometric analysers, are designed for such applications. This paper is on the state of the art in the domain of data processing in spectrophotometric analysers of food (including beverages). The following issues are covered: methodological background of food analysis, physical and metrological principles of spectrophotometry, the role of measurement data processing in spectrophotometry. General considerations are illustrated with examples, predominantly related to wine and olive oil analysis.
Źródło:
Metrology and Measurement Systems; 2012, 19, 4; 623-652
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of five SVD-based algorithms for calibration of spectrophotometric analyzers
Autorzy:
Wagner, J.
Morawski, R. Z.
Miękina, A.
Powiązania:
https://bibliotekanauki.pl/articles/220564.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spectrophotometry
chemometrics
singular value decomposition
regularisation
food analysis
edible oils analysis
Opis:
Spectrophotometry is an analytical technique of increasing importance for the food industry, applied i.a. in the quantitative assessment of the composition of mixtures. Since the absorbance data acquired by means of a spectrophotometer are highly correlated, the problem of calibration of a spectrophotometric analyzer is, as a rule, numerically ill-conditioned, and advanced data-processing methods must be frequently applied to attain an acceptable level of measurement uncertainty. This paper contains a description of four algorithms for calibration of spectrophotometric analyzers, based on the singular value decomposition (SVD) of matrices, as well as the results of their comparison - in terms of measurement uncertainty and computational complexity - with a reference algorithm based on the estimator of ordinary least squares. The comparison is carried out using an extensive collection of semi-synthetic data representative of trinary mixtures of edible oils. The results of that comparison show the superiority of an algorithm of calibration based on the truncated SVD combined with a signal-to-noise ratio used as a criterion for the selection of regularisation parameters - with respect to other SVD-based algorithms of calibration.
Źródło:
Metrology and Measurement Systems; 2014, 21, 2; 191-204
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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