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Wyświetlanie 1-4 z 4
Tytuł:
Effective Removal of Iron (II) from Aqueous Solution by Adsorption using Zn/Cr Layered Double Hydroxides Intercalated with Keggin Ion
Autorzy:
Oktriyanti, Melantina
Palapa, Neza Rahayu
Mohadi, Risfidian
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/125462.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
iron(II)
desorption
zinc
chromium
layered double hydroxide
Opis:
Zn/Cr and Zn/Cr layered double hydroxides (LDHs) intercalated with Keggin ion [α-SiW12O40]4-were successfully synthesized at room temperature and pH value of 10. The synthesized materials were characterized by means of the XRD, BET, and FT-IR analyses and used as an adsorbent iron(II). The adsorption process was investigated by studying pH, the kinetics, and thermodynamic properties of the adsorption process. The results showed the interlayer Zn/Cr LDHs was 7.53 Å and increase to 10.26 Å on Zn/Cr LDHs intercalated with Keggin ion [α-SiW12O40]4-. The BET analysis showed that the pore volume of both materials increased from 0.063 cm3 g-1 to 0.163 cm3 g-1. The pH point zero charge measurement for the Zn/Cr LDHs material was 10 while LDHs Zn/Cr intercalated with Keggin ion [α-SiW12O40]4- was 8. Zn/Cr LDHs intercalated with Keggin ion [α-SiW12O40]4- has higher adsorption capacity than Zn/Cr LDHs without intercalation. Desorption of iron (III) was successfully conducted using HCl as reagent showing the involvement of ion exchange in the adsorption.
Źródło:
Journal of Ecological Engineering; 2020, 21, 5; 63-71
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of Renewable Material Hydrochar-Based CaAl Layered Double Hydroxide to Overcome Methyl Red Dyes Contaminant
Autorzy:
Mohadi, Risfidian
Juleanti, Novie
Palapa, Neza Rahayu
Hidayati, Nurlisa
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/2068466.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
Ca/Al
layered double hydroxide
hydrochar
methyl red
selectivity
Opis:
The preparation of the CaAl/HC composite was carried out with a supporting material in the form of hydrochar from duku skin. The success of the preparation was demonstrated by XRD, FT-IR, and BET analysis. The diffractogram of CaAl/HC showed diffraction peaks at 2θ = 10.16° (003), 18.0° (002), 20.15° (006) and 65.4° (110). The diffraction showed similarity to diffraction in CaAl and hydrochar double layer hydroxyl. The FT-IR spectrum of CaAl/HC also showed similarity to the CaAl/HC double layer hydroxyl at 3448, 1635, and 1381 cm-1. The characteristic spectrum of the hydrochar also appeared in CaAl/HC at 20.15. BET analysis showed an increase in the surface area of CaAl/HC before modification of 11.842 m2/g and increased to 22.635 m2/g of CaAl/HC. The ability of CaAl/HC as an adsorbent is determined through several parameters including selectivity, regeneration, isotherm, and thermodynamics. The results of dye selectivity showed that CaAl/HC was more likely to absorb MR dyes in a mixture of dyes (DG, MO, PR, MR, CR, and DR). The regeneration results showed the ability of CaAl/HC which lasted up to 73.26% in the fifth cycle.
Źródło:
Journal of Ecological Engineering; 2022, 23, 3; 17--25
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Soft Ion Divalent Metals toward Adsorption on Zn/Al-POM Layered Double Hydroxide
Autorzy:
Silaen, Luna
Elfita, -
Mohadi, Risfidian
Normah, -
Juleanti, Novie
Palapa, Neza Rahayu
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/2027762.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
soft divalent metal ions
adsorption
polyoxometalate
regeneration
Opis:
Development of Zn/Al layered double hydroxide by intercalation using polyoxometalate (POM) $K_4 [α-SiW_12O_40]$ to Zn/Al-POM was investigated. The success of the modification is evidenced by the XRD, FT-IR, and BET characterization data. XRD characterization showed an increase in the interlayer distance from 8.59 Å in Zn/Al LDHs to 10.26 Å in Zn/Al-POM. This success is also supported by the FT-IR data with the appearance of vibrations around $779–979 cm^{-1}$ which indicates the vibration of the polyoxometalate compound in Zn/Al-POM. Other supporting data in the form of BET also prove an increase in surface area from 1.968 $m^2$/g in Zn/Al LDHs to 14.042 $m^2$/g Zn/Al-POM. The ability of Zn/Al-POM as an adsorbent is proven through several parameters such as kinetics, isotherm, thermodynamics, and regeneration for $Cd^{2+}$, $Pb^{2+}$, $Ni^{2+}$, and $Co^{2+}$. Adsorption kinetics showed that Zn/Al-POM was more likely to follow the pseudo-second-order adsorption kinetics model for $Cd^{2+}$, $Pb^{2+}$, $Ni^{2+}$, and $Co^{2+}$. The results of determining the adsorption isotherm parameters of Zn/Al-POM tend to follow the Freundlich isotherm model with a maximum adsorption capacity of 74.13 mg/g on $Pb^{2+}$. The regeneration process showed that Zn/Al-POM was more resistant than Zn/Al LDHs up to 3 cycles. It was proven that Zn/Al-POM was able to survive in the last cycle up to 69.19% on $Ni^{2+}$.
Źródło:
Journal of Ecological Engineering; 2021, 22, 10; 109-120
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improving the Performance of Mg/Cr LDH by Forming Metal Oxides Mg/Cr-Ni Using Coprecipitation Method as Adsorbent for Cationic Dyes
Autorzy:
Yuliasari, Nova
Badri, Arini Fousty
Siregar, Patimah Mega Syah Bahar Nur
Palapa, Neza Rahayu
Mardiyanto
Mohadi, Risfidian
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/2105268.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
metal oxide
rhodamine B
methylene blue
regeneration
Opis:
This study aimed to determine the adsorption capacity of rhodamine-B (Rh-B) and methylene blue (MB) on Mg/Cr-Ni adsorbents. The Mg/Cr-Ni adsorbent was synthesized by the coprecipitation method. The results of the characterization of Mg/Cr-Ni using XRD analysis showed the formation of oxides at an angle of 2θ = 31.726°, 33°, and 45.44°. The surface area of Mg/Cr-Ni is 23.139 m2/g. The adsorption capacity test for Mg/Cr-Ni for Rh-B and MB were 85.470 mg/g and 166.667 mg/g, respectively. The adsorption kinetics model followed the pseudo second order (PSO). The adsorption process is endothermic and occurs spontaneously at any temperature. Mg/CrNi showed stability in the adsorption process of Rh-B and MB for 5 regeneration cycles.
Źródło:
Journal of Ecological Engineering; 2022, 23, 6; 67--74
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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