- Tytuł:
- Olefin Hydrogenation with Single-Site Gold
- Autorzy:
-
Szlachetko, J.
Lothschütz, C.
Sá, J. - Powiązania:
- https://bibliotekanauki.pl/articles/1197714.pdf
- Data publikacji:
- 2014-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
82.80.Dx
82.20.-w
82.80.Ej - Opis:
- Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent group of the coordinating group at position 5. Resonant inelastic X-ray scattering experiments and theoretical calculations revealed an increase in unoccupied 5d states of Au when the substituent group is a donating group, which leads to a dramatic increase in catalytic activity.
- Źródło:
-
Acta Physica Polonica A; 2014, 125, 4; 940-943
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł